Title:
配位子成分、関連する反応生成物、活性化反応生成物、ヒドロシリル化触媒、及び配位子成分を含むヒドロシリル化硬化性組成物、及びそれを調製するための関連する方法
Document Type and Number:
Japanese Patent JP6824189
Kind Code:
B2
Abstract:
A ligand component is formed according to formula (1):R12P—X—N═C(R2)—Y, wherein R1 is Ph or Cyc or a C1-C20 substituted or unsubstituted ailkyl group; each Ph is a substituted or unsubstituted phenyl group; each Cyc is a substituted or unsubstituted cycloalkyl group; X is an unsubstituted arylene or a C2-C3 substituted or unsubstituted alkylene; R2 is H, methyl or Ph; and Y N is pyridyl, 6-phenylpyridyl or 6-methylpyridyl; with the proviso that when X is a C2 substituted or unsubstituted alkylene and Y is pyridyl, R2 is methyl or Ph. A reaction product including the ligand component and a metal precursor is prepared by combining the ligand component with the metal precursor. An activated reaction product is formed by activating the reaction product as a hydrosilylation catalyst.
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Inventors:
Aswini Dash
Thomas B. Louchifs
One-Lee Chu
Ryan Jay Gilbert-Wilson
Thomas B. Louchifs
One-Lee Chu
Ryan Jay Gilbert-Wilson
Application Number:
JP2017551996A
Publication Date:
February 03, 2021
Filing Date:
November 13, 2015
Export Citation:
Assignee:
Dow Silicones Corporation
The Board of Trusties of the University of Illinois
The Board of Trusties of the University of Illinois
International Classes:
C07F19/00; C08K5/49; C08K5/54; C08L83/07
Domestic Patent References:
| JP2014532045A | ||||
| JP2014531446A | ||||
| JP2014527970A | ||||
| JP2014532044A | ||||
| JP2014528940A | ||||
| JP2014524428A |
Foreign References:
| WO2014201082A1 | ||||
| WO2007013931A1 | ||||
| CN104513146A |
Other References:
Simon Doherty, Julian G. Knight, Tom H. Scanlan, Mark R. J. Elsegood, William Clegg,Iminophosphines: synthesis, formation of 2,3-dihydro-1H-benzo[1,3]azaphosphol-3-ium salts and N-(pyridin-2-yl)-2-diphenylphsphinoylaniline, coordination chemistry and applications in platinum group catalyzed Suzuki coupling reactions and hydrosilylations,Journal of Organometallic Chemistry,2002年,Vol. 650,pp. 231-248
Toshiaki Morimoto, Yoichi Yamaguchi, Masato Suzuki and Akihito Saitoh,Enantioselective copper-catalyzed conjugate addition of diethylzinc to enones using new chiral P,N ligands composed of (S)-2-alkyl-2-aminoethylphosphines and α-substituted pyridines,Tetrahedron Letters,2000年,Vol. 41,pp. 10025-10029
Fu-Bin Han, Yu-Liang Zhang, Xiu-Li Sun, Bao-Guo Li, Yang-Hui Guo, and Yong Tang,Synthesis and Characterization of Pyrrole-imine [N-NP] Nickel(II) and Palladium(II) Complexes and Their Applications to Norbornene Polymerization,Organometallics,2008年,Vol. 27,pp. 1924-1928
Fu-Zhong Han, Fu-Lin Zhu, Ya-Hui Wang, Yuan Zou, Xin-Hu Hu, Song Chen, and Xiang-Ping Hu,Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds,Organic Letters,2014年,Vol. 16,pp. 588-591
Ryan Gilbert-Wilson, Wan-Yi Chu, and Thomas B. Rauchfuss,Phosphine-Iminopyridines as Platforms for Catalytic Hydrofunctionalization of Alkenes,Inorganic Chemistry,2015年,Vol. 54,pp. 5596-5603
Toshiaki Morimoto, Yoichi Yamaguchi, Masato Suzuki and Akihito Saitoh,Enantioselective copper-catalyzed conjugate addition of diethylzinc to enones using new chiral P,N ligands composed of (S)-2-alkyl-2-aminoethylphosphines and α-substituted pyridines,Tetrahedron Letters,2000年,Vol. 41,pp. 10025-10029
Fu-Bin Han, Yu-Liang Zhang, Xiu-Li Sun, Bao-Guo Li, Yang-Hui Guo, and Yong Tang,Synthesis and Characterization of Pyrrole-imine [N-NP] Nickel(II) and Palladium(II) Complexes and Their Applications to Norbornene Polymerization,Organometallics,2008年,Vol. 27,pp. 1924-1928
Fu-Zhong Han, Fu-Lin Zhu, Ya-Hui Wang, Yuan Zou, Xin-Hu Hu, Song Chen, and Xiang-Ping Hu,Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds,Organic Letters,2014年,Vol. 16,pp. 588-591
Ryan Gilbert-Wilson, Wan-Yi Chu, and Thomas B. Rauchfuss,Phosphine-Iminopyridines as Platforms for Catalytic Hydrofunctionalization of Alkenes,Inorganic Chemistry,2015年,Vol. 54,pp. 5596-5603
Attorney, Agent or Firm:
Yasuhiko Murayama
Shinya Mitsuhiro
Tatsuhiko Abe
Shinya Mitsuhiro
Tatsuhiko Abe