PATENT Attorney Docket No.: 27178.106PCT ACRYLIC STRUCTURAL ADHESIVES AND METHODS FOR MAKING SAME CROSS-REFERENCE TO RELATED APPLICATIONS [0001] This application claims the benefit of U.S. Provisional Patent Application No. 63/414,945, filed October 11, 2022, which is incorporated herein by reference in its entirety. BACKGROUND Field [0002] Provided herein are acrylic structural adhesives that are made from high vinyl content styrene-butadiene-styrene block copolymers and acrylate monomers, such as methyl methacrylate. Description of the Related Art [0003] Structural adhesives are substances that adhere or fasten together structural elements to produce high modulus, high strength, permanent chemical bonds. They are good alternatives to other mechanical techniques for binding two materials together, such as metals or plastics. They have better force distribution through their chemical bonding compared to other techniques, such as riveting or welding. In addition, chemical bonding can allow for more rapid working and can provide better insulation from external elements, such as dust and moisture, than other mechanical means. Hence, structural adhesives are used in many industrial fields. However, structural adhesives can have disadvantages. For example, the chemical bonding formed during the curing of the structural adhesive can often be too rigid, especially when good mechanical strength is needed. In such situations, the structural adhesives can fracture, separating the structural elements. [0004] Consequently, there is a need for new structural adhesives that can provide good mechanical strength while maintaining effective elasticity. SUMMARY [0005] Disclosed herein are acrylic structural adhesives that include a high vinyl content styrene-butadiene-styrene block copolymers and acrylate monomers. In a specific embodiment, the acrylic structural adhesive includes: an acrylic monomer; a vinyl styrenic block copolymer, where the vinyl styrenic block copolymer includes a vinyl content of greater than 50 wt%; a curing agent; and an additive. [0006] In another specific embodiment, the acrylic structural adhesive includes: a methyl methacrylate monomer; a vinyl styrenic block copolymer, where the vinyl styrenic block copolymer as a Formula selected from: α-V-D-ω (I), d-V-D-ω (II), α-V ^° -D-V′-ω (III), and d- V ^° -D-V′-ω (IV), where the vinyl content of the block copolymer is at least 50%; a benzoyl peroxide; and an additive. 1 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT [0007] In another specific embodiment, the method of making an acrylic structural adhesive includes: contacting a viny styrenic block copolymer and a (meth) methacrylic monomer to make a first mixture, where the vinyl styrenic block copolymer a Formula selected from: α-V- D-ω (I), d-V-D-ω (II), α-V ^° -D-V′-ω (III), and d-V ^° -D-V′-ω (IV), where the vinyl content of the block copolymer is at least 50%; contacting an additive with the first mixture to make a second mixture; contacting a curing agent to make a third mixture; and mixing the second and third mixtures to make the acrylic structural adhesive. BRIEF DESCRIPTION OF THE DRAWINGS [0008] For the purpose of promoting an understanding of the principles of the present disclosure, reference is now made to the embodiments illustrated in the drawings, which are described below. The embodiments disclosed herein are not intended to be exhaustive or limit the present disclosure to the precise form disclosed in the following detailed description. Rather, the embodiments are chosen and described so that others skilled in the art can utilize their teachings. Therefore, no limitation of the scope of the present disclosure is thereby intended. [0009] FIGURE 1 is a photograph of an acrylic structure adhesive that was mixed for 10 minutes before the addition of the curing agent. [0010] FIGURE 2 is a photograph of an acrylic structure adhesive that was mixed for 20 minutes before the addition of the curing agent. [0011] FIGURE 3 is a graph of lap shear test results of acrylic structure adhesives made accordance with the present invention. DETAILED DESCRIPTION [0012] In one or more embodiments, acrylic structure adhesives can include, but are not limited to: one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives. In an embodiment, the one or more acrylic structure adhesives can include: one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives. In another embodiment, the one or more acrylic structure adhesives can include: one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more curing agents, and one or more additives. In another embodiment, the one or more acrylic structure adhesives can include, but are not limited to: TRILENE® liquid ethylene propylene diene monomer rubbers, and one or more acrylic monomers; TRILENE® and one or more acrylic monomers; ethylene, propylene, one or more non-conjugated dienes, and one or more acrylic monomers; liquid ethylene propylene diene monomer rubbers, acrylic polymers, and one or 2 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT more additives; TRILENE® and methyl methacrylate monomers; ethylene, propylene, diene copolymer, vinyl norbornene, and acylate monomers; ethylene, propylene, vinyl norbornene, and acylate monomers; ethylene, propylene, vinyl norbornene, and methyl methacrylate monomers; ethylene, propylene, one or more diene copolymers, vinyl norbornene, and acrylic polymers; ethylidene, dicyclopentadiene, vinyl norbornene, and acylate monomers; ethylene- propylene-dicyclopentadiene liquid polymer and acrylate monomers; ethylene-propylene- dicyclopentadiene liquid polymer, vinyl norbornene, acrylate monomers; ethylene-propylene- dicyclopentadiene liquid polymer, methyl methacrylate monomers, and one or more additives; ethylidene, dicyclopentadiene, vinyl norbornene, methyl methacrylate monomers. The TRILENE® by LION ELASTOMERS® can include, but is not limited to: TRILENE® 65, TRILENE® 65D, TRILENE® 67, TRILENE® 67 FF, TRILENE® 77, TRILENE® CP-80, TRILENE® CP-80 FF, TRILENE® CP-600, TRILENE® CP-1100, TRILENE® CP-1100 FF, and TRILENE® CP-2000. [0013] The one or more acrylic structure adhesives can include one or more vinyl styrenic block copolymers that have a vinyl content of greater than 50 wt%, which can provide the acrylic structure adhesives with many physical properties. For example, the acrylic structure adhesives can adhere or fasten together structural elements with high modulus, high strength, permanent chemical bonds. In another example, the acrylic structure adhesives can provide effective elasticity, being capable of transmitting structural stress without significant loss of structural integrity. [0014] The one or more acrylic structure adhesives can be used for a variety of commercial applications. For example, the one or more acrylic structure adhesives can be mixed with polystyrene to make a foam insulation, which can be used in building and home construction. The one or more acrylic structure adhesives can also be used for grafting, roofing, and paving asphalts. [0015] The one or more vinyl styrenic block copolymers can include but are not limited to: styrene-butadiene polymers and styrene-butadiene polymers. The one or more vinyl styrenic block copolymers can include but are not limited to: at least one polyvinyl aromatic block and at least one polydiene block. The polydiene block can be characterized by a relatively high vinyl content. In an embodiment, the vinyl styrenic block copolymers can include multiple diene blocks, and the overall copolymer can be characterized by having a high vinyl content. [0016] The one or more vinyl styrenic block