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Title:
AZEOTROPE OR AZEOTROPE-LIKE COMPOSITIONS OF 1,1,1,3,3,3-HEXAFLUORO-2-(2,2,2-TRIFLUOROETHOXY)PROPANE AND APPLICATIONS THEREOF
Document Type and Number:
WIPO Patent Application WO/2023/168268
Kind Code:
A1
Abstract:
Minimum-boiling, homogeneous azeotropic and azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane ("HFIP-TFE") with each of trans-1,2-dichloroethylene, ethanol, and isopropanol are disclosed. Other azeotropic and azeotrope-like compositions based on 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane at least one other component are also disclosed, as well as applications of the azeotropic and azeotrope-like compositions.

Inventors:
HULSE RYAN J (US)
CLOSE JOSHUA (US)
MALLEPALLY RAJENDAR (US)
Application Number:
PCT/US2023/063481
Publication Date:
September 07, 2023
Filing Date:
March 01, 2023
Export Citation:
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Assignee:
HONEYWELL INT INC (US)
International Classes:
C09K5/04; C08J9/14; C09K3/30
Domestic Patent References:
WO2021131810A12021-07-01
Foreign References:
JP2003238992A2003-08-27
US20150184049A12015-07-02
US6255273B12001-07-03
US20080283793A12008-11-20
Attorney, Agent or Firm:
BENINATI, John F. et al. (US)
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Claims:
CLAIMS 1. A composition consisting essentially of from about 20 wt.% to about 55 wt.% 1,1,1,3,3,3-hexafluoro-2(2,2,2-trifluoroethoxy)propane and from about 45 wt.% to about 80 wt.% trans-1,2-dichloroethylene. 2. The composition as claimed in claim 1, wherein said composition consists essentially of from about 29 wt.% to about 45 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and from about 55 wt.% to about 71 wt.% trans-1,2-dichloroethylene. 3. The composition as claimed in claim 1 or claim 2, wherein said composition consists essentially of about 34 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 66 wt.% trans-1,2-dichloroethylene. 4. The composition as claimed of any one of claims 1 to 3, wherein the composition has a boiling point of about 44.20°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. 5. The composition as claimed in any one of claims 1 to 4, wherein the composition is an azeotrope or azeotrope-like composition with a boiling point of about 44.20°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. 6. A composition comprising a composition consisting essentially of from about 20 wt.% to about 55 wt.% 1,1,1,3,3,3-hexafluoro-2(2,2,2-trifluoroethoxy)propane and from about 45 wt.% to about 80 wt.% trans-1,2-dichloroethylene. 7. A composition consisting essentially of from about 75 wt.% to about 97 wt.% 1,1,1,3,3,3-hexafluoro-2(2,2,2-trifluoroethoxy)propane and from about 3 wt.% to about 25 wt.% ethanol. 8. The composition as claimed in claim 7, wherein said composition consists essentially of from about 79 wt.% to about 95 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and from about 5 wt.% to about 21 wt.% ethanol. 9. The composition as claimed in claim 7 or 8, wherein said composition consists essentially of about 91 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 9 wt.% ethanol.
Description:
AZEOTROPE OR AZEOTROPE-LIKE COMPOSITIONS OF 1,1,1,3,3,3-HEXAFLUORO-2-(2,2,2-TRIFLUOROETHOXY)PROPANE AND APPLICATIONS THEREOF CROSS-REFERENCE TO RELATED APPLICATION [0001] This application claims priority to U.S. Provisional Patent Application No. 63/315,292, filed March 1, 2022, which is herein incorporated by reference in its entirety. FIELD [0002] The present disclosure is related to azeotrope or azeotrope-like compositions and, in particular, to azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (“HFIP-TFE”) and applications for these compositions. BACKGROUND [0003] Fluorocarbon fluids have properties that are desirable for use as heat transfer media, immersion coolants, liquid or gaseous dielectrics, industrial refrigerants, and other applications. For these applications, the use of single component fluids or azeotrope-like mixtures, i.e., those which do not substantially fractionate on boiling and evaporation, are particularly desirable. Unfortunately, the use of certain hydrofluorocarbons “HFCs” in industrial applications is now believed to contribute to the global warming, and accordingly, have limited their contemporary use. However, the identification of new, environmentally- safe, non-fractionating mixtures comprising HFCs, and subset classes such as hydrofluoroethers “HFEs”, are complicated, due to the fact that azeotrope formation is not readily predictable. Therefore, the industry is continually seeking new HFC-based mixtures that are acceptable and environmentally safer substitutes. [0004] The compound 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane, also known as HFIP-TFE, is a candidate for heat transfer media, and liquid dielectric applications. Furthermore, certain mixtures involving HFIP-TFE may be suitable for particular applications such as heat transfer fluids, thermal management fluids, refrigerants, and heat transfer compositions. SUMMARY OF THE DISCLOSURE [0005] It has been found that certain azeotropic and azeotrope-like compositions are formed upon mixing 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane with a second component and, in particular, the present disclosure provides minimum-boiling, homogeneous azeotropic or azeotrope-like compositions consisting essentially of HFIP-TFE with each of trans-1,2-dichloroethylene (trans-DCE), ethanol, or isopropanol. Other azeotropic and azeotrope-like compositions based on 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane at least one other component are also disclosed. [0006] The compound 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane has the following chemical structure: [0007] HFIP-TFE may be manufactured by any appropriate method, has the general chemical formula C 5 H 3 F 9 O and a molecular weight of 250.06. [0008] In one form thereof, the present disclosure provides a composition comprising an azeotrope or azeotrope-like composition consisting essentially of effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene. The azeotrope or azeotrope-like composition may have a boiling point of about 44.20°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0009] The azeotrope or azeotrope-like composition may consist essentially of from about 20 wt.% to about 55 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 45 wt.% to about 80 wt.% trans-1,2-dichloroethylene, from about 29 wt.% to about 45 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 55 wt.% to about 71 wt.% trans-1,2-dichloroethylene or about 34 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and about 66 wt.% trans-1,2-dichloroethylene. [0010] In another form thereof, the present disclosure provides a composition comprising an azeotrope or azeotrope-like composition consisting essentially of effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol. The azeotrope or azeotrope-like composition may have a boiling point of about 66.77°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0011] The azeotrope or azeotrope-like composition may consist essentially of from about 75 wt.% to about 97 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 3 wt.% to about 25 wt.% ethanol, from about 79 wt.% to about 95 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 5 wt.% to about 21 wt.% ethanol, or about 91 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 9 wt.% ethanol. [0012] In another form thereof, the present disclosure provides a composition comprising an azeotrope or azeotrope-like composition consisting essentially of effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and isopropanol. The azeotrope or azeotrope-like composition may have a boiling point of about 69.60°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0013] The azeotrope or azeotrope-like composition may consist essentially of from about 80 wt.% to about 99 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 1 wt.% to about 20 wt.% isopropanol, from about 85 wt.% to about 95 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 5 wt.% to about 15 wt.% isopropanol, or about 92 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 8 wt.% isopropanol. [0014] In particular, it is recognized that these compositions tend to exhibit relatively low global warming potentials (“GWPs”), preferably less than about 1000, more preferably less than about 500, and even more preferably less than about 150. [0015] The composition may comprise at least about 15 wt.