Title:
配位子濃度の減少および水抽出を利用した脂肪族1,3-ジオールの合成
Document Type and Number:
Japanese Patent JP2005517700
Kind Code:
A
Abstract:
This invention is a process for synthesizing aliphatic 1,3-diols in one step by hydroformylation and hydrogenation of oxirane, carbon monoxide, and hydrogen employing a catalyst comprising a cobalt carbonyl compound and a cocatalyst metal compound ligated with a ligand in a ligand to cocatalyst metal atom molar ratio in the range of 0.2:1.0 to 0.6:1.0, optionally in the presence of a promoter, where recovery of product is preferably accomplished via water extraction of a diol rich phase from the bulk reaction mixture. The process modifications can, particularly in combination, be beneficial with respect to product recovery, catalyst recycle, and overall economics of a one-step process for producing aliphatic 1,3-diols.
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Inventors:
Allen, Kevin Dale
Juan Pedro, Arhansett
Nifton, Jiyon Frederick
Powell, Joseph Brown
Throw, Lynn Henry
Wader, paul richard yard
Juan Pedro, Arhansett
Nifton, Jiyon Frederick
Powell, Joseph Brown
Throw, Lynn Henry
Wader, paul richard yard
Application Number:
JP2003567855A
Publication Date:
June 16, 2005
Filing Date:
February 12, 2003
Export Citation:
Assignee:
Ciel International Research Mart Shats Pay BV
International Classes:
B01J31/18; B01J31/20; B01J31/24; C07B61/00; C07C29/16; C07C31/20; B01J31/28; (IPC1-7): C07C29/16; B01J31/24; C07C31/20
Attorney, Agent or Firm:
Yoshio Kawaguchi
Akio Ichiiri
Makoto Ono
Katsuma Osaki
Mitsuaki Tsubokura
Akio Ichiiri
Makoto Ono
Katsuma Osaki
Mitsuaki Tsubokura