copolymers can include commercially available vinyl styrenic block copolymers. For example, the one or more vinyl styrenic block copolymers can include STEREON® SR8983 and STEREON® 721AC by LION ELASTOMERS®. The vinyl styrenic block copolymers can include solution polymerized 3 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT linear styrene-butadiene multi-block elastomer. The vinyl styrenic block copolymers can include graftable rubber modifier that is reacted with bromine and processed into clean, white powder. The one or more vinyl styrenic block copolymers can include those described in US 9,732,178, which is incorporated herein by reference in its entirety. [0017] The one or more vinyl styrenic block copolymers can include, but are not limited to: vinyl styrenic block copolymers of Formula I: α-V-D-ω (I), where V is a polyvinyl aromatic block, D is a polydiene block, α and ω are each independently a hydrogen atom, a functional group, or a polymeric segment or block, and where D is characterized by a vinyl content of at least 50%. [0018] The one or more polyvinyl aromatic blocks can include, but are not limited to: three or more mer units deriving from the polymerization of vinyl aromatic monomer. The vinyl aromatic monomer can include, but are not limited to: styrene, α-methyl styrene, p- methylstyrene, and vinylnaphthalene. In an embodiment, polydiene blocks include three or more mer units deriving from the polymerization of conjugated diene monomer. In another embodiment, polydiene blocks include three or more mer units deriving from the polymerization of a non-conjugated diene monomer. Examples of a conjugated diene monomer can include, but are not limited to: 1,3-butadiene; isoprene; 1,3-pentadiene; 1,3- hexadiene; 2,3-dimethyl-1,3-butadiene; 2-ethyl-1,3-butadiene; 2-methyl-1,3-pentadiene; 3- methyl-1,3-pentadiene; 4-methyl-1,3-pentadiene; 2,4-hexadiene; and mixtures thereof. Examples of a non-conjugated diene monomer can include, but are not limited to: dicyclopentadiene, ethylidene norbornene, vinyl norbornene, and mixtures thereof. In an embodiment, functional groups can include organic or inorganic moieties that include at least one heteroatom. In an embodiment, the polymeric segment can include homopolymers or copolymers. [0019] In an embodiment, the D of Formula I can be characterized by a vinyl content (i.e. the percentage of mer units positioned in the 1,2-microstructure) of at least about 50%, in other embodiments at least about 55%, in other embodiments at least about 60%, in other embodiments at least about 65%, in other embodiments at least about 70%, in other embodiments at least about 75%, in other embodiments at least about 80%, and in other embodiments at least 85%. In an embodiment, the D of Formula I can be characterized by a vinyl content of less than about 100%, less than about 95%, less than about 90%, less than about 85%, or less than about 80%. The vinyl content may be determined by ¹ H NMR, and as reported herein refers to the percentage of mer units positioned in the 1,2-microstructure based on the total mer units deriving from the polymerization of conjugated diene monomer. 4 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT [0020] In an embodiment, the D block of Formula I can include at least about 250, at least about 350, at least about 450, and at least about 550 mer units deriving from the polymerization of conjugated diene monomer. In an embodiment, the D block of Formula I can include less than about 800, less than about 750, less than about 700, less than about 650, and less than about 600 mer units deriving from the polymerization of conjugated diene monomer. [0021] In an embodiment, the V block copolymer of Formula I can include at least 50, at least 120, at least 145, at least 160, at least 180, at least 200, and at least 225 mer units deriving from the polymerization of vinyl aromatic monomer. In these or other embodiments, the V block of Formula I can include less than about 400, less than about 350, less than 325, less than 300, and less than 280 mer units deriving from the polymerization of vinyl aromatic monomer. [0022] In an embodiment, the vinyl styrenic block copolymers defined by the Formula I can be characterized by low levels of tapering, which may also be referred to as randomness between the blocks of the polymer chain. In other words, and for example, a vinyl aromatic block (e.g. polystyrene block) of the vinyl styrenic block copolymers can have a limited number, if any, of mer units deriving from conjugated diene (e.g. 1,3-butadiene) within the block. The tapering refers to the level or amount of mer units (in moles) present within a given block as an impurity in that block (e.g. styrene mer units within a polybutadiene block). In an embodiment, the blocks of the vinyl styrenic block copolymers defined by the Formula I can include less than about 5%, less than about 3%, less than about 1%, and less than about 0.5% tapering in any given block of the block copolymer. In an embodiment, the blocks of the vinyl styrenic block copolymers defined by the Formula I can be substantially devoid of tapering, which includes that amount of tapering or less that will not have an appreciable impact on the block copolymer. In an embodiment, the blocks of the vinyl styrenic block copolymers defined by the Formula I can be devoid of tapering. [0023] In an embodiment, a diene block deriving from the polymerization of diene monomer, and therefore the block copolymer can be defined by the Formula II: d-V-D-ω (II), where d is a polydiene block deriving from the polymerization of diene monomer, V, D, and ω are as defined above with respect to Formula I, and where D and d are characterized by a vinyl content of at least 50%. [0024] In an embodiment, d of Formula II can be characterized by a vinyl content (i.e. the percentage of mer units positioned in the 1,2-microstructure) of at least 50%, at least 55%, at least 60%, at least 65%, at least 70%, at least 75%, at least 80%, and at least 85%. In an embodiment, D is characterized by a vinyl content of less than 100%, less than 95%, less than 90%, less than 85%, and less than 80%. 5 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT [0025] In an embodiment, d of Formula II can include at least 10, at least 40, i at least 60, and at least 80, at least 100, and at least 120 mer units deriving from the polymerization of conjugated diene monomer. In an embodiment, d of Formula II can include less than about 500, less than about 350, less than about 250, less than about 200, less than about 180, less than about 160, and less than about 120 mer units deriving from the polymerization of conjugated diene monomer. [0026] In an embodiment, the blocks of the vinyl styrenic block copolymers defined by the Formula II can include less than about 5%, less than about 3%, less than about 1%, and less than about 0.5% tapering in any given block of the vinyl styrenic block copolymer. In an embodiment, the blocks of the vinyl styrenic block copolymer defined by the Formula II can be substantially devoid of tapering, which includes that amount of tapering or less that will not have an appreciable impact on the block copolymer. In an embodiment, the blocks of the vinyl styrenic block copolymer defined by the Formula II can be devoid of tapering. [0027] In an embodiment, the vinyl styrenic block copolymer can be defined by the Formula III: α-V ^° -D-V′-ω (III), where each V is independently a polyvinyl aromatic block, D is a polydiene block, α and ω are each independently a hydrogen atom, a functional group, or a polymeric segment or block, and where D is characterized by