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Title:
PRODUCTION OF NORBORNENE-BASED RANDOM COPOLYMER
Document Type and Number:
Japanese Patent JPH11171918
Kind Code:
A
Abstract:

To obtain the subject copolymer having a high glass transition point, by copolymerizing an α-olefin with a specific norbornene in the presence of a prescribed catalyst and specifying a glass transition point, etc.

(A) An 2-20C α-olefin is copolymerized with (B) a norbornene of formula I (R1 to R8 are each H, a halogen or a hydrocarbon and R5 is bonded to R6 and R7 is bonded to R8 to form an alkylidene) in the presence of (C) (i) a transition metal compound of formula II [M is Ti, Zr or the like; R11 and R12 are each a (substituted) indenyl or the like; R13 and R14 are each a 1-10C alkyl a 6-10C aryl or the like; X1 and X2 are each an O-containing group, H or the like], (ii) an organoaluminum oxy compound and /or a compound which is reacted with the component (i) to form a counter ion and (iii) optionally an organoaluminum compound to give the objective copolymer containing ≥60 mol.% of a constituent unit derived from the component B and having ≥160°C glass transition point.


Inventors:
YAMAGUCHI MASAYOSHI
TAKIMOTO KAZUYUKI
Application Number:
JP34104297A
Publication Date:
June 29, 1999
Filing Date:
December 11, 1997
Export Citation:
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Assignee:
MITSUI CHEMICALS INC
International Classes:
C08F4/642; C08F4/6592; C08F210/14; C08F232/08; (IPC1-7): C08F4/642; C08F210/14; C08F232/08
Attorney, Agent or Firm:
Shunichiro Suzuki