Title:
A guest compound intension polymer metal complex crystal, its manufacturing method, a manufacturing method of the sample for crystal structure analyses, and a molecular structure deciding method of an organic compound
Document Type and Number:
Japanese Patent JP5969616
Kind Code:
B2
Abstract:
The present invention is: a guest-compound-enveloping polymer-metal-complex crystal characterized by at least one selected from an aliphatic hydrocarbon, an alicyclic hydrocarbon, an ether, an ester, an aromatic hydrocarbon, a halogenated hydrocarbon, and a nitrile being enveloped as a guest compound (A) in the minute pores or the like of a polymer-metal complex that contains a metal ion as a central metal and a ligand having at least two ligating sites, has a 3D network structure formed by the ligand being ligated to the metal ion, and has the minute pores or the like regularly arranged three-dimensionally within the 3D network structure, the amount of the guest compound (A) present within the minute pores or the like being at least 60 mol% of all the guest compounds enveloped in the minute pores or the like; a method for producing the guest-compound-enveloping polymer-metal-complex crystal; a method for preparing a crystal structure analysis sample using the crystal; and a method for determining the molecular structure of an organic compound using the sample obtained by said method.
Inventors:
Makoto Fujita
Inokuma Yasuhide
Shota Yoshioka
Ayako Ayako
Inokuma Yasuhide
Shota Yoshioka
Ayako Ayako
Application Number:
JP2014534207A
Publication Date:
August 17, 2016
Filing Date:
March 07, 2013
Export Citation:
Assignee:
Japan Science and Technology Agency
International Classes:
C30B29/54; C07C7/14; C07C7/152; C07C9/15; C07C13/18; C07C13/47; C07C15/06; C07C17/392; C07C19/041; C07C25/08; C07C41/40; C07C43/04; C07C46/10; C07C49/403; C07C50/10; C07C67/52; C07C69/14; C07C253/32; C07C255/03; C07C255/50; C07D307/92; C07D311/30; C07D333/18; C07D401/14; C30B7/06
Domestic Patent References:
| JP2006188560A | ||||
| JP2008247884A |
Foreign References:
| WO2011062260A1 |
Other References:
M. KAWANO et al.,Direct observation of crystalline-state guest exchange in coordination networks,Coordination Chemistry Reviews,2007年,Vol. 251,p. 2592-2605
Attorney, Agent or Firm:
Haruhito Oishi
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