Title:
APPARATUS AND METHOD FOR CONTINUOUSLY PREPARING FORMIC ACID BY USING IMMOBILIZED CARBON DIOXIDE REDUCTASE
Document Type and Number:
WIPO Patent Application WO/2024/048837
Kind Code:
A1
Abstract:
The present invention relates to an apparatus and a method for continuously preparing formic acid by using an immobilized carbon dioxide reductase. Since an electrochemical reactor for producing a reduced electron carrier and an enzyme reactor for converting carbon dioxide into formic acid are separated from each other, scaling up in the future poses no problem, and thus scaling up of formic acid production is advantageous. In addition, formic acid produced using an ion exchange resin column is isolated and recovered so that deterioration in production can be prevented, and thus formic acid can be continuously produced, and separately adjusting pH is unnecessary.
Inventors:
KIM YONG HWAN (KR)
JEON BYOUNG WOOK (KR)
RYU JUNG KI (KR)
JEON BYOUNG WOOK (KR)
RYU JUNG KI (KR)
Application Number:
PCT/KR2022/015180
Publication Date:
March 07, 2024
Filing Date:
October 07, 2022
Export Citation:
Assignee:
ULSAN NAT INST SCIENCE & TECH UNIST (KR)
International Classes:
C12M1/00; C12M1/34; C12M1/40; C12N9/04; C12N11/08; C12P7/40
Foreign References:
| US20110315560A1 | 2011-12-29 | |||
| KR20160033411A | 2016-03-28 |
Other References:
CO2로부터 포름산제조기술개발. KOREA CCS 2020사업 최종보고서. 08 October 2020, pp. 1-136, non-official translation (Technology Development of Formic Acid Production by CO2 Hydrogenation. Final Report of KOREA CCS 2020 Program.)
HERNÁNDEZ-IBÁÑEZ NAIARA; GOMIS-BERENGUER ALICIA; MONTIEL VICENTE; ANIA CONCHI O.; INIESTA JESÚS: "Fabrication of a biocathode for formic acid production upon the immobilization of formate dehydrogenase from Candida boidinii on a nanoporous carbon", CHEMOSPHERE, PERGAMON PRESS, OXFORD., GB, vol. 291, 30 November 2021 (2021-11-30), GB , XP086944804, ISSN: 0045-6535, DOI: 10.1016/j.chemosphere.2021.133117
BACCOUR MOHAMED, LAMOTTE ALEXANDRA, SAKAI KENTO, DUBREUCQ ERIC, MEHDI AHMAD, KANO KENJI, GALARNEAU ANNE, DRONE JULLIEN, BRUN NICOL: "Production of formate from CO 2 gas under ambient conditions: towards flow-through enzyme reactors", GREEN CHEMISTRY, ROYAL SOCIETY OF CHEMISTRY, GB, vol. 22, no. 12, 22 June 2020 (2020-06-22), GB , pages 3727 - 3733, XP093145725, ISSN: 1463-9262, DOI: 10.1039/D0GC00952K
HERNÁNDEZ-IBÁÑEZ NAIARA; GOMIS-BERENGUER ALICIA; MONTIEL VICENTE; ANIA CONCHI O.; INIESTA JESÚS: "Fabrication of a biocathode for formic acid production upon the immobilization of formate dehydrogenase from Candida boidinii on a nanoporous carbon", CHEMOSPHERE, PERGAMON PRESS, OXFORD., GB, vol. 291, 30 November 2021 (2021-11-30), GB , XP086944804, ISSN: 0045-6535, DOI: 10.1016/j.chemosphere.2021.133117
BACCOUR MOHAMED, LAMOTTE ALEXANDRA, SAKAI KENTO, DUBREUCQ ERIC, MEHDI AHMAD, KANO KENJI, GALARNEAU ANNE, DRONE JULLIEN, BRUN NICOL: "Production of formate from CO 2 gas under ambient conditions: towards flow-through enzyme reactors", GREEN CHEMISTRY, ROYAL SOCIETY OF CHEMISTRY, GB, vol. 22, no. 12, 22 June 2020 (2020-06-22), GB , pages 3727 - 3733, XP093145725, ISSN: 1463-9262, DOI: 10.1039/D0GC00952K
Attorney, Agent or Firm:
THEWAVE IP LAW FIRM (KR)
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