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Patent Searching and Data


Title:
PRODUCTION OF GAMMA-JASMOLACTONE
Document Type and Number:
Japanese Patent JPS63119480
Kind Code:
A
Abstract:

PURPOSE: To easily obtain the titled compound by using easily available acrylaldehyde diethylacetal as a raw material, subjecting to radical addition reaction with cis-4-heptenal, reducing the resultant intermediate and oxidizing the product with Jones reagent.

CONSTITUTION: The objective compound useful as a perfume discovered from an essential oil such as jasmine or peppermint, etc., can be produced by carrying out radical addition reaction of acrylaldehyde diethylacetal derived easily from acrylaldehyde with cis-4-heptenal to obtain γ-oxoaldehyde acetal intermediate exhibiting pheromone activity, reducing the intermediate to 1,1-diethoxy-cis-7- decen-4-ol and oxidizing the product with Jones reagent. The process is valuable because an intermediate useful as a production raw material for pheromones exhibiting the activity of animal pheromone is produced during the reaction and the reaction can be carried out under mild condition without using expensive reagent.


Inventors:
TSUKASA HIDETAKA
Application Number:
JP26358686A
Publication Date:
May 24, 1988
Filing Date:
November 05, 1986
Export Citation:
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Assignee:
TOYOTAMA PERFUMERY
International Classes:
C07D307/33; C07C41/00; C07C43/315; C07C45/00; C07C49/255; C07C67/00; C07D307/32; (IPC1-7): C07C43/315; C07C49/255; C07D307/32
Attorney, Agent or Firm:
Hideaki Sato