Title:
RADICAL POLYMERIZATION OR COPOLYMERIZATION OF (METH) ACRYLIC MONOMER AND VINYL MONOMER UNDER CONTROL AND (CO)POLYMER OBTAINED BY THE SAME METHOD
Document Type and Number:
Japanese Patent JP3100354
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide a method for radical (co)polymerization by which good control is carried out in relation to various polymerization parameters and a block copolymer is obtained and to produce a (co)polymer obtained by the method.
SOLUTION: At least one of a (meth)acrylic monomer and/or a vinyl monomer is polymerized or copolymerized in a bulk, a solution, an emulsion or a suspension in the presence of an initiator system containing at least one radical former compound other than an arenesulfonyl chloride and at least one catalyst having a metallic complex represented by the formula MAa(L)n {M denotes Ni, Pd or Pt; A denotes a halogen or a pseudohalide; L denotes a ligand of a metal M and is independently selected from a ligand containing at least one of N, P, As, Sb and Bi; at least two of the ligands may mutually be connected with one or more bivalent groups; (a) is an integer of 1-5; (n) is an integer of 1-4; [(a)+(n)] indicating the coordination number of the complex is 4≤[(a)+(n)]≤6} at a temperature which may be as low as about 0°C.
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Inventors:
Thierry Seninge
Muriel Prussia
Muriel Prussia
Application Number:
JP18774997A
Publication Date:
October 16, 2000
Filing Date:
June 27, 1997
Export Citation:
Assignee:
Elf Atochem S.A.
International Classes:
C08F2/38; C08F4/00; C08F4/26; C08F4/40; C08F4/42; C08F2/00; C08F4/70; C08F4/80; C08F12/08; C08F14/06; C08F20/00; C08F20/16; (IPC1-7): C08F4/40; C08F4/26; C08F12/08; C08F14/06; C08F20/00
Domestic Patent References:
| JP6107715A |
Attorney, Agent or Firm:
Yusuke Hiraki (1 person outside)
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