a vinyl content of at least 50%. [0028] In an embodiment, D of Formula III can be characterized by a vinyl content (i.e. the percentage of mer units positioned in the 1,2-microstructure) of at least 50%, at least 55%, at least 60%, at least 65%, at least 70%, at least 75%, at least 80%, and at least 85%. In an embodiment, D can be characterized by a vinyl content of less than about 100%, less than about 95%, less than about 90%, less than about 85%, and less than about 80%. [0029] In an embodiment, D of Formula III can include at least 250, at least 350, at least 450, and at least 550 mer units deriving from the polymerization of conjugated diene monomer. In an embodiment, the D block of Formula III can include less than about 800, less than about 750, less than about 700, less than about 650, and less than about 600 mer units deriving from the polymerization of conjugated diene monomer. [0030] In an embodiment, the V ^° and V′ blocks of Formula III can each independently include at least 25, at least 60, at least 75, at least 80, at least 90, at least 100, and at least 115 mer units deriving from the polymerization of vinyl aromatic monomer. In an embodiment, the V ^° and V′ each independently can include less than about 200, less than about 175, less than about 160, less than about 150, and less than about 140 mer units deriving from the polymerization of vinyl aromatic monomer. 6 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT [0031] In an embodiment, the ratio of V ^° mer units to V′ mer units can be at least 0.2:1, at least 0.4:1, at least 0.6:1, at least 0.8:1, at least 0.9:1, and at least 0.95:1. In an embodiment, the ratio of V ^° mer units to V′ mer units can be less than about 4:1, less than about 3:1, less than about 2:1, than 1.5:1, less than about 1.1:1, and less than about 1.05:1. In an embodiment, the ratio of V ^° mer units to V′ mer units can be about 1:1. [0032] In an embodiment, the blocks of the vinyl styrenic block copolymer defined by the Formula III can include less than 5%, less than 3%, less than 1%, and less than 0.5% tapering in any given block of the block copolymer. In an embodiment, the blocks of the vinyl styrenic block copolymer defined by the Formula III can be substantially devoid of tapering, which includes that amount of tapering or less that will not have an appreciable impact on the block copolymer. In an embodiment, the blocks of the vinyl styrenic block copolymer defined by the Formula III can be devoid of tapering. [0033] In an embodiment, the vinyl styrenic block copolymer of Formula III is a diene block, and therefore the block copolymer can be defined by the Formula IV: d- V ^° -D-V′-ω (IV), where d is a polydiene block, V ^° , V′, D, and ω are as defined above with respect to Formula III, and where D and d are characterized by a vinyl content of at least 50%. [0034] In an embodiment, d of Formula IV can be characterized by a vinyl content (i.e. the percentage of mer units positioned in the 1,2-microstructure) of at least 50%, at least 55%, at least 60%, at least 65%, at least 70%, at least 75%, at least 80%, and at least 85%. In an embodiment, d of Formula IV can be characterized by a vinyl content of less than about 100%, less than about 95%, less than about 90%, less than about 85%, and less than about 80%. [0035] In an embodiment, d of Formula IV includes at least 10, least 40, at least 60, and at least 80, at least 100, and at least 120 mer units deriving from the polymerization of conjugated diene monomer. In an embodiment, d of Formula IV includes less than about 500, less than about 350, less than about 250, less than about 200, less than about 180, less than about 160, and less than about 120 mer units deriving from the polymerization of conjugated diene monomer. [0036] In an embodiment, the overall vinyl content of the block copolymers of the present invention can be at least 50%, in other embodiments at least 55%, in other embodiments at least 60%, in other embodiments at least 65%, in other embodiments at least 70%, in other embodiments at least 75%, in other embodiments at least 80%, and in other embodiments at least 85%. In these or other embodiments, d of Formula IV is characterized by a vinyl content of less than 100%, in other embodiments less than 95%, in other embodiments less than 90%, in other embodiments less than 85%, and in other embodiments less than 80%. The overall 7 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT vinyl content of the block copolymers can be tailored by adjusting the vinyl content of particular diene blocks. For example, where the block copolymers are defined by the Formulae II and IV, the vinyl content of the d block can be increased, without necessarily providing a corresponding increase to the D block, to affect an overall increase in the vinyl content of block copolymer. [0037] In an embodiment, the blocks of the vinyl styrenic block copolymer defined by the Formula IV include less than about 5%, less than about 3%, less than about 1%, and less than about 0.5% tapering in any given block of the vinyl styrenic block copolymer. In an embodiment, the blocks of the vinyl styrenic block copolymer defined by the Formula IV can be substantially devoid of tapering, which includes that amount of tapering or less that will not have an appreciable impact on the block copolymer. In an embodiment, the blocks of the vinyl styrenic block copolymer defined by the Formula IV can be devoid of tapering. [0038] In an embodiment, the peak molecular weight (Mp) of the overall vinyl styrenic block copolymer can be at least 40 kg/mole, at least 50 kg/mole, at least 60 kg/mole, and at least 70 kg/mole. In an embodiment, the overall peak molecular weight of the vinyl styrenic block copolymer can be less than about 150 kg/mole, less than about 125 kg/mole, less than about 100 kg/mole, and less than about 90 kg/mole. [0039] In one or more embodiments, the method of making the vinyl styrenic block copolymer can include a polymerization reaction. For example, the method of making the vinyl styrenic block copolymer can be performed in solution, which includes those polymerization mediums where the monomer to be polymerized can be dissolved in a solvent. In an embodiment, the polymer that is synthesized according to the method can also be soluble in the solvent. [0040] The polymerization can be carried out as a batch process, a continuous process, or a semi-continuous process. In an embodiment, conditions can be controlled to perform the polymerization under a pressure of from about 10,132.5 Pa (0.1 atmosphere) to about 5.066 x 10 ⁶ Pa (50 atmospheres), about 50,662.5 Pa (0.5 atmospheres) to about 2.066 x 10 ⁶ Pa (20 atmospheres), or about 101,325 Pa (1 atmosphere) to about 1.013 x 10 ⁶ Pa (10 atmospheres). In an embodiment, the polymerization mixture may be maintained under anaerobic conditions. [0041] The one or more acrylic structure adhesives can include one or more vinyl styrenic block copolymers with a vinyl content that varies widely. For example, the one or more acrylic structure adhesives can include one or more vinyl styrenic block copolymers with a vinyl content from a low of about 45 wt%, about 50 wt%, or about 55 wt%, to a high of about 75 wt%, about 85 wt%, or about 95 wt%. In another example, the one or more acrylic structure adhesives can include one or more vinyl styrenic block copolymers with vinyl content greater 8 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT than about 50 wt%, greater than about 60 wt%, greater than about 70 wt%, and greater than about 80 wt%, greater than about 90 wt%. In another example, the one or more acrylic structure