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Patent Searching and Data


Title:
PRODUCTION OF 4,4'-DIAMINODIPHENYLETHANE DERIVATIVE
Document Type and Number:
Japanese Patent JPS61189231
Kind Code:
A
Abstract:

PURPOSE: To obtain the titled compound useful as an intermediate for the pigment of pressure-sensitive paper, etc., in high efficiency, by carrying out the dehydrative condensation of an N,N-disubstituted aniline with 1-(4- aminophenyl)ethanol, and if necessary, condensing the product with an alkylation agent.

CONSTITUTION: The compound of formula I (R1 and R2 are lower aliphatic alkyl, cycloalkyl, aralkyl, allyl, aryl, propargyl, etc.; R3 is H, lower aliphatic alkyl, lower aliphatic alkoxy or halogen) is subjected to the dehydrative condensation with the compound of formula II at room temperature W 200°C for several hours to obtain an objective compound of formula III, which can be converted if necessary to another objective compound of formula V by condensing with the alkylation agent of formula IV (R4 is the group in R1 and R2; X is residue of the alkylation agent) at 50W150°C for several hours. The objective compound of formula III or formula IV useful as an intermediate for the pigment of pressure-sensitive paper and an organic photo-conductor for electrophotography can be produced by the above method, economically with extremely simple purification and separation operations.


Inventors:
KANDA NOBUO
KONDO MITSURU
Application Number:
JP2889785A
Publication Date:
August 22, 1986
Filing Date:
February 15, 1985
Export Citation:
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Assignee:
KANZAKI PAPER MFG CO LTD
International Classes:
C07B43/04; C07B31/00; C07C67/00; C07C209/00; C07C209/10; C07C209/18; C07C209/68; C07C211/50; C07C213/00; C07C217/56; C07C217/84; C07D295/12; (IPC1-7): C07B43/04; C07C85/24; C07C87/50; C07C93/04; C07D295/12
Attorney, Agent or Firm:
Hasumi Masaru