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Title:
A manufacturing method of 4-alkanoloxy 2-methyl butanoic acid
Document Type and Number:
Japanese Patent JP6209776
Kind Code:
B2
Abstract:
The present invention relates to an improved process for the production of 4-alkanoyloxy-2-methylbutanoic acid, as well as to the use of such compounds in organic syntheses, especially in processes forming intermediates (building blocks) for the synthesis of organic compounds comprising isoprene (isoterpene) units, such as β-carotene or other carotenoids (e.g. canthaxanthin, zeaxanthin or astaxanthin) or as vitamin E or vitamin A as well as other structurally similar compounds.

Inventors:
Bonras, Werner
Schutz, Jean
Wustenberg, Bettina
Netchel, thomas
Application Number:
JP2015515511A
Publication Date:
October 11, 2017
Filing Date:
June 05, 2013
Export Citation:
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Assignee:
DSM IP ASSETS B.V.
International Classes:
C07C67/29; B01J27/053; B01J27/055; B01J27/10; B01J27/122; B01J27/128; B01J31/04; C07C69/14
Domestic Patent References:
JP62033133A
JP57156442A
JP58140038A
JP8143499A
JP4198149A
JP2011246426A
JP2000063373A
Foreign References:
US4665091
CN101391948A
US3649672
WO2012098067A1
Other References:
Yamada, Yasuhiro; Seo, Chull Won; Okada, Hirosuke,Oxidation of acyclic terpenoids by Corynebacterium sp,Applied and Environmental Microbiology,1985年,49(4),960-3
El Ali, Bassam; Alper, Howard,Formic acid-palladium acetate-1,4-bis(diphenylphosphino)butane: an effective catalytic system for regioselective hydrocarboxylation of simple and functionalized olefins,Journal of Molecular Catalysis,1992年,77(1),7-13
Ohta, Tetsuo; Takaya, Hidemasa; Kitamura, Masato; Nagai, Katsunori; Noyori, Ryoji,Asymmetric hydrogenation of unsaturated carboxylic acids catalyzed by BINAP-ruthenium(II) complexes,Journal of Organic Chemistry,1987年,52(14),3174-6
Lin, S.; Yan, L.; Liu, P.,Carboxylic Acids: Synthesis from aldehydes, ketones, and derivatives (including enol ethers),Science of Synthesis,2006年,20a,93-135
Klement, Ingo; Lutjens, Henning; Knochel, Paul,Transition metal catalyzed oxidations in perfluorinated solvents,Angewandte Chemie, International Edition in English,1997年,36(13/14),1454-1456
Stevens, Robert V.; Beaulieu, Normand; Chan, Wing Hong; Daniewski, Andrej R.; Takeda, Takeshi; Waldner, Adrian; Williard, Paul G.; Zutter, Ulrich,Studies on the synthesis of vitamin B12. 4,Journal of the American Chemical Society ,1986年,108(5),1039-49
Attorney, Agent or Firm:
Ikeda adult
Yoshinori Shimizu
Junichiro Sakamaki