adhesives can include one or more vinyl styrenic block copolymers with vinyl content from about 49 wt% to about 95 wt %, about 25 wt% to about 35 wt%, about 47 wt% to about 51 wt %, about 49 wt% to about 53 wt %, about 50 wt% to about 61 wt %, about 55 wt% to about 68 wt %, about 51 wt% to about 88 wt %, about 55 wt% to about 76 wt %, or about 65 wt% to about 92 wt %. The weight percent of the vinyl in the vinyl styrenic block copolymers can be based on the total weight of the vinyl styrenic block copolymer; or based on the total weight of the vinyl mer units and the styrene mer units. [0042] The one or more acrylic monomers can include, but are not limited to: acrylic monomer, and (meth)acrylic monomer, methyl methacrylate, methacrylic acid, and methyl ester. The acrylic structure adhesives can have a content of the one or more acrylic monomers that can vary widely. For example, the acrylic structure adhesives can have a content of the one or more acrylic monomers from a low of about 5 wt%, about 10 wt%, or about 30 wt%, to a high of about 70 wt%, about 80 wt%, or about 95 wt%. In another example, the acrylic structure adhesives can have a content of the one or more acrylic monomers from about 5 wt% to about 95 wt%, about 65 wt% to about 75 wt%, about 25 wt% to about 75 wt%, about 20 wt% to about 80 wt%, about 69 wt% to about 75 wt%, about 68 wt% to about 82 wt%, about 72 wt% to about 86 wt%, about 50 wt% to about 73 wt%, about 33 wt% to about 48 wt%, about 60 wt% to about 70 wt%, about 71 wt% to about 81 wt%, about 20 wt% to 30 wt%, about 50 wt% to about 60 wt%, or about 70 wt% to about 80 wt%. The weight percent of the vinyl styrenic block copolymers in the acrylic structure adhesives can be based on the total weight of the acrylic structure adhesives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more curing agents, and one or more additives. [0043] A ratio of the one or more acrylic monomers to the one or more vinyl styrene block copolymers can vary widely. For example, the one or more acrylic monomers to the one or more vinyl styrene block copolymers can be 8:3, 7:3, 7:4, 7:5; 4:1, 3:1, 2:1, and 1:1. In an embodiment, the one or more vinyl styrene block copolymers can be at least partially replaced by the one or more ethylene propylene diene monomer rubbers to make same ratios. [0044] The one or more acrylic monomers can be provided in various forms. For example, the one or more acrylic monomers can be provided as a waterborne polymer, a resin, an emulsion, a dispersion, a colloidal suspension, a gel, a latex, a rubber, or a rubber latex. In 9 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT another example, the one or more acrylic monomers can be provided as a stable dispersion and/or emulsion of styrene-butadiene polymer microparticles in water. The one or more acrylic monomers can be crosslinked, non-crosslinked, or a mixture of crosslinked and non- crosslinked. [0045] The one or more acrylic monomers can have a widely varying solids content. For example, the one or more acrylic monomers can have a solids content from a low of about about 5 wt%, about 10 wt%, or about 30 wt%, to a high of about 70 wt%, about 80 wt%, or about 95 wt%. In another example, the one or more acrylic monomers can have a solids content from about 5 wt% to about 95 wt%, about 20 wt% to about 70 wt%, about 40 wt% to about 60 wt%, about 45 wt% to about 55 wt%, about 47 wt% to about 54 wt%, about 30 wt% to about 54 wt%, about 33 wt% to about 48 wt%, about 51 wt% to about 54 wt%, or about 50 wt% to about 60 wt%. The weight percent of the solids content of one or more acrylic polymers can be based on the total weight of the one or more acrylic polymers. [0046] The one or more ethylene propylene diene monomer rubbers can include, but are not limited to: TRILENE®; liquid ethylene propylene diene monomer rubbers; liquid ethylene propylene diene monomer rubbers and the one or more additives; TRILENE® and liquid ethylene propylene diene monomer rubbers; ethylene, propylene, diene copolymer, and vinyl norbornene; ethylene, propylene, and vinyl norbornene; ethylene, propylene, vinyl norbornene, and the one or more additives. For example, the ethylene propylene diene monomer rubbers can include about 6 wt% of vinyl norbornene or about 94 wt% of TRILENE®. [0047] The one or more ethylene propylene diene monomer rubbers can have an ethylene to propylene ratio that varies widely. For example, the ethylene propylene diene monomer rubbers can have an ethylene to propylene ratio of about 50/50, about 46/54, about 74/26, or about 43/57, about 41/59. [0048] The one or more ethylene propylene diene monomer rubbers can have a viscosity that varies widely. For example, the one or more ethylene propylene diene monomer rubbers can have a viscosity from a low of about 1 cP, about 100 cP, or about 100 cP, to a high of about 5,000 cP, to about 90,000 cP, or about 900,000 cP. In another example, the one or more ethylene propylene diene monomer rubbers can have a viscosity from about 1 cP to about 900,000 cP, about 1 cP to about 10 cP, about 1 cP to about 500 cP, about 10 cP to about 50 cP, about 10 cP to about 100 cP, about 100 cP to about 500 cP, about 100,000 cP to about 128,000 cP, about 6,200 cP to about 8,500 cP, about 7,387 cP to about 7,500 cP, about 7,000 cP to about 8,000 cP, about 6,500 cP to about 8,550 cP, about 7,000 cP to about 8,000 cP, about 5,000 cP to about 10,000 cP, about 128,000 cP to about 900,000 cP, or about 100,000 cP to about 200,000 cP. The viscosity of the ethylene propylene diene monomer rubbers can be measured 10 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT on a Brookfield viscosimeter. The viscosity of the ethylene propylene diene monomer rubbers can be measured at various temperatures, such as 25 °C, 40 °C, 60 °C, and 100 °C. [0049] The acrylic structure adhesives can have a content of the one or more ethylene propylene diene monomer rubbers that can vary widely. For example, the acrylic structure adhesives can have a content of the one or more styrene-butadiene rubbers from a low of about 0 wt%, about 5 wt%, or about 30 wt%, to a high of about 70 wt%, about 80 wt%, or about 95 wt%. In another example, the acrylic structure adhesives can have a concentration of the one or more styrene-butadiene rubbers from about 5 wt% to about 95 wt%, about 25 wt% to about 75 wt%, about 20 wt% to about 80 wt%, about 69 wt% to about 75 wt%, about 68 wt% to about 82 wt%, about 72 wt% to about 86 wt%, about 50 wt% to about 73 wt%, about 33 wt% to about 48 wt%, about 60 wt% to about 70 wt%, about 71 wt% to about 81 wt%, about 20 wt% to 30 wt%, about 50 wt% to about 60 wt%, or about 70 wt% to about 80 wt%. The weight percent of the vinyl styrenic block copolymers in the acrylic structure adhesives can be based on the total weight of the acrylic structure adhesives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives. The acrylic structure adhesives can be free of ethylene propylene diene monomer rubbers. The one or more ethylene propylene diene monomer rubbers can be used to replace at least a portion of the one or more vinyl styrenic block copolymers in the acrylic structure adhesives. [0050] The content of the one or more acrylic polymers in the acrylic structure adhesives can vary widely. For example, the acrylic structure adhesives can have a content of the one or more acrylic polymers from a low of about 0.1 wt%, about 0.5 wt%, or about 1 wt%, to a high of about 50 wt%, about 70 wt%, or about 90 wt%. For example, the acrylic structure adhesives can have a content of the one or more acrylic polymers from about 0.1 wt% to about 90 wt%, 0 wt% to about 10 wt%, 0.5 wt% to about 10 wt%, about 2 wt% to about 20 wt%, about 5 wt% to about 60 wt%, about 15 wt% to about 25 wt%, about 17 wt% to about 54 wt%, about 19 wt% to about 27 wt%, about 15 wt% to about 27 wt%, about 14 wt% to about 24 wt%, about 11 wt% to about 28 wt%, about 33 wt% to about 48 wt%, about 51 wt% to about 54 wt%, or about 50 wt% to about 60 wt%. The weight percent of the vinyl styrenic block copolymers in the acrylic structure adhesives can be based on the total weight of the acrylic structure adhesives; based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more curing agents, and one or more additives. 