% of an azeotropic mixture as described herein. [0016] In further aspects, it has been found that certain minimum boiling, homogenous azeotrope compositions are formed upon mixing 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane with each of ethanol, trans-1,2-dichloroethylene, or isopropanol. [0017] The azeotropic and azeotrope-like mixtures of the disclosure exhibit characteristics which make them particularly desirable for number of applications, including as heat transfer fluids, which may be used, for example, as thermal management fluids in electronic cooling, or as working fluids in Organic Rankine Cycles. BRIEF DESCRIPTION OF THE DRAWINGS [0018] Fig.1 illustrates the change in boiling point temperature of mixtures of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene at ambient pressure according to Example 1. [0019] Fig.2 illustrates the change in boiling point temperature of mixtures of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol at ambient pressure according to Example 2. [0020] Fig.3 illustrates the change in boiling point temperature of mixtures of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and isopropanol at ambient pressure according to Example 3. DETAILED DESCRIPTION I. Description of azeotrope or azeotrope-like compositions [0021] An “azeotrope” composition is a unique combination of two or more components. An azeotrope composition can be characterized in various ways. For example, at a given pressure, an azeotrope composition boils at a constant characteristic temperature which is either greater than the higher boiling point component (maximum boiling azeotrope) or less than the lower boiling point component (minimum boiling azeotrope). At this characteristic temperature the same composition will exist in both the vapor and liquid phases. The azeotrope composition does not fractionate upon boiling or evaporation. Therefore, the components of the azeotrope composition cannot be separated during a phase change. [0022] An azeotrope composition is also characterized in that at the characteristic azeotrope temperature, the bubble point pressure of the liquid phase is identical to the dew point pressure of the vapor phase. [0023] The behavior of an azeotrope composition is in contrast with that of a non- azeotrope composition in which during boiling or evaporation, the liquid composition changes to a substantial degree. [0024] For the purposes of the present disclosure, an azeotrope composition is characterized as that composition which boils at a constant characteristic temperature, the temperature being lower (a minimum boiling azeotrope) than the boiling points of the two or more components, and thereby having the same composition in both the vapor and liquid phases. [0025] One of ordinary skill in the art would understand however that at different pressures, both the composition and the boiling point of the azeotrope composition will vary to some extent. Therefore, depending on the temperature and/or pressure, an azeotrope composition can have a variable composition. The skilled person would therefore understand that composition ranges, rather than fixed compositions, can be used to define azeotrope compositions. In addition, an azeotrope may be defined in terms of exact weight percentages of each component of the compositions characterized by a fixed boiling point at a specified pressure. [0026] An “azeotrope-like” composition is a composition of two or more components which behaves substantially as an azeotrope composition. Thus, for the purposes of this disclosure, an azeotrope-like composition is a combination of two or more different components which, when in liquid form under given pressure, will boil at a substantially constant temperature, and which will provide a vapor composition substantially identical to the liquid composition undergoing boiling. [0027] Azeotrope or azeotrope-like compositions can be identified using a number of different methods. [0028] For the purposes of this disclosure the azeotrope or azeotrope-like composition is identified experimentally using an ebulliometer (Walas, Phase Equilibria in Chemical Engineering, Butterworth-Heinemann, 1985, 533-544). An ebulliometer is designed to provide extremely accurate measurements of the boiling points of liquids by measuring the temperature of the vapor-liquid equilibrium. [0029] The boiling points of each of the components alone are measured at a constant pressure. As the skilled person will appreciate, for a binary azeotrope or azeotrope- like composition, the boiling point of one of the components of the composition is initially measured. The second component of the composition is then added in varying amounts and the boiling point of each of the obtained compositions is measured using the ebulliometer at said constant pressure. [0030] The measured boiling points are plotted against the composition of the tested composition, for example, for a binary azeotrope, the amount of the second component added to the composition, (expressed as either weight % or mole %). The presence of an azeotrope composition can be identified by the observation of a maximum or minimum boiling temperature which is greater or less than the boiling points of any of the components alone. [0031] As the skilled person will appreciate, the identification of the azeotrope or azeotrope-like composition is made by the comparison of the change in the boiling point of the composition on addition of the second component to the first component, relative to the boiling point of the first component. Thus, it is not necessary that the system be calibrated to the reported boiling point of the particular components in order to measure the change in boiling point. [0032] As used herein, the term “consisting essentially of”, with respect to the components of an azeotrope or azeotrope-like composition or mixture, means the composition contains the indicated components in an azeotrope or azeotrope-like ratio, and may contain additional components provided that the additional components do not form new azeotrope or azeotrope-like systems. For example, azeotrope mixtures consisting essentially of two compounds are those that form binary azeotropes, which optionally may include one or more additional components, provided that the additional components do not render the mixture non-azeotropic and do not form an azeotrope with either or both of the compounds (e.g., do not form a ternary or higher azeotrope). [0033] As used herein, the term “about”, when used in connection with recited weight percentages of the components of the present compositions, includes a deviation of ± 0.3 % from the recited weight percentage. [0034] As used herein, the singular forms “a”, “an” and “the” include plural unless the context clearly dictates otherwise. Moreover, when an amount, concentration, or other value or parameter is given as either a range, preferred range, or a list of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. Where a range of numerical values is recited herein, unless otherwise stated, the range is intended to include the endpoints thereof, and all integers and fractions within the range. It is not intended that the scope of the disclosure be limited to the specific values recited when defining a range. [0035] As previously discussed, at the maximum or minimum boiling point, the composition of the vapor phase will be identical to the composition of the liquid phase. The azeotrope-like composition is therefore that composition of components which provides a substantially constant minimum or maximum boiling point at which substantially constant boiling point the composition of the vapor phase will be substantially identical to the composition of the liquid phase. II. Azeotrope or azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and trans-1,2-dichloroethylene [0036] The present composition provides for compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and trans-1,2-dichloroethylene (trans-DCE), alternatively compositions consisting essentially of 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane (HFIP-TFE) and trans-1,2-dichloroethylene (trans-DCE), and alternatively compositions consisting of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and trans-1,2-dichloroethylene (trans-DCE). [0037] In the above compositions, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) may be present in an amount preferably from about 20 wt.% to about 55 wt.%, preferably from about 29 wt.% to about 45 wt.%, or preferably about 34 wt.%. The trans-1,2-dichloroethylene (trans-DCE) may be present in an amount preferably from about 45 wt.% to about 80 wt.%, preferably from about 55 wt.