Title:
遷移金属超微粒子からなるクロスカップリング用触媒およびそれを用いたクロスカップリング法
Document Type and Number:
Japanese Patent JP5700624
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide a catalyst for cross coupling dramatically improved in catalyst activity compared with a conventional catalyst, capable of making best use of a metal surface on a catalyst efficiently in a cross coupling reaction by using transition metal ultrafine particles comprising a transition metal and a coordinating organic solvent, which does not include a component such as a ligand, protective agent, or polymer, and to provide a cross coupling reaction using the catalyst.SOLUTION: There are disclosed the catalyst for the cross coupling reaction comprising the transition metal ultrafine particles including at least one transition metal selected from a group consisting of group 8-11 transition metals and the coordinating organic solvent, and moreover, the cross coupling reaction using the catalyst for the cross coupling reaction.
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Inventors:
Yasushi Oto
Kawasaki Hideya
Megumi Hyotanishi
Hiroko Yamamoto
Kawasaki Hideya
Megumi Hyotanishi
Hiroko Yamamoto
Application Number:
JP2010139638A
Publication Date:
April 15, 2015
Filing Date:
June 18, 2010
Export Citation:
Assignee:
Kansai University
International Classes:
B01J23/44; B01J35/02; B01J37/08; B01J37/34; C07C2/82; C07C15/16; C07C17/26; C07C22/08; C07C25/18; C07C41/30; C07C43/205; C07C45/68; C07C49/217; C07C67/343; C07C69/618; C07C69/65; C07C69/736; C07C201/12; C07C205/06; C07D307/48; C07D307/54; C07D333/10; C07D333/24
Domestic Patent References:
| JP2000256707A | ||||
| JP2006043697A | ||||
| JP2002515326A |
Other References:
M. B. THATHAGAR et al.,Copper-Catalyzed Suzuki Cross-Coupling Using Mixed Nanocluster Catalysts,J. Am. Chem. Soc.,2002, 124, 11858-11859.,See also Supporting Information.
H. KAWASAKI et al.,Stability of the DMF-Protected Au Nanoclusters: Photochemical, Dispersion, and Thermal Properties,Langmuir,2010, 26, 5926-5933.,Published on Web 12/11/2009.
X. LIU et al.,Surfactant-Free Synthesis and Functionalization of Highly Fluorescent Gold Quantum Dots,J. Phys. Chem. C,2008, 112, 10778-10783.
I. PASTORIZA-SANTOS et al.,Reduction of silver nanoparticles in DMF. Formation of monolayers and stable colloids,Pure Appl. Chem.,2000, 72, 83-90.
H. KAWASAKI et al.,Stability of the DMF-Protected Au Nanoclusters: Photochemical, Dispersion, and Thermal Properties,Langmuir,2010, 26, 5926-5933.,Published on Web 12/11/2009.
X. LIU et al.,Surfactant-Free Synthesis and Functionalization of Highly Fluorescent Gold Quantum Dots,J. Phys. Chem. C,2008, 112, 10778-10783.
I. PASTORIZA-SANTOS et al.,Reduction of silver nanoparticles in DMF. Formation of monolayers and stable colloids,Pure Appl. Chem.,2000, 72, 83-90.
Attorney, Agent or Firm:
Samejima Mutsumi
Kyousei Tamura
Nagatoshi Shinagawa
Yasushi Morimoto
Kyousei Tamura
Nagatoshi Shinagawa
Yasushi Morimoto