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Title:
MANUFACTURE OF ALPHA, ALPHA-DIFLUOROALKOXY OR ALPHA, ALPHA-DIFLUOROALKYLTHIOPHENYLKETONE
Document Type and Number:
Japanese Patent JPS58124732
Kind Code:
A
Abstract:
A process for the preparation of alpha , alpha -difluoroalkoxy or alpha , alpha -difluoroalkylthiophenyl ketones, in which a polyhaloalkoxybenzene or a polyhaloalkylthiobenzene is reacted with a carboxylic acid, a precursor or a derivative of this acid in the presence of boron trifluoride in such an amount that the absolute pressure of the boron trifluoride within the reaction vessel exceeds 1 bar, and in the presence of hydrofluoric acid as a solvent. The resultant products are useful as intermediates in the synthesis of compounds having phytosanitary (e.g., herbicidal) or pharmaceutical activity.

Inventors:
MISHIERU DEBOWA
Application Number:
JP11087882A
Publication Date:
July 25, 1983
Filing Date:
June 29, 1982
Export Citation:
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Assignee:
RHONE POULENC SPEC CHIM
International Classes:
B01J27/00; C07B61/00; C07C45/00; C07C45/46; C07C49/84; C07C67/00; C07C313/00; C07C319/20; C07C323/22; (IPC1-7): B01J27/12; C07C45/46; C07C49/84; C07C149/32
Attorney, Agent or Firm:
Motohiro Kurauchi