% to 71 wt.%, or preferably about 66 wt.%. [0038] It has also been found that 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) forms homogeneous, minimum boiling azeotrope and azeotrope-like compositions or mixtures with trans-1,2-dichloroethylene, and the present disclosure provides homogeneous azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene. The azeotrope or azeotrope-like compositions may consist essentially of 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene, or the azeotrope or azeotrope-like compositions may consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and trans-1,2-dichloroethylene. [0039] The present inventors have found experimentally that 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene form an azeotrope or azeotrope-like composition. [0040] The azeotrope or azeotrope-like composition of 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene is a binary azeotrope which includes only the foregoing two components, and lacks other components such as alcohols, including methanol and/or ethanol, for example. [0041] The present disclosure provides an azeotrope or azeotrope-like composition which comprises effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene to form an azeotrope or azeotrope-like composition. As used herein, the term “effective amount” is an amount of each component which, when combined with the other component, results in the formation of an azeotrope or azeotrope-like mixture. [0042] The present azeotrope or azeotrope-like compositions may consist essentially of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and trans-1,2- dichloroethylene, or consist of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and trans-1,2-dichloroethylene. [0043] The present disclosure also provides a method of forming an azeotrope or azeotrope-like composition by mixing, combining, or blending, effective amounts of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be used in the present methods. For example, 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. Both 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene are commercially available and can be procured from several different vendors. The components can be provided in the required amounts, for example by weighing and then combining the amounts. [0044] Preferably, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, from about 20 wt.% to about 55 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane, preferably from about 29 wt.% to about 45 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, or preferably about 34 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, and preferably from about 45 wt.% to about 80 wt.% trans-1,2-dichloroethylene, preferably from about 55 wt.% to about 71 wt.% trans-1,2- dichloroethylene, or preferably about 66 wt.% trans-1,2-dichloroethylene. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 44.20°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0045] In other words, the azeotrope or azeotrope-like composition may comprise from about 20 wt.% to about 55 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 45 wt.% to about 80 wt.% trans-1,2-dichloroethylene, or from about 29 wt.% to about 45 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 55 wt.% to about 71 wt.% trans-1,2-dichloroethylene, or about 34 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and about 66 wt.% trans-1,2-dichloroethylene. The azeotrope or azeotrope-like composition may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and trans-1,2-dichloroethylene in the above amounts, or consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and trans-1,2-dichloroethylene in the above amounts. [0046] Preferably, the azeotrope or azeotrope-like composition has a boiling point of about 44.20°C + 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0047] Stated alternatively, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 1 wt.%, about 10 wt.% or about 15 wt.%, or as great as about 40 wt.%, about 50 wt.% or about 70 wt.% 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane, or within any range defined between any two of the foregoing values, and the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 30 wt.%, about 50 wt.% or about 60 wt.%, or as great as about 85 wt.%, about 90 wt.% or about 99 wt.% trans-1,2-dichloroethylene, or within any range defined between any two of the foregoing values. In one embodiment, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, about 34 wt.% and 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 66 wt.% of trans-1,2-dichloroethylene. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 44.20°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0048] The present disclosure also provides a composition comprising the azeotrope or azeotrope-like composition. For example, there is provided a composition comprising at least about 5 wt.% of the azeotrope or azeotrope-like composition, or at least about 15 wt.% of the azeotrope or azeotrope-like composition, or at least about 50 wt.% of the azeotrope or azeotrope-like composition, or at least about 70 wt.% of the azeotrope or azeotrope-like composition, or at least about 90 wt.% of the azeotrope or azeotrope-like composition. [0049] The following non-limiting Example serves to illustrate the disclosure. Example 1 – Ebulliometer Study [0050] Boiling point temperature was measured using an isobaric ebulliometer including reboiler, twin-armed Cottrell pumps, an equilibrium temperature well, a chilled reflux condenser, and a pressure controller. The top, or reflux condenser, of each ebulliometer was cooled with a circulating, chilled fluid (50/50 water/propylene glycol) to attain a temperature between 0 to 15°C, which is significantly lower than the normal boiling points of 71.9°C for 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and 47.7°C for trans-1,2-dichloroethylene at a pressure of 14.7 psia, set by the attached pressure controller. In this manner, it was ensured that all vapors in the ebulliometer were condensed and flowed along the equilibrium temperature well and ultimately back into the reboiler. Inserted into the temperature well was a calibrated resistance temperature detector (RTD) with an accuracy of ± 0.01°C. [0051] The isobaric ebulliometer was used to measure the boiling point temperature of pure and mixed fluids at ambient pressure. The ebulliometer was charged with an initial fluid, measured with a mass that occupies the reboiler volume and which permits reflux. When the temperature of the condensing fluid reached a constant value, the second fluid was added to the measurement flask in measured increments. Sufficient time delay was allowed between additions of the second fluid to achieve proper mixing of the two fluids and thermodynamic equilibration as indicated by stabilization of the temperature. [0052] The measurement was carried out by first introducing 50 grams of trans-1,2- dichloroethylene having a purity of >99 area% as determined by gas chromatography (GC) into the ebulliometer by weighing the container before and after the addition using a balance having an accuracy of ± 0.01g. The liquid was brought to a boil and the equilibrium temperature of the trans-1,2-dichloroethylene was recorded at the set pressure of 14.7 psia. Then, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane having a purity of > 99 area% as determined by gas chromatography (GC) was introduced into the ebulliometer in small, measured increments via an automated syringe pump. After a predetermined amount of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane was added to the ebulliometer, the system was allowed to reach equilibrium for approximately five minutes before the equilibrium temperature of the condensing vapor-liquid mixture was recorded. Once the ebulliometer was full from these additions, the system was reset, and the same procedure was followed starting with 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane, incrementing in trans-1,2-dichloroethylene. [0053] Composition versus boiling point data was obtained for the composition range from 0-100 weight percent of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and is presented below in Table 1, which shows a minimum in temperature which indicates that an azeotrope had been formed, and this data is also presented in graphic form in Fig.1. [0054] A minimum boiling point temperature was observed at 34 wt.% + 0.3 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane in the temperature versus weight percent 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane curve (Fig.1), indicating a minimum boiling azeotrope. Select temperature and composition data are shown in Table 1 below. Table 1 Composition HFIP-TFE/trans-1,2-DCE vs Boiling Point Temperature

