Title:
表面修飾した固体無機/有機ハイブリッド
Document Type and Number:
Japanese Patent JP5410435
Kind Code:
B2
Abstract:
Solid crystalline porous metal organic framework with modified surface comprising three-dimensional units (I), is new, where the modified surface comprises at least an organic surface agent. Solid crystalline porous metal organic framework with modified surface comprising three-dimensional units of formula (M mO kX lL p) (I), is new, where the modified surface comprises at least an organic surface agent. M : metallic ion comprising Fe 2+>, Fe 3+>, Zn 2+>, Ti 3+>, Ti 4+>, Zr 2+>, Zr 4+>, Ca 2+>, Cu 2+>, Gd 3+>, Mg 2+>, Mn 2+>, Mn 3+>, Mn 4+>or Si 4+>; m, k, l, p : >= 0; X : ligand comprising OH ->, Cl ->, F ->, I ->, Br ->, SO 4 2->, NO 3 ->, ClO 4 ->, PF 6 ->, R 1>-(COO) n ->, R 1>-(SO 3) n ->or R 1>-(PO 3) n ->; R 1> : H or 1-8C alkyl; n : 1-6; L : spacer ligand comprising radical R comprising q groups A; q : 1-6; A : carboxylate (asterisk-C(=O(a1)-O(a1))), phosphate (asterisk-P(=O(a1)(ORA1)-O(a1))), sulfonate (asterisk-S(=O(a1)(=O)-O(a1))), amine (asterisk-N(a1)(RA1)-(RA2)), imine (asterisk-C(RA1)=N(a1)-(RA2)), amide (asterisk-C=O(a1)-N(a1)(RA1)-(RA2)), carboxyamide (asterisk-C=O(a1)-NH 2(a1)), pyridine of formula (i), pyridine oxide of formula (ii) or imidazole of formula (iii); asterisk : attachment point of group A with the radical R; a1 : attachment point of group A with the metallic ion; RA1, RA2 : H, 1-12C alkyl, 2-12C alkene, 2-12C alkyne (optionally substituted), mono- or poly-cyclic aryl comprising 6-50C (optionally branched and/or branched); R : 1-12C alkyl, 2-12C alkene, 2-12C alkyne, mono- or poly-cyclic aryl (optionally fused) comprising 6-50C, mono- or poly-cyclic heteroaryl (optionally fused) comprising 1-50C, organic radical comprising a metallic element comprising ferrocene, porphyrin, phthalocyanine or schiff base (RX1RX2-C=N-RX3) (all optionally substituted by one or more R 2>groups comprising 1-10C alkyl, 2-10C alkene, 2-10C alkyne, 3-10C cycloalkyl, 1-10C heteroalkyl, 1-10C haloalkyl, 6-10C aryl, 3-10C heteroaryl, 5-20C heterocyclic, 1-10C alkyl-6-10C aryl, 1-10C alkyl-3-10C heteroaryl, 1-10C alkoxy, 6-10C aryloxy, 3-10C heteroalkoxy, 3-10C heteroaryloxy, 1-10C alkylthio, 6-10C arylthio, 1-10C heteroalkylthio, 3-10C heteroarylthio, F, Cl, Br, I, -NO 2, -CN, -CF 3, -CH 2CF 3, -CHCl 2, -OH, -CH 2OH, -CH 2CH 2OH, -NH 2, -CH 2NH 2, -NHCOH, -COOH, -CONH 2, SO 3H, -CH 2SO 2CH 3, -PO 3H 2, -B 1>(ORG1) 2or GR(G1) function); G : -O-, -S-, -NR(G2)-, -OC(=O)-, -S(=O)-, -SO 2-, -C(=O)O-, -C(=O)NR(G2)-, -OC(=O)-, NR(G2)C(=O)-, -OC(=O)O-, -OC (=O)NR(G2)-, -NR(G2)C(=O)O-, -NR(G2)C(=O)NR(G2)-, -C(=S)-, -C(=S)S-, -SC(=S)-, -SC(=S)S-, -C(=NR(G2))-, -C(=NR(G2))O-, -C(=NR(G2))NR(G3)-, -OC(=NR(G2))-, NR(G2)C(=NR(G3))-, -NR(G2)SO 