11 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT [0051] The one or more curing agents can include, but are not limited to: benzoyl peroxide, dicumyl peroxide, and t-butyl perbenzoate. The acrylic structure adhesives can have a content of the one or more curing agents that can vary widely. For example, the acrylic structure adhesives can have a content of the one or more curing agents from a low of about 0.1 wt%, about 0.5 wt%, or about 1 wt%, to a high of about 10 wt%, about 20 wt%, or about 30 wt%. In another example, the acrylic structure adhesives can have a concentration of the one or more acrylic polymers from about 0.1 wt% to about 90 wt%, about 0.1 wt% to about 1 wt%, about 0.5 wt% to about 1.0 wt%, about 1 wt% to about 20 wt%, about 5 wt% to about 10 wt%, about 5 wt% to about 10 wt%, or about 7 wt% to about 30 wt%. The weight percent of the vinyl styrenic block copolymers in the acrylic structure adhesives can be based on the total weight of the acrylic structure adhesives; based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more curing agents, and one or more additives. In another example, the acrylic structure adhesives can have a content from about 2 per hundred rubber (phr) to about 3 phr, about 1 phr to about 3 phr, about 1 phr to about 4 phr, or about 1 phr to about 5 phr. [0052] The one or more additives can include, but are not limited to: one or more curing promoters, one or more neoprenes, one or more acids, one or more bases, one or more buffers, one or more wetting agents, one or more surfactants, one or more pigments, one or more opacifying agents, one or more anti-foam agents, one or more antioxidant stabilizers, one or more tackifier agents, water, and mixtures thereof. The one or more curing promoters can include, but are not limited to: one or more amines and 2,2’-(4-methylphenylimino)diethanol. The one or more tackifier agents can include, but is not limited to, a rosin ester, a hydrocarbon, rosin acid, terpene, modified terpene, coumarone-indene, or a combination thereof. Commercially available tackifiers can include, but are not limited to, TACOLYN® 3400 and TACOLYN® 1070 by Hercules, Inc. [0053] The acrylic structure adhesives can have a content of the one or more additives that can vary widely. For example, the acrylic structure adhesives can have a content of the one or more additives from a low of about 0.1 wt%, about 0.5 wt%, or about 1 wt%, to a high of about 50 wt%, about 70 wt%, or about 90 wt%. In another example, the acrylic structure adhesives can have content of the one or more additives from about 0.1 wt% to about 90 wt%, 0 wt% to about 10 wt%, 0.5 wt% to about 10 wt%, about 2 wt% to about 20 wt%, about 5 wt% to about 60 wt%, about 15 wt% to about 25 wt%, about 17 wt% to about 54 wt%, about 19 wt% to about 27 wt%, about 15 wt% to about 27 wt%, about 14 wt% to about 24 wt%, about 11 wt% to about 12 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT 28 wt%, about 33 wt% to about 48 wt%, about 51 wt% to about 54 wt%, or about 50 wt% to about 60 wt%. The weight percent of the vinyl styrenic block copolymers in the acrylic structure adhesives can be based on the total weight of the acrylic structure adhesives; based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more curing agents, and one or more additives. In an embodiment, the acrylic structure adhesives can be free of the one or more additives. [0054] The acrylic structure adhesives can have a water content that varies widely. For example, the acrylic structure adhesives can have a water content from a low of about 0 wt%, about 0.5 wt%, or about 1 wt%, to a high of about 50 wt%, about 70 wt%, or about 90 wt%. In another example, the acrylic structure adhesives can have a water content of less than 5 wt%, less than 2 wt%, or less than 1 wt%. In another example, the acrylic structure adhesives can have a water content from about 0 wt% to about 90 wt%, 0 wt% to about 10 wt%, 0.5 wt% to about 10 wt%, about 2 wt% to about 20 wt%, about 5 wt% to about 60 wt%, about 15 wt% to about 25 wt%, about 17 wt% to about 54 wt%, about 30 wt% to about 54 wt%, about 33 wt% to about 48 wt%, about 51 wt% to about 54 wt%, or about 50 wt% to about 60 wt%. In another example, the acrylic structure adhesives can be free of water. The weight percent of the water in the acrylic structure adhesives can be based on the total weight of the acrylic structure adhesives; based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more curing agents, and one or more additives. [0055] The acrylic structure adhesives can have a widely varying solids content. For example, the acrylic structure adhesives can have a solids content from a low of about about 5 wt%, about 10 wt%, or about 30 wt%, to a high of about 70 wt%, about 80 wt%, or about 95 wt%. In another example, the acrylic structure adhesives can have a solids content greater than about 50 wt%, about 55 wt%, or about 70 wt%. In another example, the acrylic structure adhesives can have a solids content from about 5 wt% to about 95 wt%, about 20 wt% to about 70 wt%, about 40 wt% to about 60 wt%, about 45 wt% to about 55 wt%, about 47 wt% to about 54 wt%, about 30 wt% to about 54 wt%, about 33 wt% to about 48 wt%, about 51 wt% to about 54 wt%, or about 50 wt% to about 60 wt%. The weight percent of the solids content of acrylic structure adhesives can be based on the total weight of the acrylic structure adhesives; based 13 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more curing agents, and one or more additives. [0056] The one or more acrylic structure adhesives can have tensile strength that can vary widely. For example, the one or more acrylic structure adhesives can have a tensile strength from a low of about 10.0 MPa, about 12.0 MPa, or about 15.0 MPa, to a high of about 35.0 MPa, about 45.0 MPa, or about 55.0 MPa. In another example, the one or more acrylic structure adhesives can have a tensile strength from about 10.0 MPa to about 55.0 Mpa, about 11.0 MPa to about 35.0 MPa, about 12.0 MPa to about 55.0 Mpa, about 15.0 MPa to about 35.0 MPa, about 14.0 MPa to about 45.0 MPa, about 26.0 MPa to about 32.0 MPa, or about 22.0 MPa to about 39.0 MPa. [0057] The one or more acrylic structure adhesives can have elastic modulus that can vary widely. For example, the one or more acrylic structure adhesives can have an elastic modulus from a low of about 10.0 MPa, about 12.0 MPa, or about 15.0 MPa, to a high of about 35.0 MPa, about 45.0 MPa, or about 55.0 MPa. In another example, the one or more acrylic structure adhesives can have an elastic modulus from about 10.0 MPa to about 55.0 MPa, about 11.0 MPa to about 35.0 MPa, about 12.0 MPa to about 55.0 MPa, about 15.0 MPa to about 35.0 MPa, about 14.0 MPa to about 45.0 MPa, about 26.0 MPa to about 32.0 MPa, or about 22.0 MPa to about 39.0 MPa. [0058] The one or more acrylic structure adhesives can have a percent of elongation at break that can vary widely. For example, the one or more acrylic structure adhesives can have a percent of elongation