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Patent Searching and Data


Title:
PROCESS FOR POLYMERIZING WATER-SOLUBLE AND WATER-INSOLUBLE CARBOXYLIC ACID MONOMERS IN SILICONE OIL
Document Type and Number:
Japanese Patent JPH08208719
Kind Code:
A
Abstract:

To obtain an improved process for producing a (thickened) polymer wherein a usual nonpressurized reactor can be used by producing a carboxylic acid (co)polymer in a silicone oil.

The process comprises the step of polymerizing a carboxylic acid monomer in a silicone solvent in an inert atmosphere in the presence of an initiator. In the process, a water-insol. cross-linked thickened (co)polymer which gives a 0.5 wt.% water soln. having a viscosity of about 50,000-300,000 cP is obtd. by conducting the polymn. at a molar ratio of the carboxylic acid monomer to a cross-linking monomer of (1:0.03)-(1:0.10). A pref. initiator is a redox initiator. An esp. pref. carboxylic acid monomer is acrylic acid, and an esp. pref. cross-linking monomer is allkyl methacrylate. Examples of the silicone solvent are cyclomethylsiloxane, a linear polydimethylsiloxane, an arom. phenyl-contg. siloxane, a polymethylalkylsiloxane, and a fluorosilicone.


Inventors:
ANSONII ESU TOMURIN
MIRAN EFU SOYOKA
Application Number:
JP27553595A
Publication Date:
August 13, 1996
Filing Date:
October 24, 1995
Export Citation:
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Assignee:
AMCOL INTERNATIONAL CORP (US)
International Classes:
C08F2/08; B01J20/26; B01J20/30; C08F2/06; C08F20/04; C08F20/06; C08F20/18; C08F120/04; C08F220/04; C08F220/10; C09K3/32; C09K8/12; C09K8/88; (IPC1-7): C08F2/08; C08F20/06; C08F20/18
Attorney, Agent or Firm:
Yoshihiro Tsunoda