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Title:
The metal complex in which at least N-amino friend Jinato distribution has a child
Document Type and Number:
Japanese Patent JP5964865
Kind Code:
B2
Abstract:
The invention relates to new metal complexes having N-aminoamidinate ligands, more particularly metal complexes having N,N′-bis(dimethylamino)acetamidinate, N,N′-bis(dimethylamino)formamidinate, N-dimethylaminoacetamidinate or N-dimethylamino-N′-isopropyl-acetamidinate ligands as well as to their preparation and use. The metal complexes are characterized by a five-membered chelate ring. The metal complexes are formed with the metals from the main groups of the PTE, but also with transition-group elements such as tantalum (Ta), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu) or zinc (Zn), and also with precious metals such as palladium (Pd). The complexes of the invention find use as precursors for the preparation of functional layers by means of gas-phase thin-film processes such as CVD, MO-CVD and ALD. Additionally they may be used as catalysts for olefin hydroamination and for olefin polymerization.

Inventors:
Jork Thundermeyer
Wolf Schorn
Ralph Karsh
Application Number:
JP2013554862A
Publication Date:
August 03, 2016
Filing Date:
February 20, 2012
Export Citation:
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Assignee:
Umicore AG & Co.KG
International Classes:
C07F1/02; C07F1/06; C07F5/00; C07F5/06; C07F7/00; C07F7/02; C07F7/28; C07F9/00; C07F15/00; C07F15/04; C08F4/06; C23C16/34
Domestic Patent References:
JP2004002305A
JP2004002306A
JP2003531934A
JP2004506745A
JP2008536800A
Foreign References:
US4544759
Other References:
SHAPIRO,P.J. et al,Inorganic Chemistry,1990年,Vol.29,pp.4560-4565
CRIMMIN,M.R. et al,Dalton Transactions,2011年,Vol.40,pp.514-522,Published 25 Nov. 2010
Attorney, Agent or Firm:
Yasuhiko Murayama
Masatake Shiga
Takashi Watanabe
Shinya Mitsuhiro