at break from a low of about 3%, about 4%, or about 5%, to a high of about 14 %, about 20%, or about 99%. In another example, the one or more acrylic structure adhesives can have a percent of elongation at break from about 3% to about 26%, about 4% to about 14%, about 5% to about 16%, or about 9% to about 99%. [0059] The one or more acrylic structure adhesives can have a viscosity that can vary widely. For example, the one or more acrylic structure adhesives can have a viscosity from a low of about 30 cP, about 1,000 cP to about 5,000 cP, about 3,500 cP, or about 4,000 cP, to a high of about 6,000 cP, to about 70,000 cP, or about 900,000 cP. In another example, the one or more acrylic structure adhesives can have a viscosity from about 3 cP to about 900,000 cP, about 3,200 cP to about 4,800 cP, about 4,800 cP to about 5,500 cP, about 4,500 cP to about 5,550 cP, about 5,000 cP to about 6,000 cP, about 4,000 cP to about 9,000 cP, about 10,000 cP to about 90,000 cP, or about 400,000 cP to about 900,000 cP. The viscosity of the acrylic structure 14 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT adhesives can be measured on a Brookfield viscosimeter. The viscosity of the acrylic structure adhesives can be measured at various temperatures, such as 25 °C, 40 °C, 60 °C, and 100 °C. [0060] In one or more embodiments, methods of making the one or more acrylic structure adhesives can include, but are not limited to: contacting a vinyl styrenic block copolymer and an acrylic monomer to make a first mixture; contacting an additive with the first mixture to make a second mixture; and contacting a curing agent to make a third mixture; and mixing the third mixture to make an acrylic structural adhesive. The one or more methods of making the one or more acrylic structure adhesives can include, but are not limited to: contacting a vinyl styrenic block copolymer and an acrylic monomer to make a first mixture; and contacting a curing agent to make a second mixture; and mixing the second mixture to make an acrylic structural adhesive. The one or more methods of making the one or more acrylic structure adhesives can include, but are not limited to: contacting a vinyl styrenic block copolymer and an acrylic monomer to make a first mixture; mixing the first mixture for a time or pre-cure time, contacting a curing agent to make a second mixture; and mixing the second mixture to make an acrylic structural adhesive. The one or more methods of making the one or more acrylic structure adhesives can include, but are not limited to: contacting a viny styrenic block copolymer and a (meth) methacrylic monomer to make a first mixture, where the vinyl styrenic block copolymer includes a Formula selected from: α-V-D-ω (I), d-V-D-ω (II), α-V ^° -D-V′-ω (III), and d-V ^° -D-V′-ω (IV); contacting an additive with the first mixture to make a second mixture; contacting a curing agent to make a third mixture; and mixing the third mixture to make the acrylic structural adhesive. In an embodiment, the method of making the one or more acrylic structure adhesives can include: dissolving vinyl styrenic block copolymer into (meth)acrylic monomer; mixing in a curing agent; and pre-curing in water bath to make the acrylic structure adhesive. In another embodiment, the method of making the acrylic structure adhesives can include dissolving a viny styrenic block copolymer into a (meth) acrylic monomer(s); adding additives; and mixing in a curing agent to form the acrylic structure adhesive. In another embodiment, the method of making the acrylic structure adhesives can include dissolving a viny styrenic block copolymer into a (meth) acrylic monomer(s); adding additives; and mixing in a curing agent to form the acrylic structure adhesive. In another embodiment, the method for the acrylic structure adhesives can include: dissolving vinyl styrenic block copolymer into (meth)acrylic monomer; mixing in a curing agent; and pre- curing in water bath to make the acrylic structure adhesives. In another embodiment, the one or more acrylic structure adhesives can be made by dissolving styrene-butadiene polymer in methyl methacrylate and then polymerizing the methyl methacrylate to form the acrylic structure adhesive. In another embodiment, the method of making the acrylic structure 15 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT adhesives can include, but are not limited to: contacting a vinyl styrenic block copolymer, a (meth) acrylic monomer, and, optionally an ethylene propylene diene monomer rubber to make a first mixture; and, optionally, contacting an additive with the first mixture to make a second mixture; and contacting a curing agent to make the acrylic structure adhesive. [0061] A ratio of the one or more acrylic monomers to the one or more vinyl styrene block copolymers in the first mixture, second mixture, and third mixture can vary widely. For example, the one or more acrylic monomers to the one or more vinyl styrene block copolymers can be 8:3, 7:3, 7:4, 7:5; 4:1, 3:1, 2:1, and 1:1. In an embodiment, the one or more vinyl styrene block copolymers can be at least partially replaced by the one or more ethylene propylene diene monomer rubbers to make same ratios in the first mixture, second mixture, and third mixture. [0062] The curing agent can be provided to the first mixture, second mixture, and third mixture from a low of about 0.1 wt%, about 0.5 wt%, or about 1 wt%, to a high of about 10 wt%, about 20 wt%, or about 30 wt%. In another example, the curing agent can be provided to the first mixture, second mixture, and third mixture from about 0.1 wt% to about 90 wt%, about 0.1 wt% to about 1 wt%, about 0.5 wt% to about 1.0 wt%, about 1 wt% to about 20 wt%, about 5 wt% to about 10 wt%, about 5 wt% to about 10 wt%, or about 7 wt% to about 30 wt%. The weight percent of the vinyl styrenic block copolymers in the acrylic structure adhesives can be based on the total weight of the acrylic structure adhesives; based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more curing agents, and one or more additives. In another example, the curing agent can be provided to the first mixture, second mixture, and third mixture from about 2 per hundred rubber (phr) to about 3 phr, about 1 phr to about 3 phr, about 1 phr to about 4 phr, or about 1 phr to about 5 phr. [0063] The one or more cure promoters can shorten the time for curing the acrylic structure adhesives compared to acrylic structure adhesives made without a cure promoter. The curing promoters can be provided to the first mixture, second mixture, and third mixture from about 0.5 phr to about 1 phr, about 0.5 phr to about 1.5 phr, about 1 phr to about 4 phr, or about 1 phr to about 5 phr. [0064] The one or more additives can be provided to the first mixture, second mixture, and third mixture the from a low of about 0.1 wt%, about 0.5 wt%, or about 1 wt%, to a high of about 50 wt%, about 70 wt%, or about 90 wt%. In another example, the one or more additives can be provided to the first mixture, second mixture, and third mixture the from about 0.1 wt% to about 90 wt%, 0 wt% to about 10 wt%, 0.5 wt% to about 10 wt%, about 2 wt% to about 20 16 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT wt%, about 5 wt% to about 60 wt%, about 15 wt% to about 25 wt%, about 17 wt% to about 54 wt%, about 19 wt% to about 27 wt%, about 15 wt% to about 27 wt%, about 14 wt% to about 24 wt%, about 11 wt% to about 28 wt%, about 33 wt% to about 48 wt%, about 51 wt% to about 54 wt%, or about 50 wt% to about 60 wt%. The weight percent of the vinyl styrenic block copolymers in the acrylic structure adhesives can be based on the total weight of the