PRODUCTION OF AMIDE-ETHER CARBOXYLATE

Title:

PRODUCTION OF AMIDE-ETHER CARBOXYLATE

Document Type and Number:

Japanese Patent JPH09143134

Kind Code:

A

Abstract:

To obtain an amide-ether carboxylate of high purity with reduced content of amide ester as an by-product by the reaction of an amide alcohol with an alkanolamine followed by reaction of the product with a monohalogenoacetic acid.

An amide alcohol of the formula: R1CONH-CH2CH2O-(CH2CH2 O)nH (R1 is a 7-21C alkyl or alkenyl; n is 0-20) is allowed to react with an alkanolamine of the formula: NH(Y)a [(R2O) mH]b (Y is H, a 1-3C alkyl; R3 is a 2-3C alkylene; m is 1-20; a is 0 or 1; b is 1 or 2 where a+b=2) at a temperature higher than the melting point of the amide alcohol but not higher than 100°C for 0.1-5 hours. Then, a monohalogenoacetic acid of the formula: XCH2 COOM (X is a halogen; M is H or an alkali metal) or its salt at 50-100°C under a reduced pressure of 5-200mmHg to give the objective amide-ether carboxylate of the formula: R1CONH-CH2CH2O-(CH2CH2O)nCH2COOM' (M' is H, a cation).

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Inventors:

IMOTO HIROYUKI
OSHIMA YUKIKO
FUJIO AKIRA

Application Number:

JP30879595A

Publication Date:

June 03, 1997

Filing Date:

November 28, 1995

Export Citation:

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Assignee:

KAO CORP

International Classes:

C07C231/12; C07C233/18; C07C233/20; (IPC1-7): C07C233/18; C07C231/12; C07C233/20

Attorney, Agent or Firm:

Kaoru Furuya (3 outside)

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