メソポーラス材料内における金属－有機構造体の固相結晶化方法及びそのハイブリッド材料

Japanese Patent JP7426976

B2

A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula AX(L−X) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula AX(L−X)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula HX(L−X)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M+y(B)y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M+y(B)y][Hx(L−x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M+yL−x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.

Ignacio Ruth Minguez
Mustafa Sokri
Marty Lyle

JP2021179381A

February 02, 2024

November 02, 2021

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Research Triangle Institute

C07C63/15; A61K47/02; A61K47/04; A61K47/12; B01J20/22; C01B37/00; C07C51/41; C07C63/28; C07C65/03; C07C227/16; C07C229/62; C07C303/22; C07C309/57; C07D233/56; C07D487/22; C07F7/02

JP2011126775A

CN105056895A

Journal of Materials Chemistry,2011年,Vol. 21, No. 18,pp. 6698-6706
Chemical Communications,2013年,Vol. 49,pp. 1223-1225
The Journal of Physical Chemistry B,2002年,Vol. 106, No. 27,pp. 6913-6920

Kenji Sugimura
Mitsutsugu Sugimura
Hiromitsu Takashi

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