Title:
メソポーラス材料内における金属−有機構造体の固相結晶化方法及びそのハイブリッド材料
Document Type and Number:
Japanese Patent JP6972102
Kind Code:
B2
Abstract:
A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula AX(L−X) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula AX(L−X)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula HX(L−X)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M+y(B)y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M+y(B)y][Hx(L−x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M+yL−x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.
Inventors:
Ignacio Rutz Minguez
Mustafa Socri
Marty Lyle
Mustafa Socri
Marty Lyle
Application Number:
JP2019502086A
Publication Date:
November 24, 2021
Filing Date:
August 10, 2017
Export Citation:
Assignee:
Research Triangle Institute
International Classes:
C07C51/41; C01B37/00; C01B37/02; C01B39/02; C01F7/02; C07C63/28; C07C63/307; C07C63/48; C07C65/05; C07C227/18; C07C229/62; C07C303/32; C07C309/58; C07D233/54; C07D239/24; C07D249/02
Domestic Patent References:
| JP2011126775A |
Foreign References:
| CN105056895A | ||||
| US20120152845 |
Other References:
Journal of Materials Chemistry,2011年,Vol. 21, No. 18,pp. 6698-6706
Chemical Communications,2013年,Vol. 49,pp. 1223-1225
Modulated formation of metal-organic frameworks by oriented growth over mesoporous silica,Journal of Materials Chemistry A,2013年,Vol. 1,pp. 3047-3054
Synthesis of a metal-organic framework confined in periodic mesoporous silica with enhanced hydrostability as a novel fiber coating for solid-phase microextraction,Journal of Separation Science,2015年,Vol. 38, No. 7,pp. 1187-1193
Chemical Communications,2013年,Vol. 49,pp. 1223-1225
Modulated formation of metal-organic frameworks by oriented growth over mesoporous silica,Journal of Materials Chemistry A,2013年,Vol. 1,pp. 3047-3054
Synthesis of a metal-organic framework confined in periodic mesoporous silica with enhanced hydrostability as a novel fiber coating for solid-phase microextraction,Journal of Separation Science,2015年,Vol. 38, No. 7,pp. 1187-1193
Attorney, Agent or Firm:
Kenji Sugimura
Mitsutsugu Sugimura
Hiroshi Kishi
Mitsutsugu Sugimura
Hiroshi Kishi