Title:
分子酸素又は空気を使用した酸化のための触媒としての金属錯体化合物の使用
Document Type and Number:
Japanese Patent JP2006504516
Kind Code:
A
Abstract:
Use, as a catalyst for oxidation reactions using molecular oxygen and/or air, of at least one metal complex compound of formula (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge of Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; -COOR12 or -SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; -SR13, -SO2R13 or -OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; -NR14R15; -(C1-C6alkylene)-NR14R15; -N(+)R14R15R16; -(C1-C6alkylene)-N(+)R14R15R16; -N(R13)-(C1-C6alkylene)-NR14R15; -N[(C1-C6alkylene)-NR14R15]2; -N(R13)-(C1-C6alkylene)-N(+)R14R15R16; -N[(C1-C6alkylene)-N(+)R14R15R16]2; -N(R13)-N-R14R15 or -N(R13)N''R14R15R16, wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15, together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms. [LnMemXp]zYq (1)
Inventors:
Weprecht, Torsten
Schlinglov, Gunther
Kisia, Juntao
Heinz, Wu
Schneider, Albert
Dubus, Marie-Josie
Bachmann, Frank
Hasencamp, Menno
Donna Har, Joseph
Schlinglov, Gunther
Kisia, Juntao
Heinz, Wu
Schneider, Albert
Dubus, Marie-Josie
Bachmann, Frank
Hasencamp, Menno
Donna Har, Joseph
Application Number:
JP2004547538A
Publication Date:
February 09, 2006
Filing Date:
October 21, 2003
Export Citation:
Assignee:
Ciba Specialty Chemicals Holding Inc.
International Classes:
B01J31/22; C11D3/16; C11D3/39; C11D3/395; C07D213/22; C07D213/61; C07D213/68; C07D213/74; C07D213/77; C07D213/79; C07F13/00
Attorney, Agent or Firm:
Calyx
Miyazaki Yoshio
Mitsuo Tateishi
Toshio Nakamura
Tsutomu Kato
Kaoru Onozuka
High Masahiro
Yusuke Murakoshi
Tomoaki Komiya
Miyazaki Yoshio
Mitsuo Tateishi
Toshio Nakamura
Tsutomu Kato
Kaoru Onozuka
High Masahiro
Yusuke Murakoshi
Tomoaki Komiya