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Title:
PRODUCTION OF 2,6-NAPHTHALENEDICARBOXYLIC ACID
Document Type and Number:
Japanese Patent JPH10316615
Kind Code:
A
Abstract:

To provide a method for producing 2,6-naphthalenedicarboxylic acid by which a substance inhibiting an oxidizing reaction can be prevented from accumulating and a high yield can be maintained when circulating an oxidizing reaction mother liquor for use in the liquid-phase oxidizing reaction of 2,6- dimethylnaphthalene.

The total amount of cobalt and manganese which are catalyst components is 50-300 mg atoms based on 1 g atom 2,6-dimethylnaphthalene at an atomic ratio of the manganese to the cobalt of (1:20) to (1:4) and an oxidizing reaction is carried out at 200-250°C temperature in a method for oxidizing the 2,6-dimthylnaphthalene with an oxygen-containing gas in the presence of a catalyst containing the cobalt, manganese and bromine in a solvent containing a lower aliphatic carboxylic acid and producing 2,6- naphthalenedicarboxylic acid.


Inventors:
TANAKA KAZUO
INARI MASAHITO
MACHIDA HIROSHI
Application Number:
JP13103397A
Publication Date:
December 02, 1998
Filing Date:
May 21, 1997
Export Citation:
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Assignee:
MITSUBISHI GAS CHEMICAL CO
International Classes:
B01J27/128; C07B61/00; C07C51/265; C07C51/43; C07C63/38; (IPC1-7): C07C63/38; B01J27/128; C07C51/265; C07C51/43