2-, -NR(G2)SO 2NR(G3)-, -NR(G2)C(=S)-, SC(=S)NR(G2)-, -NR(G2)C(=S)S-, -NR(G2)C(=S)NR(G2)-, -SC(=NR(G2))-, -C(=S)NR(G2)-, -OC(=S)NR(G2)-, -NR(G2)C(=S)O-, -SC(=O)NR(G2)-, -NR(G2)C(=O)S-, -C(=O)S-, -SC(=O)-, -SC(=O)S-, -C(=S)O-, -OC(=S)-, -OC(=S)O- or -SO 2NR(G2)-; RX1, RX2 : H, 1-12C alkyl, 2-12C alkene, 2-12C alkyne (all optionally substituted) or mono- or poly-cyclic aryl comprising 6-50C (optionally branched and substituted); RX3 : 1-12C alkyl, 2-12C alkene, 2-12C alkyne (all optionally substituted) or mono- or poly-cyclic aryl comprising 6-50C (optionally branched and substituted); either R(G1), R(G2), R(G3) : H, halo, 1-12C alkyl, 1-12C heteroalkyl, 2-10C alkene, 2-10C alkyne (all optionally substituted), 6-10C aryl, 3-10C heteroaryl, 5-10C heterocycle, 1-10C alkyl-6-10C aryl or 1-10C alkyl-3-10C heteroaryl (all optionally substituted); or NR(G1)R(G2) : heterocycle or heteroaryl (both optionally substituted). An independent claim is included for the preparation of the solid. [Image].
Inventors:
Orca Hada Cortez, Patricia
Ferrei, Gerard
Sale, Christian
Gref, luxandra
Coob rule, Patrick
Ferrei, Gerard
Sale, Christian
Gref, luxandra
Coob rule, Patrick
Application Number:
JP2010527490A
Publication Date:
February 05, 2014
Filing Date:
October 01, 2008
Export Citation:
Assignee:
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE(CNRS)
UNIVERSITE DE VERSAILLES-SAINT-QUENTIN-EN-YVELINES
UNIVERSITE DE VERSAILLES-SAINT-QUENTIN-EN-YVELINES
International Classes:
A61K9/20; A61K8/19; A61K8/20; A61K8/23; A61K8/24; A61K8/25; A61K8/29; A61K8/34; A61K8/35; A61K8/362; A61K8/368; A61K8/41; A61K8/46; A61K8/49; A61K8/55; A61K8/60; A61K31/138; A61K31/185; A61K31/337; A61K31/675; A61K31/7068; A61K31/7072; A61K39/395; A61K47/02; A61K47/04; A61K47/12; A61K47/16; A61K47/22; A61K47/24; A61K47/26; A61K47/32; A61K47/34; A61K47/36; A61K47/38; A61K47/42; A61K49/00; A61K51/00
Other References:
HORCAJADA, PATRICIA ET AL,ANGEWANDTE CHEMIE, INTERNATIONAL EDITION,2006年,45(36),p.5974-5978
Erjola Shehu et al,Design and synthesis of new extended metal organic frameworks (MOFs),ABSTRACTS, 56TH SOUTHEAST REGIONAL MEETING OF THE AMERICAN CHEMICAL SOCIETY,2004年,URL,http://acs.confex.com/acs/56serm/techprogram/P13829.HTM
Ferey, G. et al,Science,2005年,309(5743),p.2040-2042
Erjola Shehu et al,Design and synthesis of new extended metal organic frameworks (MOFs),ABSTRACTS, 56TH SOUTHEAST REGIONAL MEETING OF THE AMERICAN CHEMICAL SOCIETY,2004年,URL,http://acs.confex.com/acs/56serm/techprogram/P13829.HTM
Ferey, G. et al,Science,2005年,309(5743),p.2040-2042
Attorney, Agent or Firm:
Hironobu Onda
Makoto Onda
Atsushi Honda
Makoto Onda
Atsushi Honda