Title:
The metal complex in which at least Distribution contains a child and at least the Distribution contains a child, and the reaction using the metal complex
Document Type and Number:
Japanese Patent JP6218153
Kind Code:
B2
Abstract:
A hydrogen transfer reaction may be more efficiently promoted by using a metal complex represented by Formula (2):
(wherein, R 1 to R 8 are the same or different, and each represents a hydrogen atom, a substituted or unsubstituted alkyl group or the like; or wherein; R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 4 and R 5 , and R 5 and R 6 are respectively bonded to each other to form a bivalent hydrocarbon group;
R 9 are the same or different, and each represents an alkyl group or cycloalkyl group;
M is ruthenium (Ru) or the like;
X is a ligand; and
n is 0, 1 or 2). More specifically, the metal complex enables a hydrogenation reaction of various substrates having a stable carbonyl group or the like to be advanced with a high yield under mild conditions.
Inventors:
Susumu Saito
Ryoji Noyori
Takashi Miura
Masayuki Naruto
Kazuki Iida
Takada Yuki
Katsuaki Toda
Futata Sota
Agrawal Santosh
Lee Sung Nock
Ryoji Noyori
Takashi Miura
Masayuki Naruto
Kazuki Iida
Takada Yuki
Katsuaki Toda
Futata Sota
Agrawal Santosh
Lee Sung Nock
Application Number:
JP2015504341A
Publication Date:
October 25, 2017
Filing Date:
March 04, 2014
Export Citation:
Assignee:
Nagoya University
International Classes:
C07F9/58; B01J31/24; C07C29/156; C07C29/157; C07C31/04; C07C31/20; C07C31/24; C07C33/22; C07C209/50; C07C211/03; C07C211/27; C07C213/00; C07C215/08; C07C215/28; C07D207/33; C07D307/33; C07F5/02; C07F9/6509
Domestic Patent References:
| JP2011037809A | ||||
| JP2010215604A |
Foreign References:
| WO2012102247A1 | ||||
| US20120253042 |
Other References:
Ziessel, R.,A new family of aromatic polyimine chelates substituted with two diphenylphosphines,Tetrahedron Letters,1989年,30(4),463-466
Langer, R. et al.,Stepwise metal-ligand cooperation by a reversible aromatization/deconjugation sequence in ruthenium,Chemistry - A European Journal,2013年 1月29日,19(10),3407-3414
Liu, X. et al.,Flexible Redox-Active Binuclear Macrocycles Formed via the Weak-Link Approach and Novel Hemilabile L,Inorganic Chemistry,2001年,40(13),2940-2941
Langer, R. et al.,Stepwise metal-ligand cooperation by a reversible aromatization/deconjugation sequence in ruthenium,Chemistry - A European Journal,2013年 1月29日,19(10),3407-3414
Liu, X. et al.,Flexible Redox-Active Binuclear Macrocycles Formed via the Weak-Link Approach and Novel Hemilabile L,Inorganic Chemistry,2001年,40(13),2940-2941
Attorney, Agent or Firm:
Patent Business Corporation Saegusa International Patent Office