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Title:
【発明の名称】漂白剤の活性化
Document Type and Number:
Japanese Patent JPH0765074
Kind Code:
B2
Abstract:
Novel bleach and oxidation catalysts, a method of bleaching substrates using these catalysts and bleaching (detergent) compositions containing the catalysts are reported. The catalysts are a manganese-based co-ordination complex of the general formula : [LnMnmXp] Yq wherein Mn is manganese in the IV-oxidation state; n and m are independent integers from 2-8; X represents a co-ordination or bridging species; p is an integer from 0-32; Y is a counter-ion, the type of which is dependent on the charge z of the complex which can be positive, zero or negative; q = z/[charge Y]; and L is a ligand which is an organic molecule containing a number of hetero-atoms selected from N, P, O, and S, which co-ordinates via all or some of its hetero-atoms and/or carbon atoms to the Mn<(IV)>-center(s), which latter are anti-ferromagnetically coupled.

Inventors:
Thomas Rauis F Huabre
Ronald Hagie
Karin Juan del Helmura de Makel
Ian Hippolytes Cook
Rudolph Johann Martens
Ton Swartov
Marten Robert P. Juan Fried
Application Number:
JP21812991A
Publication Date:
July 12, 1995
Filing Date:
May 21, 1991
Export Citation:
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Assignee:
Unilever Namrose Rose Bennaught Sharp
International Classes:
B01J31/28; B01J31/32; C07B61/00; C07D255/02; C07D341/00; C07F13/00; B01J31/18; C11D3/39; C11D3/395; C11D7/54; D06L3/00; D06L3/02; (IPC1-7): C11D7/54; B01J31/28; B01J31/32; C07B61/00; C11D3/395; D06L3/02
Attorney, Agent or Firm:
Yoshio Kawaguchi (2 outside)