PURPOSE: To obtain a polyimide having excellent moldability, heat resistance and mechanical characteristics, by reacting p-phenylenediamine with a pyromellitic acid derivative, aromatic diamine and aromatic tetracarboxylic acid derivative in a given order and then heating the resultant product.
CONSTITUTION: p-Phenylenediamine is reacted with a pyromellitic acid derivative and then an aromatic diamine and aromatic tetracarboxylic acid derivative or the aromatic diamine is reacted with the aromatic tetracarboxylic acid derivative. Furthermore, the p-phenylenediamine and pyromellitic acid derivative are added so as to provide a substantially equimolar amount of the respective total numbers of mol. of the p-phenylenediamine and aromatic diamine with pyromellitic acid derivative and aromatic tetracarboxylic acid derivative and reacted to afford a polyamic acid or derivative thereof, which is then thermally reacted.
YAMAMOTO YASUSHI
ETO SHOHEI
FUKAMI AKIRA
JPH01131241A | 1989-05-24 | |||
JPH01103626A | 1989-04-20 |
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