III. Azeotrope or azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and ethanol [0055] The present composition provides for compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and ethanol, alternatively compositions consisting essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and ethanol, and alternatively compositions consisting of 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and ethanol. [0056] In the above compositions, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) may be present in an amount preferably from about 75 wt.% to about 97 wt.%, preferably from about 79 wt.% to about 95 wt.%, or preferably about 91 wt.%. The ethanol may be present in an amount preferably from about 3 wt.% to about 25 wt.%, preferably from about 5 wt.% to 21 wt.%, or preferably about 9 wt.%. [0057] It has also been found that 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) forms homogeneous, minimum boiling azeotrope and azeotrope-like compositions or mixtures with ethanol, and the present disclosure provides homogeneous azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and ethanol. The azeotrope or azeotrope-like compositions may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol, or the azeotrope or azeotrope-like compositions may consist of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol. [0058] The present inventors have found experimentally that 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and ethanol form an azeotrope or azeotrope-like composition. [0059] The present disclosure provides an azeotrope or azeotrope-like composition which comprises effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol to form an azeotrope or azeotrope-like composition. As used herein, the term “effective amount” is an amount of each component which, when combined with the other component, results in the formation of an azeotrope or azeotrope-like mixture. [0060] The present azeotrope or azeotrope-like compositions may consist essentially of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol, or consist of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol. [0061] The present disclosure also provides a method of forming an azeotrope or azeotrope-like composition by mixing, combining, or blending, effective amounts of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be used in the present methods. For example, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and ethanol can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. Both 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and ethanol are commercially available and can be procured from several different vendors. The components can be provided in the required amounts, for example by weighing and then combining the amounts. [0062] Preferably, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, from about 75 wt.% to about 97 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane, preferably from about 79 wt.% to about 95 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, or preferably about 91 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, and preferably from about 3 wt.% to about 25 wt.% ethanol, preferably from about 5 wt.% to about 21 wt.% ethanol, or preferably about 9 wt.% ethanol. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 66.77°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0063] In other words, the azeotrope or azeotrope-like composition may comprise from about 75 wt.% to about 97 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 3 wt.% to about 25 wt.% ethanol, or from about 79 wt.% to about 95 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 5 wt.% to about 21 wt.% ethanol, or about 91 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 9 wt.% ethanol. The azeotrope or azeotrope-like composition may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol in the above amounts, or consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and ethanol in the above amounts. [0064] Preferably, the azeotrope or azeotrope-like composition has a boiling point of about 66.77°C + 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0065] Stated alternatively, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 30 wt.%, about 70 wt.% or about 80 wt.%, or as great as about 90 wt.%, about 96 wt.% or about 98 wt.% 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane, or within any range defined between any two of the foregoing values, and the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 2 wt.%, about 4 wt.% or about 10 wt.%, or as great as about 20 wt.%, about 30 wt.% or about 70 wt.% ethanol, or within any range defined between any two of the foregoing values. In one embodiment, the azeotrope or azeotrope- like composition comprises, consists essentially of, or consists of, about 91 wt.% and 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 9 wt.% of ethanol. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 66.77°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0066] The present disclosure also provides a composition comprising the azeotrope or azeotrope-like composition. For example, there is provided a composition comprising at least about 5 wt.% of the azeotrope or azeotrope-like composition, or at least about 15 wt.% of the azeotrope or azeotrope-like composition, or at least about 50 wt.% of the azeotrope or azeotrope-like composition, or at least about 70 wt.% of the azeotrope or azeotrope-like composition, or at least about 90 wt.% of the azeotrope or azeotrope-like composition. [0067] The following non-limiting Example serves to illustrate the disclosure. Example 2 – Ebulliometer Study [0068] The isobaric ebulliometer described in Example 1 was used to measure the boiling point temperature of pure and mixed fluids at ambient pressure. Approximately 50 grams of a first fluid was charged into the reboiler and heated to reflux. When the temperature of the condensing fluid reached a constant value, the second fluid was added to the measurement flask in measured increments. Sufficient time delay was allowed between additions of the second fluid to achieve proper mixing of the two fluids and thermodynamic equilibration as indicated by stabilization of the temperature. The second fluid was not added to the control flask. Rather, the control flask was used to confirm constant pressure throughout the duration of the experiment by measuring an invariable boiling point for the pure first fluid. [0069] The measurement was carried out by first introducing 50 grams of ethanol having a purity of >99 area% as determined by gas chromatography (GC) into the ebulliometer by weighing the container before and after the addition using a balance having an accuracy of ± 0.01g. The liquid was brought to a boil and the equilibrium temperature of the ethanol was recorded at the set pressure of 14.7 psia. Then, 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane having a purity of > 99 area% as determined by gas chromatography (GC) was introduced into the measurement flask in small, measured increments via an automated syringe pump. After a predetermined amount of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane was added to the ebulliometer, the system was allowed to reach equilibrium for approximately five minutes before the equilibrium temperature of the condensing vapor-liquid mixture was recorded. Once the ebulliometer was full from these additions, the system was reset, and the same procedure was followed starting with 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane, incrementing in ethanol. [0070] Composition versus boiling point data was obtained for the composition range from 0-100 weight percent of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and is presented below in Table 2, which shows a minimum in temperature which indicates that an azeotrope had been formed, and this data is also presented in graphic form in Fig.2. [0071] A minimum boiling point temperature was observed at 91 wt.% + 0.3 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane in the temperature versus weight percent 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane curve (Fig.2) indicating a minimum boiling azeotrope. Select temperature and composition data are shown in Table 2 below. Table 2 Composition HFIP-TFE/Ethanol vs Boiling Point Temperature

