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Title:
PRODUCTION OF BIPHENYL DERIVATIVE
Document Type and Number:
Japanese Patent JP3869531
Kind Code:
B2
Abstract:

PROBLEM TO BE SOLVED: To selectively produce the subject derivative useful as an intermediate for medicines, agrochemicals, liquid crystals, heat-resistant polymers or the like from an inexpensive raw material by reacting a specific cyclohexenone derivative with a halogenating agent in (or without) a solvent and then carrying out an eliminating reaction of the halogen atom in the presence of a base in (or without) a solvent.
SOLUTION: A compound represented by formula I (X is H or the like; Y is CO2 or the like) is reacted with methyl vinyl ketone in the presence of a condensing agent in (or without) a solvent to synthesize a compound represented by formula II. A cyclizing reaction is then carried out in the presence of the condensing agent in (or without) a solvent to produce a cyclohexenone derivative represented by formula III, which is then reacted with a halogenating agent in (or without) a solvent to form a compound represented by formula IV or the like. The halogen atom of the resultant compound represented by formula IV or the like is further eliminated in the presence of a base in (or without) a solvent to afford the objective derivative represented by formula V.


Inventors:
Tetsuya Totani
Hidetoshi Shirakura
Junichi now
Application Number:
JP21979497A
Publication Date:
January 17, 2007
Filing Date:
August 01, 1997
Export Citation:
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Assignee:
NIPPON KAYAKU KABUSHIKI KAISHA
International Classes:
C07C51/377; C07C65/38; C07C63/331; C07C63/66; C07C67/317; C07C67/333; C07C69/757; C07C255/46; (IPC1-7): C07C65/38; C07C51/377; C07C63/331; C07C63/66; C07C67/317; C07C67/333; C07C69/757; C07C255/46
Domestic Patent References:
JP4505625A