Title:
PRODUCTION OF FREE CARBON-CONTAINING GROUP AND APPLICATION PARTICULARLY TO RADICAL POLYMERIZATION
Document Type and Number:
Japanese Patent JPS60166627
Kind Code:
A
Abstract:
Process for the formation of carbon-containing free radicals R., which optionally include functional groups, wherein thermal and/or photochemical energy is supplied to a thiocarbonyl-containing ester corresponding to the general formula (I): (I) in which: R denotes a saturated or unsaturated, linear or branched, aliphatic or aromatic, acyclic or alternatively mono- or poly-cyclic or mono- or poly-heterocyclic, carbon-containing radical which in addition can optionally include functional groups; R' and R'' denote, independently of each other, an alkyl, alkenyl, aryl, aralkyl or alkaryl radical, or alternatively form together a 5- or 6-membered nitrogen-containing heterocycle which can also contain an additional heteroatom chosen from nitrogen and sulfur and which can optionally be substituted or fused to at least one other aliphatic or aromatic ring; R1 and R2 denote, independently of each other, a hydrogen atom or a lower alkyl radical, and n is an integer equal to 0, 1, 2 or 3.
Inventors:
JIIRU DEREKU HARORUDO RICHIYAA
DEBITSUTO KURITSUKU
UIRIAMU BURANKUSU MOZAAUERU
DEBITSUTO KURITSUKU
UIRIAMU BURANKUSU MOZAAUERU
Application Number:
JP17579984A
Publication Date:
August 29, 1985
Filing Date:
August 23, 1984
Export Citation:
Assignee:
CENTRE NAT RECH SCIENT
International Classes:
B01J19/12; C07B31/00; C07B60/00; C07B61/00; C07C1/00; C07C1/207; C07C9/22; C07C17/00; C07C17/093; C07C17/18; C07C33/24; C07C67/00; C07C325/00; C07C325/02; C07D213/70; C07D515/04; C07J7/00; C07J9/00; C07J43/00; C07J75/00; C08F2/46; C08F4/00; C08F10/00; (IPC1-7): B01J19/12; C07B61/00; C07C1/253; C07C17/22; C07C151/00; C07D213/70; C07D515/04; C07J43/00; C07J75/00
Attorney, Agent or Firm:
Teruo Akimoto