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Title:
水分子内包配位高分子金属錯体化合物
Document Type and Number:
Japanese Patent JP4882762
Kind Code:
B2
Abstract:

To provide a coordinated polymer-metal complex compound containing a water molecule that exhibits enhanced proton-conductivity at room temperature.

The unidimensional linear coordinated polymer metal complex compound containing a water molecule has such a composition that one unit thereof is represented by the general formula: [MA-2ä(C4H2N2)-(COOH)2}]-nH2O, and is composed of a metal ion MA having a tetracoordinate planar structure, 2,3-pyrazine dicarboxylic acid and a water molecule as crystal water. The tridimensional coordinated polymer metal complex compound containing a water molecule has such a composition that one unit thereof is represented by the general formula: [MB-2ä(C4H2N2)-(COOH)2}-2H2O]-H2O, and is composed of a metal ion MB having a hexacoordinate octahedron structure, 2,3-pyrazine dicarboxylic acid, a water molecule as a ligand and a water molecule in a pore.

COPYRIGHT: (C)2008,JPO&INPIT


Inventors:
Kodama Tomoki
Application Number:
JP2007016749A
Publication Date:
February 22, 2012
Filing Date:
January 26, 2007
Export Citation:
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Assignee:
TOYOTA JIDOSHA KABUSHIKI KAISHA
International Classes:
C08G79/00
Domestic Patent References:
JP2004196594A
JP9324006A
JP2007204446A
JP9227572A
JP2004323455A
JP2004031174A
JP2004031173A
JP2006342249A
Other References:
Canadian Journal of Chemistry,1996年,Vol.74, No.3,P.433-P444
Inorganica Chimica Acta,1977年,Vol.26,P.247-P.250
Inorganica Chimica Acta,2004年,Vol.357,No.5,P.1593-P.1597
Attorney, Agent or Firm:
Atsushi Aoki
Takashi Ishida
Tetsuji Koga
Nagasaka Tomoyasu
Hiroshi Kamematsu



 
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