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Title:
A base generator, a base reactive composition containing the base generator, and a base generation method.
Document Type and Number:
Japanese Patent JP6332870
Kind Code:
B2
Abstract:
It is a subject of the present invention to provide a base generator which has high solubility to general-purpose organic solvents, can dissolve directly into a base-reactive compound, such as an epoxy-based compound, further is provided with both performance of high heat resistance and low nucleophilicity, and generates a strong base, a base-reactive composition comprising the base generator and a base-reactive compound, as well as a method for generating a base, etc. The present invention relates to a compound represented by the general formula (A), a base generator comprising the compound, a base-reactive composition which comprises the base generator and a base-reactive compound, as well as a method for generating a base, etc. (wherein R 1 to R 5 each independently represent a hydrogen atom; an alkyl group; an aryl group which may have a substituent; or an arylalkyl group which may have a substituent, R 6 represents a hydrogen atom; an alkyl group which may have a substituent; an alkenyl group; an alkynyl group; an aryl group which may have a substituent; or an arylalkyl group which may have a substituent, R 7 represents a hydrogen atom; an alkyl group which may have an amino group; an aryl group which may have a substituent; or an arylalkyl group which may have a substituent, and Z - represents an anion derived from a carboxylic acid having a specific structure.)

Inventors:
Nobuhiko Sakai
Yasuyuki Yaba
Koji Arimitsu
Application Number:
JP2015524100A
Publication Date:
May 30, 2018
Filing Date:
June 25, 2014
Export Citation:
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Assignee:
FUJIFILM Wako Pure Chemical Industries, Ltd.
Tokyo University of Science
International Classes:
C07C59/84; C07C65/28; C07C279/26; C07D209/48; C07D311/86; C09K3/00
Domestic Patent References:
JP46018018A
JP48044225A
JP4602068A
JP2010024369A
Foreign References:
US3261809
FR2796940A1
Other References:
GLASOVAC, Zoran et al.,SYNLETT,2013年,24,2540-2544
GELBARD, Georges et al.,Terahedron Letters,1998年,39,2743-2746
GELBARD, Georges et al.,Comptes Rendus de l'Academie des Sciences, Serie llc, Chimie,2000年,3(7),563-567
RACZYNSKA, E. D. et al.,Journal of Physical Organic Chemistry,2001年,14,25-34