IV. Azeotrope or azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and isopropanol [0072] The present composition provides for compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and isopropanol, alternatively compositions consisting essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and isopropanol, and alternatively compositions consisting of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and isopropanol. [0073] In the above compositions, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) may be present in an amount preferably from about 80 wt.% to about 99 wt.%, preferably from about 85 wt.% to about 95 wt.%, or preferably about 92 wt.%. The isopropanol may be present in an amount preferably from about 1 wt.% to about 20 wt.%, preferably from about 5 wt.% to about 15 wt.%, or preferably about 8 wt.%. [0074] It has also been found that 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) forms homogeneous, minimum boiling azeotrope and azeotrope-like compositions or mixtures with isopropanol, and the present disclosure provides homogeneous azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and isopropanol. The azeotrope or azeotrope- like compositions may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and isopropanol, or the azeotrope or azeotrope-like compositions may consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and isopropanol. [0075] The present inventors have found experimentally that 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and isopropanol form an azeotrope or azeotrope-like composition. [0076] The present disclosure provides an azeotrope or azeotrope-like composition which comprises effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and isopropanol to form an azeotrope or azeotrope-like composition. As used herein, the term “effective amount” is an amount of each component which, when combined with the other component, results in the formation of an azeotrope or azeotrope-like mixture. [0077] The present azeotrope or azeotrope-like compositions may consist essentially of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and isopropanol, or consist of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and isopropanol. [0078] The present disclosure also provides a method of forming an azeotrope or azeotrope-like composition by mixing, combining, or blending, effective amounts of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and isopropanol. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be used in the present methods. For example, 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and isopropanol can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. Both 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and isopropanol are commercially available and can be procured from several different vendors. The components can be provided in the required amounts, for example by weighing and then combining the amounts. [0079] Preferably, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, from about 80 wt.% to about 99 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane, preferably from about 85 wt.% to about 95 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, preferably or about 92 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, and preferably from about 1 wt.% to about 20 wt.% isopropanol, preferably from about 5 wt.% to about 15 wt.% isopropanol, or preferably about 8 wt.% isopropanol. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 69.60°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0080] In other words, the azeotrope or azeotrope-like composition may comprise from about 80 wt.% to about 99 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 1 wt.% to about 20 wt.% isopropanol, or from about 85 wt.% to about 95 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 5 wt.% to about 15 wt.% isopropanol, or about 92 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 8 wt.% isopropanol. The azeotrope or azeotrope-like composition may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and isopropanol in the above amounts, or consist of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and isopropanol in the above amounts. [0081] Preferably, the azeotrope or azeotrope-like composition has a boiling point of about 69.60°C + 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0082] Stated alternatively, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 30 wt.%, about 70 wt.% or about 80 wt.%, or as great as about 90 wt.%, about 96 wt.% or about 98 wt.% 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane, or within any range defined between any two of the foregoing values, and the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 2 wt.%, about 4 wt.% or about 10 wt.%, or as great as about 20 wt.%, about 30 wt.% or about 70 wt.% isopropanol, or within any range defined between any two of the foregoing values. In one embodiment, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, about 92 wt.% and 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 8 wt.% of isopropanol. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 69.60°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0083] The present disclosure also provides a composition comprising the azeotrope or azeotrope-like composition. For example, there is provided a composition comprising at least about 5 wt.% of the azeotrope or azeotrope-like composition, or at least about 15 wt.% of the azeotrope or azeotrope-like composition, or at least about 50 wt.% of the azeotrope or azeotrope-like composition, or at least about 70 wt.% of the azeotrope or azeotrope-like composition, or at least about 90 wt.% of the azeotrope or azeotrope-like composition. [0084] The following non-limiting Example serves to illustrate the disclosure. Example 3 – Ebulliometer Study [0085] The isobaric ebulliometer described in Example 1 was used to measure the boiling point temperature of pure and mixed fluids at ambient pressure. Approximately 50 grams of a first fluid was charged into the reboiler and heated to reflux. When the temperature of the condensing fluid reached a constant value, the second fluid was added to the measurement flask in measured increments. Sufficient time delay was allowed between additions of the second fluid to achieve proper mixing of the two fluids and thermodynamic equilibration as indicated by stabilization of the temperature. The second fluid was not added to the control flask. Rather, the control flask was used to confirm constant pressure throughout the duration of the experiment by measuring an invariable boiling point for the pure first fluid. [0086] The measurement was carried out by first introducing 50 of isopropanol having a purity of >99 area% as determined by gas chromatography (GC) into the ebulliometer by weighing the container before and after the addition using a balance having an accuracy of ± 0.01g. The liquid was brought to a boil and the equilibrium temperature of the 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane was recorded at the set pressure of 14.7 psia. Then, isopropanol having a purity of > 99 area% as determined by gas chromatography (GC) was introduced into the measurement flask in small, measured increments via an automated syringe pump. After a predetermined amount of isopropanol was added to the ebulliometer, the system was allowed to reach equilibrium for approximately five minutes before the equilibrium temperature of the condensing vapor-liquid mixture was recorded. [0087] Composition versus boiling point data was obtained for the composition range from 0-100 weight percent of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and is presented below in Table 3, which shows a minimum in temperature which indicates that an azeotrope had been formed, and this data is also presented in graphic form in Fig.3. [0088] A minimum boiling point temperature was observed at 92 wt.% + 0.3 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane in the temperature versus weight percent 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane curve (Fig.3), indicating a minimum boiling azeotrope. Select temperature and composition data are shown in Table 3 below. Table 3 Composition HFIP-TFE/Isopropanol vs Boiling Point Temperature

