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Title:
PRODUCTION OF POLYESTER CONTAINING FINE PARTICLE
Document Type and Number:
Japanese Patent JPS62146919
Kind Code:
A
Abstract:

PURPOSE: To obtain the title polyester which is free of yarn break and can give a product of excellent surface smoothness, by reacting a dicarboxylic acid or the like with ethylene glycol and adding a SiO2 sol, a S-containing compound and a Cl-containing compound in amounts satisfying specified relationships to the reaction system in an arbitarary stage of the reaction.

CONSTITUTION: A sol (C) is obtained by mixing a sol (a), concentration ≤50wt%, obtained by adding SiO2 of an average particle diameter of 0.01W2.0μ to water or ethylene glycol, a sulfur-containing compound (b) (e.g., Na2SO4) and a chlorine-contaning compound (c) (e.g., NaCl) n such amounts that the relationships I, II and III (wherein S is a ratio of the sulfur in compound (b) to SiO2, and Cl is a ratio of the chlorine in component (c) to SiO2, in terms of ppm) hold. A dicarboxylic acid (esterifiable derivative) (A) is transesterified, for example, with ethylene glycol (B), and component Ci s added to the reaction system in an arbitarary stage of the reaction to obtain the title polyester freed of secondary aggloerates.


Inventors:
SHIMIZU YUZO
SUZUKI MASARU
OKASAKA HIDESADA
Application Number:
JP28641085A
Publication Date:
June 30, 1987
Filing Date:
December 19, 1985
Export Citation:
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Assignee:
TORAY INDUSTRIES
International Classes:
C08K3/10; C08G63/16; C08G63/18; C08G63/68; C08G63/682; C08G63/688; C08G63/695; C08G63/78; C08J5/18; C08K3/00; C08K3/34; C08K5/36; C08L67/00; C08L67/02; (IPC1-7): C08G63/22
Domestic Patent References:
JPS51597A1976-01-06
JPS4843193A1973-06-22
JPS4843192A1973-06-22



 
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