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Title:
PREPARATION OF DIPENTAERYTHRITOL ESTER MIXTURE
Document Type and Number:
Japanese Patent JPS5782343
Kind Code:
A
Abstract:

PURPOSE: To obtain the titled compound useful as a monomer for a homopolymer, etc., by reacting dipentaerythritol with acrylic acid, benzoic acid and a saturated monobasic acid, and introducing a benzoyl group or alkanoyl group into the molecule.

CONSTITUTION: Dipentaerythritol is reacted with acrylic acid (or methacrylic acid), benzoic acid (or phenoxyacetic acid) and a 2W6C saturated monobasic acid at 75W120°C to give the mixture of the aimed formula (R1 is acryloyl or methacryloyl; R2 is benzoyl or phenoxyethanoyl; R3 is 2W6C alkanoyl; R4 is H; p, q, r and s are as follows: p+q+r+s=6; 1≤p≤6; 0≤q≤5; 0≤r≤5; 0≤s≤3). The reaction can be accelerated by using an acid catalyst in the reaction system, and distilling the formed water with an azeotropic solvent, etc.

USE: A monomer for a copolymer, etc. and a raw material for a resin, reactive diluting agent, reactive plasticizer, adhesive, ink, coating materal, etc.


Inventors:
MATSUDA HATANOBU
NAWATA KAZUMITSU
HIRONAKA TETSUO
Application Number:
JP15888180A
Publication Date:
May 22, 1982
Filing Date:
November 13, 1980
Export Citation:
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Assignee:
NIPPON KAYAKU KK
International Classes:
C07C69/003; C07C67/08; (IPC1-7): C07C67/08; C07C69/003
Domestic Patent References:
JPS5363306A1978-06-06
JPS52131513A1977-11-04
JP40002908A
JPS51118843A1976-10-19
JPS5464264A1979-05-23