V. Azeotrope or azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and cis-1,2-dichloroethylene (cis-DCE) [0089] The present composition provides for compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and cis-1,2-dichloroethylene, alternatively compositions consisting essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and cis-1,2-dichloroethylene, and alternatively compositions consisting of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP- TFE) and cis-1,2-dichloroethylene. [0090] In the above compositions, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) may be present in an amount preferably from about 30 wt.% to about 65 wt.%, preferably from about 44 wt.% to about 62 wt.%, or preferably about 58 wt.%. The cis-1,2-dichloroethylene (cis-DCE) may be present in an amount preferably from about 35 wt.% to about 70 wt.%, preferably from about 38 wt.% to about 56 wt.%, or preferably about 42 wt.%. [0091] It has also been found that 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) forms homogeneous, minimum boiling azeotrope and azeotrope-like compositions or mixtures with cis-1,2-dichloroethylene, and the present disclosure provides homogeneous azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cis-1,2-dichloroethylene. The azeotrope or azeotrope-like compositions may consist essentially of 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and cis-1,2-dichloroethylene, or the azeotrope or azeotrope- like compositions may consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cis-1,2-dichloroethylene. [0092] The present disclosure provides an azeotrope or azeotrope-like composition which comprises effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cis-1,2-dichloroethylene to form an azeotrope or azeotrope-like composition. As used herein, the term “effective amount” is an amount of each component which, when combined with the other component, results in the formation of an azeotrope or azeotrope-like mixture. [0093] The present azeotrope or azeotrope-like compositions may consist essentially of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cis-1,2- dichloroethylene, or consist of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and cis-1,2-dichloroethylene. [0094] The present disclosure also provides a method of forming an azeotrope or azeotrope-like composition by mixing, combining, or blending, effective amounts of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cis-1,2-dichloroethylene. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be used in the present methods. For example, 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and cis-1,2-dichloroethylene can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. Both 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and cis-1,2-dichloroethylene are commercially available and can be procured from several different vendors. The components can be provided in the required amounts, for example by weighing and then combining the amounts. [0095] Preferably, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, from about 30 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane, preferably from about 44 wt.% to about 62 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, or preferably about 58 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, and preferably from about 35 wt.% to about 70 wt.% cis-1,2-dichloroethylene, preferably from about 38 wt.% to about 56 wt.% cis-1,2- dichloroethylene, or preferably about 42 wt.% cis-1,2-dichloroethylene. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 56.7°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0096] In other words, the azeotrope or azeotrope-like composition may comprise from about 30 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 35 wt.% to about 70 wt.% cis-1,2-dichloroethylene, or from about 44 wt.% to about 62 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 38 wt.% to about 56 wt.% cis-1,2-dichloroethylene, or about 58 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and about 42 wt.% cis-1,2-dichloroethylene. The azeotrope or azeotrope-like composition may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and cis-1,2-dichloroethylene in the above amounts, or consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cis-1,2-dichloroethylene in the above amounts. [0097] Preferably, the azeotrope or azeotrope-like composition has a boiling point of about 56.7°C + 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0098] Stated alternatively, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 30 wt.%, about 70 wt.% or about 80 wt.%, or as great as about 90 wt.%, about 96 wt.% or about 98 wt.% 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane, or within any range defined between any two of the foregoing values, and the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 2 wt.%, about 4 wt.% or about 10 wt.%, or as great as about 20 wt.%, about 30 wt.% or about 70 wt.% cis-1,2-dichloroethylene, or within any range defined between any two of the foregoing values. In one embodiment, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, about 58 wt.% and 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 42 wt.% of cis-1,2-dichloroethylene. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 56.7°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [0099] The present disclosure also provides a composition comprising the azeotrope or azeotrope-like composition. For example, there is provided a composition comprising at least about 5 wt.% of the azeotrope or azeotrope-like composition, or at least about 15 wt.% of the azeotrope or azeotrope-like composition, or at least about 50 wt.% of the azeotrope or azeotrope-like composition, or at least about 70 wt.% of the azeotrope or azeotrope-like composition, or at least about 90 wt.% of the azeotrope or azeotrope-like composition. VI. Azeotrope or azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and methanol [00100] The present composition provides for compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and methanol, alternatively compositions consisting essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and methanol, and alternatively compositions consisting of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and methanol. [00101] In the above compositions, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) may be present in an amount preferably from about 75 wt.% to about 93 wt.%, preferably from about 80 wt.% to about 89 wt.%, or preferably about 86 wt.%. The methanol may be present in an amount preferably from about 7 wt.% to about 25 wt.%, preferably from about 11 wt.% to about 20 wt.%, or preferably about 14 wt.%. [00102] It has also been found that 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) forms homogeneous, minimum boiling azeotrope and azeotrope-like compositions or mixtures with methanol, and the present disclosure provides homogeneous azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and methanol. The azeotrope or azeotrope-like compositions may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and methanol, or the azeotrope or azeotrope-like compositions may consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and methanol. [00103] The present disclosure provides an azeotrope or azeotrope-like composition which comprises effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and methanol to form an azeotrope or azeotrope-like composition. As used herein, the term “effective amount” is an amount of each component which, when combined with the other component, results in the formation of an azeotrope or azeotrope-like mixture. [00104] The present azeotrope or azeotrope-like compositions may consist essentially of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and methanol, or consist of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and methanol. [00105] The present disclosure also provides a method of forming an azeotrope or azeotrope-like composition by mixing, combining, or blending, effective amounts of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and methanol. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be used in the present methods. For example, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and methanol can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. Both 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and methanol are commercially available and can be procured from several different vendors. The components can be provided in the required amounts, for example by weighing and then combining the amounts. [00106] Preferably, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, from about 75 wt.% to about 93 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane, preferably from about 80 wt.% to about 89 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, or preferably about 86 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, and preferably from about 7 wt.% to about 25 wt.% methanol, preferably from about 11 wt.% to about 20 wt.% methanol, or preferably about 14 wt.% methanol. