Title:
An organic synthesis reaction which uses a mononuclear iron complex and it
Document Type and Number:
Japanese Patent JP6085892
Kind Code:
B2
Abstract:
Provided is a mononuclear iron complex that comprises an iron-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound.
In formula (1), R 1 -R 6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R 1 -R 3 and one of R 4 -R 6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.
Inventors:
Hideo Nagashima
Yusuke Sunada
Daisuke Tsutsumi
Toru Hashimoto
Koji Sakuta
Yusuke Sunada
Daisuke Tsutsumi
Toru Hashimoto
Koji Sakuta
Application Number:
JP2015502960A
Publication Date:
March 01, 2017
Filing Date:
February 26, 2014
Export Citation:
Assignee:
Kyushu University
Shin-Etsu Chemical Co., Ltd.
Shin-Etsu Chemical Co., Ltd.
International Classes:
C07F19/00; B01J23/745; C07C5/03; C07C5/05; C07C9/16; C07C13/10; C07C13/18; C07C15/073; C07C29/14; C07C33/34; C07C41/26; C07C43/23; C07C209/50; C07C211/27; C07C211/29; C07D223/04; C07F7/08
Domestic Patent References:
| JP2011045798A |
Other References:
FRANCIS et al.,Reactivity of μ-silanediyl iron carbonyl complexes with alkynes,INORGANIC CHEMISTRY,1982年,V21,P3099-3105,化合物8、化合物9(P3102, 右下欄「(eq 5)」)
SCHUBERT et al.,Investigations on the reactivity of the anionic silyl complexes [Fe(CO)3(PR3')SiR3],CHEMISCHE BERICHTE,1987年,V120,P1079-1085,化合物2、化合物3、化合物4(P1080、右欄(2)
SAKURAI et al.,h3-1-Silapropenyltricarbonyliron complexes,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,1976年,V98,P7453-7454,化合物2a、化合物2b(P7453 右欄)
SATO et al.,Alkoxyhydrosilanes as sources of silylene ligands: Novel approaches to transition metal-silylene com,CHEMISTRY LETTERS,2004年,V33,P868-869,化合物6(P869、右欄のScheme 2)
LEE et al.,From Tetragermacyclobutene to Tetragermacyclobutadiene Dianion to Tetragermacyclobutadiene Transitio,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011年,V133,P5103-5108,化合物5'(P5106、Figure 3)
TAKANASHI et al.,A (tetrasilacyclobutadiene)tricarbonyliron complex[{h4-(tBu2MeSi)4Si4}Fe(CO)3]: the silicon cousin o,ANGEWANDTE CHEMIE, INTERNATIONAL EDITION,2006年,V45,P3269-3272,化合物2a、化合物2b(P3270、左欄)
HEYN et al.,Coordinatively and electronically unsaturated tris(trimethylsilyl)silyl complexes of manganese and i,INORGANICA CHIMICA ACTA,2002年,V341,P91-98,化合物7(P97、左欄 (4))
SCHUBERT et al.,Investigations on the reactivity of the anionic silyl complexes [Fe(CO)3(PR3')SiR3],CHEMISCHE BERICHTE,1987年,V120,P1079-1085,化合物2、化合物3、化合物4(P1080、右欄(2)
SAKURAI et al.,h3-1-Silapropenyltricarbonyliron complexes,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,1976年,V98,P7453-7454,化合物2a、化合物2b(P7453 右欄)
SATO et al.,Alkoxyhydrosilanes as sources of silylene ligands: Novel approaches to transition metal-silylene com,CHEMISTRY LETTERS,2004年,V33,P868-869,化合物6(P869、右欄のScheme 2)
LEE et al.,From Tetragermacyclobutene to Tetragermacyclobutadiene Dianion to Tetragermacyclobutadiene Transitio,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011年,V133,P5103-5108,化合物5'(P5106、Figure 3)
TAKANASHI et al.,A (tetrasilacyclobutadiene)tricarbonyliron complex[{h4-(tBu2MeSi)4Si4}Fe(CO)3]: the silicon cousin o,ANGEWANDTE CHEMIE, INTERNATIONAL EDITION,2006年,V45,P3269-3272,化合物2a、化合物2b(P3270、左欄)
HEYN et al.,Coordinatively and electronically unsaturated tris(trimethylsilyl)silyl complexes of manganese and i,INORGANICA CHIMICA ACTA,2002年,V341,P91-98,化合物7(P97、左欄 (4))
Attorney, Agent or Firm:
Takashi Kojima
Saori Shigematsu
Katsunari Kobayashi
Takeshi Ishikawa
Saori Shigematsu
Katsunari Kobayashi
Takeshi Ishikawa