Title:
【発明の名称】ニトログアニジン誘導体の製法
Document Type and Number:
Japanese Patent JP2002506866
Kind Code:
A
Abstract:
A process for the production of a compound of formula (I)whereinR1 is hydrogen or C1-C4-alkyl;R2 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or a radical -CH2B;A is selected from the group consisiting of 2-chloropyrid-5-yl, tetrahydrofuran-3 -yl, 5-methyl-tetrahydrofuran-3-yl or 2-chlorothiazol-5-yl; andB is phenyl, 3-pyridyl or thiazolyl, which are optionally substituted by one to three substituents selected from the group consisting of C1-C3-alkyl, C1-C3-halogenalkyl, cyclopropyl, halogencyclopropyl, C2-C3-alkenyl, C2-C3-alkinyl, C1-C3-alkoxy, C2-C3-halogenalkenyl, C2-C3-halogenalkinyl, C1-C3-halogenalkoxy, C1-C3-alkylthio, C1-C3-halogenalkylthio, allyloxy, propargyloxy, allylthio, propargylthio, halogenallyloxy, halogenallylthio, halogen, cyano or nitro;and optionally the possible E/Z isomers, E/Z isomeric mixtures and/or tautomers thereof, respectively in free form or in salt form;characterised in that a compound of formula (II)whereinR1, R2 and A have the same significances as in formula (I), andX is O or S;is hydrolysed with a strong acid at a pH below 2; at a temperature between 50 and 100° C; and in a solvent selected from the group consisting of water, alcohols, ethers or mixtures thereof. The compounds of formula (I) are suitable for the preparation of pesticides.
Inventors:
My enfish, peter
La Porte, Thomas
Henry Szepanski
La Porte, Thomas
Henry Szepanski
Application Number:
JP2000536715A
Publication Date:
March 05, 2002
Filing Date:
March 17, 1999
Export Citation:
Assignee:
Novartis Actien Gezel Shaft
International Classes:
C07D213/61; C07D213/89; C07D273/04; C07D277/32; C07D285/34; C07D307/14; C07D413/06; C07D277/20; (IPC1-7): C07D213/61; C07D213/89; C07D273/04; C07D277/32; C07D285/34; C07D307/14; C07D413/06
Attorney, Agent or Firm:
Takashi Ishida (4 others)