(P-P)配位されたフェロセニルジホスフィン配位子を有するルテニウム錯体、該錯体の製造方法、および均一系触媒での該錯体の使用

Japanese Patent JP5473900

B2

The invention relates to ruthenium complexes with a chiral ferrocenyldiphosphine ligand, wherein the ruthenium has the oxidation state (+II) and the chiral ferrocenyldiphosphine ligand has bidentate P-P coordination to the ruthenium. The ruthenium complexes are cyclic and with the ferrocenyldiphosphine ligand have an at least eight-membered ring. The ferrocenyldiphosphine ligands are selected from the group consisting of Taniaphos, Taniaphos-OH and Walphos ligands. A process for preparing the Ru complexes is described. The Rn complexes are used as catalysts for homogeneous asymmetric catalysis for preparing organic compounds.

WO/2004/005304	RUTHENIUM ANTICANCER COMPLEXES
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Albrecht Salzer
Angelino Doppiu
Nadine Langenscheid
Andreas Rivas-Eggplant
Ralph Karchi
Laurent Vinde
Stephanie Meirhofer

JP2010506852A

April 16, 2014

May 08, 2008

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Umicore AG & Co.KG

C07F17/02; B01J31/30; C07B53/00; C07C51/36; C07C53/126; C07B61/00; C07F15/00

JP2005528354A

WO2007005550A1
WO2006108562A1
WO2006067412A1

CAYUELA,E.,ET AL.,"Monocyclopentadienylhydride Derivatives of Ruthenium: Stereoselective Proton Transfer and Proton-Hydride Exchange in an Extremely Short Dihydrogen Bond",JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2004年 6月 9日,VOL.126,NO.22,PP.7049-7062
MOBERG,V.,ET AL.,"Unprecedented Enantioselectivity in a Cluster-Based Catalytic System",ORGANOMETALLICS,2007年 8月13日,VOL.26,NO.17,PP.4090-4093
UMICORE PRODUCT LIST,ドイツ,UMICORE AG & CO.,2008年 7月18日

Toshio Yano
Takuya Kuno
Takahashi
Kimihiro Hoshi
Hiroyasu Ninomiya
Einzel Felix-Reinhard

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