acrylic structure adhesives; based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more ethylene propylene diene monomer rubbers, one or more curing agents, and one or more additives; or based on the total weight of the one or more acrylic monomers, one or more vinyl styrenic block copolymers, one or more curing agents, and one or more additives. In an embodiment, the first mixture, second mixture, and third mixture can be free of the one or more additives. [0065] The first mixture, second mixture, and third mixture can be heated to a temperature from a low of about 0 °C, about 15 °C, or about 25 °C, to a high of about 35 °C, about 65 °C, or about 200 °C. For example, the first mixture, second mixture, and third mixture can be heated to a temperature from about 25 °C to about 28 °C, about 25 °C to about 35 °C, about 25 °C to about 90 °C, about 30 °C to about 45 °C, about 40 °C to about 90 °C, about 43 °C to about 78 °C, about 40 °C to about 90 °C, about 100 °C to about 200 °C. In another example, the first mixture, second mixture, and third mixture can be at room temperature. In another example, the reaction occurs at a temperature of greater than about 40 °C or greater than about 50 °C. The first mixture, second mixture, third mixtures can be performed at different temperatures. [0066] The first mixture, second mixture, and third mixture can be reacted and/or stirred for a first reaction time, second reaction time, and third reaction time from a short of about 15 s, about 120 s, or about 300 s, to a long of about 1 h, about 24 h, or about 72 h. For example, the first mixture, second mixture, and third mixture can be reacted and/or stirred for a first reaction time, second reaction time, and third reaction time from about 1 min to about 15 min, about 5 min to about 45 min, about 10 min to about 25 min, about 1 h to about 12 h, about 5 h to about 15 h, about 10 hours to about 24 hours, about 12 h to about 17 h, about 12 h to about 24 h, about 22 h to about 50 h, or about 24 h to about 72 h. [0067] The first mixture, second mixture, and third mixture can be mixed for a pre-cure time form a short of about 15 s, about 120 s, or about 300 s, to a long of about 1 h, about 24 h, or about 72 h. For example, the pre-cure time can be from about 1 min to about 15 min, about 5 min to about 45 min, about 10 min to about 25 min, about 1 h to about 12 h, about 5 h to about 15 h, about 10 hours to about 24 hours, about 12 h to about 17 h, about 12 h to about 24 h, about 22 h to about 50 h, or about 24 h to about 72 h. 17 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT [0068] The first mixture, second mixture, and third mixture can be reacted and/or stirred in an open container or a closed container. The first mixture, second mixture, and third mixture can be reacted and/or stirred under a vacuum. The first mixture, second mixture, and third mixture can be reacted and/or stirred under an inert atmosphere, such as He, Ne, Ar, and N2. [0069] The first mixture, second mixture, and third mixture can be reacted and/or stirred under a widely varying gauge pressure. For example, first mixture, second mixture, and third mixture can be reacted and/or stirred under a gauge pressure from a low of about 0.7 kPa (0.1 psig), about 6.9 kPa (1 psig), or about 34.5 kPa (5 psig), to a high of about 344.7 kPa (50 psig), about 620.5 kPa (90 psig), or about 1,034.2 kPa (150 psig). In another example, first mixture, second mixture, and third mixture can be reacted and/or stirred under a gauge pressure from about 206.8 kPa (30 psig) to about 586.1 kPa (85 psig), about 0.7 kPa (0.1 psig) to about 620.5 kPa (90 psig), about 0.7 kPa (0.1 psig) to about 6.9 kPa (1 psig), about 6.9 kPa (1 psig) to about 586.1 kPa (85 psig), about 137.9 kPa (20 psig) to about 620.5 kPa (90 psig), about 34.5 kPa (5 psig) to about 137.9 kPa (20 psig), about 172.4 kPa (25 psig) to about 517.1 kPa (75 psig), or about 0.7 kPa (0.1 psig) to about1,034.2 kPa (150 psig). In an embodiment, the reactions can occur in a pressure reactor. [0070] The pH of the first mixture, second mixture, and third mixture can vary widely. For example, the first mixture, second mixture, and third mixture can have a pH from about 4.0 to about 12.0, about 5.0 to about 10.0, about 7.5 to about 11.0, about 7.0 to about 10.0, about 8.0 to about 9.0, about 9.0 to about 10.0, about 8.0 to about 10.0, about 9.0 to about 11.0, or about 6.0 to about 9.0. [0071] The first mixture, second mixture, and third mixture can be agitated and/or stirred. For example, the mixtures and reaction mixtures can be stirred from about 50 revolution per minute (rpm) to about 1,500 rpm, about 50 rpm to about 500 rpm or about 60 rpm to about 1,000 rpm. [0072] The first mixture, second mixture, and third mixture can have a viscosity that can vary widely. For example, the first mixture, second mixture, and third mixture can have a viscosity from a low of about 1 cP, about 100 cP, or about 100 cP, to a high of about 15,000 cP, to about 90,000 cP, or about 900,000 cP. In another example, the first mixture, second mixture, and third mixture can have a viscosity from about 1 cP to about 10 cP, about 1 cP to about 900,000 cP, about 1 cP to about 500 cP, about 10 cP to about 50 cP, about 10 cP to about 100 cP, about 100 cP to about 500 cP, about 6,200 cP to about 8,500 cP, about 7,387 cP to about 7,500 cP, about 7,000 cP to about 8,000 cP, about 6,500 cP to about 8,550 cP, about 7,000 cP to about 8,000 cP, about 70,000 cP to about 128,000 cP, or about 5,000 cP to about 10,000 cP. The viscosity of the first mixture, second mixture, and third mixture can be measured on a 18 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT Brookfield viscosimeter. The viscosity of the first mixture, second mixture, and third mixture can be measured at various temperatures, such as 25 °C, 40 °C, 60 °C, and 100 °C. [0073] In one or more embodiments, the acrylic structural adhesives can be used for wide variety of applications. For example, the acrylic structural adhesives can be used in insulating packer fluids, fluid loss pills, drilling fluids, and completion fluids. In one or more embodiments, using the acrylic structural adhesives in a drilling fluid or a completion fluid can include, but is not limited to: injecting an acrylic structural adhesive into a wellbore or injecting the acrylic structural adhesive into a subterranean formation. In another example, the acrylic structural adhesives can be made into thixotropic fluids and/or cohesive gels. In another example, the acrylic structural adhesives can be used with the compositions and methods discussed in U.S. Patent No. 9,657,213, U.S. Patent No. 10,053,609, and U.S. Patent No. 11,692,048, each of which is incorporated herein by reference in its entirety. EXAMPLES [0074] To provide a better understanding of the foregoing discussion, the following non- limiting examples are offered. Although the examples can be directed to specific embodiments, they are not to be viewed as limiting the invention in any specific respect. [0075] Methyl methacrylate was mixed with STEREON® 8983 at 7:3 ratio in closed reaction vessel. A mixer was used to mix at 2,150 rpm for 30 minutes. 