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Patent Searching and Data


Title:
PRODUCTION OF AROMATIC CARBOXYLIC ACID
Document Type and Number:
Japanese Patent JPH0853391
Kind Code:
A
Abstract:

PURPOSE: To efficiently obtain the subject compound in high yield at a low cost by using a specific catalyst in oxidizing an aromatic compound containing an alkyl substituent group with a gas containing molecular oxygen in an aqueous medium.

CONSTITUTION: This method for producing an aromatic carboxylic acid is to oxidize an aromatic compound containing an alkyl substituent group or a partially oxidized alkyl substituent group (e.g. p-xylene) with a gas containing molecular oxygen in an aqueous medium using a compound in which a transition metal (preferably Cr, Mn, Fe, etc.) integrated into a heteropoly acid skeleton having a deficient structural site {preferably a deficient type hexametalate-form ion, etc., of the formula [M5O18]n- [M is Mo or W; (n) is an integer]} as a catalyst. Furthermore, the reaction is preferably carried out at 150-230°C under 10-80atm for 1-5hr and the amount of the catalyst used is preferably 100-5000ppm based on the reactional solution.


Inventors:
MIZUHO YUUJI
ASAHI YOSHIO
SASAKI YASUYUKI
Application Number:
JP19063394A
Publication Date:
February 27, 1996
Filing Date:
August 12, 1994
Export Citation:
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Assignee:
MITSUBISHI CHEM CORP
International Classes:
B01J23/28; B01J23/30; B01J27/188; B01J27/19; B01J27/199; C07B61/00; C07C51/265; C07C63/00; C07C63/26; (IPC1-7): C07C63/00; B01J23/28; B01J23/30; B01J27/188; B01J27/19; B01J27/199; C07C51/265; C07C63/26
Attorney, Agent or Firm:
Hasegawa Moji