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 53.4°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00107] In other words, the azeotrope or azeotrope-like composition may comprise from about 75 wt.% to about 93 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 7 wt.% to about 25 wt.% methanol, or from about 80 wt.% to about 89 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 11 wt.% to about 20 wt.% methanol, or about 86 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 14 wt.% methanol. The azeotrope or azeotrope-like composition may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and methanol in the above amounts, or consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and methanol in the above amounts. [00108] Preferably, the azeotrope or azeotrope-like composition has a boiling point of about 53.4°C + 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00109] Stated alternatively, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 30 wt.%, about 70 wt.% or about 80 wt.%, or as great as about 90 wt.%, about 96 wt.% or about 98 wt.% 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane, or within any range defined between any two of the foregoing values, and the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 2 wt.%, about 4 wt.% or about 10 wt.%, or as great as about 20 wt.%, about 30 wt.% or about 70 wt.% methanol, or within any range defined between any two of the foregoing values. In one embodiment, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, about 86 wt.% and 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 14 wt.% of methanol. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 53.4°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00110] The present disclosure also provides a composition comprising the azeotrope or azeotrope-like composition. For example, there is provided a composition comprising at least about 5 wt.% of the azeotrope or azeotrope-like composition, or at least about 15 wt.% of the azeotrope or azeotrope-like composition, or at least about 50 wt.% of the azeotrope or azeotrope-like composition, or at least about 70 wt.% of the azeotrope or azeotrope-like composition, or at least about 90 wt.% of the azeotrope or azeotrope-like composition. VII. Azeotrope or azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and diisopropylether [00111] The present composition provides for compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and diisopropylether, alternatively compositions consisting essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and diisopropylether, and alternatively compositions consisting of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and diisopropylether. [00112] In the above compositions, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) may be present in an amount preferably from about 35 wt.% to about 66 wt.%, preferably from about 42 wt.% to about 57 wt.%, or preferably about 49 wt.%. The diisopropylether may be present in an amount preferably from about 34 wt.% to about 65 wt.%, preferably from about 43 wt.% to about 58 wt.%, or preferably about 51 wt.%. [00113] It has also been found that 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) forms homogeneous, minimum boiling azeotrope and azeotrope-like compositions or mixtures with diisopropylether, and the present disclosure provides homogeneous azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and diisopropylether. The azeotrope or azeotrope-like compositions may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and diisopropylether, or the azeotrope or azeotrope-like compositions may consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and diisopropylether. [00114] The present disclosure provides an azeotrope or azeotrope-like composition which comprises effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and diisopropylether to form an azeotrope or azeotrope-like composition. As used herein, the term “effective amount” is an amount of each component which, when combined with the other component, results in the formation of an azeotrope or azeotrope-like mixture. [00115] The present azeotrope or azeotrope-like compositions may consist essentially of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and diisopropylether, or consist of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and diisopropylether. [00116] The present disclosure also provides a method of forming an azeotrope or azeotrope-like composition by mixing, combining, or blending, effective amounts of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and diisopropylether. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be used in the present methods. For example, 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and diisopropylether can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. Both 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and diisopropylether are commercially available and can be procured from several different vendors. The components can be provided in the required amounts, for example by weighing and then combining the amounts. [00117] Preferably, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, from about 34 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane, preferably from about 43 wt.% to about 58 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, or preferably about 51 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, and preferably from about 35 wt.% to about 66 wt.% diisopropylether, preferably from about 42 wt.% to about 57 wt.% diisopropylether, or preferably about 49 wt.% diisopropylether. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 64.2°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00118] In other words, the azeotrope or azeotrope-like composition may comprise from about 34 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 35 wt.% to about 66 wt.% diisopropylether, or from about 43 wt.% to about 58 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 42 wt.% to about 57 wt.% diisopropylether, or about 51 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 49 wt.% diisopropylether. The azeotrope or azeotrope-like composition may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and diisopropylether in the above amounts, or consist of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and diisopropylether in the above amounts. [00119] Preferably, the azeotrope or azeotrope-like composition has a boiling point of about 64.2°C + 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00120] Stated alternatively, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 30 wt.%, about 70 wt.% or about 80 wt.%, or as great as about 90 wt.%, about 96 wt.% or about 98 wt.% 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane, or within any range defined between any two of the foregoing values, and the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 2 wt.%, about 4 wt.% or about 10 wt.%, or as great as about 20 wt.%, about 30 wt.% or about 70 wt.% diisopropylether, or within any range defined between any two of the foregoing values. In one embodiment, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, about 51 wt.% and 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 49 wt.% of diisopropylether. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 64.2°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00121] The present disclosure also provides a composition comprising the azeotrope or azeotrope-like composition. For example, there is provided a composition comprising at least about 5 wt.% of the azeotrope or azeotrope-like composition, or at least about 15 wt.% of the azeotrope or azeotrope-like composition, or at least about 50 wt.% of the azeotrope or azeotrope-like composition, or at least about 70 wt.% of the azeotrope or azeotrope-like composition, or at least about 90 wt.% of the azeotrope or azeotrope-like composition. VIII. Azeotrope or azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and acetone [00122] The present composition provides for compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and acetone, alternatively compositions consisting essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and acetone, and alternatively compositions consisting of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and acetone. [00123] In the above compositions, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) may be present in an amount preferably from about 33 wt.% to about 64 wt.%, preferably from about 34 wt.% to about 49 wt.%, or preferably about 35 wt.%. The acetone may be present in an amount preferably from about 36 wt.% to about 67 wt.