2% Benzoyl peroxide was then added and mixed for additional 10 min. To prevent evaporation of methyl methacrylate monomer, the mixture was pre-cured in 60°C water bath for 15 minutes. Magnetic stirring was at 260 rpm to well disperse sample. To eliminate bubbles formed during pre-curing, sample was mixed again by mixer at 2,150 rpm for 20 minutes. [0076] The acrylic structural adhesive was cured by heat press to measure tensile properties. The sample was cured at elevated temperature for 90 min. Curing temperature was initially set at 75 °C for 30 min, then increased to 95 °C and 120 °C for 30 minutes. Dumbbell samples were cut from cured sample slab to conduct tensile tests with 50 mm/min crosshead rate. [0077] STEREON® 8983 (79% vinyl)/methyl methacrylate adhesive (group A) had higher tensile strength, elongation at break and elastic modulus than KRATON® 1101 (15% vinyl)/methyl methacrylate adhesive (group B) and KRATON® 1192 (43% vinyl) /methyl methacrylate adhesive (group C). [0078] Initial efforts to demonstrate this invention resulted in adhesive formulations that contained a lot of bubbles that created defects in the cured adhesive, as shown in FIGURE 1. These problems were overcome in the following example. [0079] The pre-polymerization and mixing time were further adjusted to well disperse STEREON® 8983 in methyl methacrylate. Increasing pre-polymerization time from 15 19 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT minutes to 20 minutes caused some bubbles before curing, because bubbles were difficult to be eliminated in liquid sample with high viscosity. So, pre-polymerization time was maintained at 15 minutes. Mixing time was increased from 10 minutes to 20 minutes, and undispersed methyl methacrylate dots disappeared, as shown in FIGURE 2. [0080] In one experiment, three inventive examples of the structure adhesive compositions using different concentrations of monomers and copolymers were made to determine the effect on the strength properties of the adhesive. In a first example (Ex 1), SB 8983 was used to make the structure adhesive composition. In a second example (Ex 2), KRATON® 1101 was used to make the structure adhesive composition. In a third example (Ex 3), 25 wt % of the vinyl styrenic block copolymer, STEREON® 8983, and 5 wt% of vinyl norbornene TRILENE® was used to make the structure adhesive composition. The strength properties of these three structural adhesives are shown in Table 1. Table 1: Acrylic Structural Adhesive Strength Properties t [008 gth and elongation at break than KRATON® 1101/methyl methacrylate compositions. Since both SB copolymers had about 30 wt% of styrene, the different tensile performance can be related to high vinyl content of STEREON® 8983. The tensile strength and elongation at break were similar as the formulation without TRILENE®. Some small bubbles on cured slab may have detrimental effects on tensile properties. The small bubbles may be related to slow polymerization rate caused by addition of TRILENE®. [0082] In another experiment, five more acrylic structural adhesives (Ex A, Ex B, Ex C, Ex D, and Ex E) using different concentrations of monomers and copolymers were made. The reaction conditions and resulting properties are shown in Tables 2-6. The substrate is aluminum. 20 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT Table 2: Acrylic Structural Adhesive Reaction Conditions Table 3: Acrylic Structural Adhesive Compositions a e : ens e erormance o te cry c tructura esive Table 5: Acrylic Structural Adhesive Physical Properties n] 21 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT Table 6: Acrylic Structural Adhesive Physical Properties e [ late structural adhesive formulation improved cure time. Initially, methyl methacrylate (MMA) and high vinyl SBR (SR 8983) were mixed, then benzoyl peroxide (BPO) was added, and finally the curing promoter, 2,2’-(4-methylphenylimino)diethanol (amine) was added. Table 7: Methyl Methacrylate and STEREON® 8983 With 2,2′-(4- ao e epe e , e o e o e a o o e oy peo e a , -(4- methylphenylimino)diethanol were reversed. 22 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT Table 8: Methyl Methacrylate and STEREON® 8983 With 2,2′-(4- Methylphenylimino)diethanol Curing Promoter [ hanol first and, then, adding SR 8983 and benzoyl peroxide are shown in Table 9. Table 9: Methyl Methacrylate and STEREON® 8983 With 2,2′-(4- Mthlh li i dith l C i P t g e [0 ,2′-(4- methylphenylimino)diethanol were made according to Table 10. Table 10: Methyl Methacrylate and STEREON® 8983 with 2,2′-(4- 4868 -9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT Final sample BPO PART 1 5 50 Methylphenylimino)diethanol Curing Promoter y ^g p [ nally equivalent components, materials, designs, and equipment can be used. The inclusion of additional elements can be deemed readily apparent and obvious to one of ordinary skill in the art. Specific elements disclosed herein are not to be interpreted as limiting, but rather as a basis for the claims and as a representative basis for teaching one of ordinary skill in the art to employ the present invention. Various modifications and additions can be made to the exemplary embodiments discussed without departing from the scope of the present disclosure. For example, while the embodiments described above refer to particular features, the scope of this disclosure also includes embodiments having different combinations of features and embodiments that do not include all of the described features. Accordingly, the scope of the 24 4868-9670-1574 v.8 PATENT Attorney Docket No.: 27178.106PCT present invention is intended to embrace all such alternatives, modifications, and variations as fall within the scope of the claims, together with all equivalents thereof. [0088] As used herein, the singular forms "a", "an", and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise. Furthermore, to the extent that the terms "including", "includes", "having", "has", "with", or variants thereof are used in either the detailed description and/or the claims, such terms are intended to be inclusive in a manner similar to the term "comprising". As used herein, use of the term "including" as well as other forms, such as "includes," and "included," is not limiting. [0089] Certain embodiments and features have been described using a set of numerical upper limits and a set of numerical lower limits. It should be appreciated that ranges including the combination of any two values, e.g., the combination of any lower value with any upper value, the combination of any two lower values, and/or the combination of any two upper values are contemplated unless otherwise indicated. It should also be appreciated that the numerical limits can be the values from the examples. Certain lower limits, upper limits and ranges appear in at least one claims below. All numerical values are "about" or "approximately" the indicated value, and consider experimental error and variations that would be expected by a person having ordinary skill in the art. [0090] It is understood that any specific order or hierarchy of steps in the processes disclosed is an illustration of example approaches. Based upon design preferences, it is understood that the specific order or hierarchy of steps in the processes can be rearranged, or that all illustrated steps be performed. Some of the steps can be performed simultaneously. For example, in certain circumstances, multitasking and parallel processing can be advantageous. Moreover, the separation of various system components illustrated above should not be understood as requiring such separation, and it should be understood that the described program components and systems can generally be integrated together in a single software product or packaged into multiple software products. [0091] All patents, patent applications, provisional applications, and publications referred to or cited herein are incorporated by reference in their entirety, including all figures and tables, to the extent they are not inconsistent with the explicit teachings of this specification. 25 4868-9670-1574 v.8