%, preferably from about 51 wt.% to about 66 wt.%, or preferably about 65 wt.%. [00124] It has also been found that 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) forms homogeneous, minimum boiling azeotrope and azeotrope-like compositions or mixtures with acetone, and the present disclosure provides homogeneous azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and acetone. The azeotrope or azeotrope-like compositions may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and acetone, or the azeotrope or azeotrope-like compositions may consist of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and acetone. [00125] The present disclosure provides an azeotrope or azeotrope-like composition which comprises effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and acetone to form an azeotrope or azeotrope-like composition. As used herein, the term “effective amount” is an amount of each component which, when combined with the other component, results in the formation of an azeotrope or azeotrope-like mixture. [00126] The present azeotrope or azeotrope-like compositions may consist essentially of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and acetone, or consist of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and acetone. [00127] The present disclosure also provides a method of forming an azeotrope or azeotrope-like composition by mixing, combining, or blending, effective amounts of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and acetone. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be used in the present methods. For example, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and acetone can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. Both 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and acetone are commercially available and can be procured from several different vendors. The components can be provided in the required amounts, for example by weighing and then combining the amounts. [00128] Preferably, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, from about 33 wt.% to about 64 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane, preferably from about 34 wt.% to about 49 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, or preferably about 35 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, and preferably from about 36 wt.% to about 67 wt.% acetone, preferably from about 51 wt.% to about 66 wt.% acetone, or preferably about 65 wt.% acetone. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 55.4°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00129] In other words, the azeotrope or azeotrope-like composition may comprise from about 33 wt.% to about 64 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 36 wt.% to about 67 wt.% acetone, or from about 34 wt.% to about 49 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 51 wt.% to about 66 wt.% acetone, or about 35 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 65 wt.% acetone. The azeotrope or azeotrope-like composition may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and acetone in the above amounts, or consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and acetone in the above amounts. [00130] Preferably, the azeotrope or azeotrope-like composition has a boiling point of about 55.4°C + 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00131] Stated alternatively, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 30 wt.%, about 70 wt.% or about 80 wt.%, or as great as about 90 wt.%, about 96 wt.% or about 98 wt.% 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane, or within any range defined between any two of the foregoing values, and the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 2 wt.%, about 4 wt.% or about 10 wt.%, or as great as about 20 wt.%, about 30 wt.% or about 70 wt.% acetone, or within any range defined between any two of the foregoing values. In one embodiment, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, about 35 wt.% and 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 65 wt.% of acetone. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 55.4°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00132] The present disclosure also provides a composition comprising the azeotrope or azeotrope-like composition. For example, there is provided a composition comprising at least about 5 wt.% of the azeotrope or azeotrope-like composition, or at least about 15 wt.% of the azeotrope or azeotrope-like composition, or at least about 50 wt.% of the azeotrope or azeotrope-like composition, or at least about 70 wt.% of the azeotrope or azeotrope-like composition, or at least about 90 wt.% of the azeotrope or azeotrope-like composition. IX. Azeotrope or azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and pentane [00133] The present composition provides for compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and pentane, alternatively compositions consisting essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and pentane, and alternatively compositions consisting of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and pentane. [00134] In the above compositions, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) may be present in an amount preferably from about 22 wt.% to about 65 wt.%, preferably from about 28 wt.% to about 50 wt.%, or preferably about 34 wt.%. The pentane may be present in an amount preferably from about 35 wt.% to about 78 wt.%, preferably about 50 wt.% to about 72 wt.%, or preferably about 66 wt.%. [00135] It has also been found that 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) forms homogeneous, minimum boiling azeotrope and azeotrope-like compositions or mixtures with pentane, and the present disclosure provides homogeneous azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane and pentane. The azeotrope or azeotrope-like compositions may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and pentane, or the azeotrope or azeotrope-like compositions may consist of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and pentane. [00136] The present disclosure provides an azeotrope or azeotrope-like composition which comprises effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and pentane to form an azeotrope or azeotrope-like composition. As used herein, the term “effective amount” is an amount of each component which, when combined with the other component, results in the formation of an azeotrope or azeotrope-like mixture. [00137] The present azeotrope or azeotrope-like compositions may consist essentially of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and pentane, or consist of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and pentane. [00138] The present disclosure also provides a method of forming an azeotrope or azeotrope-like composition by mixing, combining, or blending, effective amounts of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and pentane. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be used in the present methods. For example, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and pentane can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. Both 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and pentane are commercially available and can be procured from several different vendors. The components can be provided in the required amounts, for example by weighing and then combining the amounts. [00139] Preferably, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, preferably from about 22 wt.% to about 65 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, preferably from about 28 wt.% to about 50 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane, or preferably about 34 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane, and preferably from about 35 wt.% to about 78 wt.% pentane, preferably from about 50 wt.% to about 72 wt.% pentane, or preferably about 66 wt.% pentane. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 34.9°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00140] In other words, the azeotrope or azeotrope-like composition may comprise from about 22 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 35 wt.% to about 78 wt.% pentane, or from about 28 wt.% to about 50 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 50 wt.% to about 72 wt.% pentane, or about 34 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 66 wt.% pentane. The azeotrope or azeotrope-like composition may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and pentane in the above amounts, or consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and pentane in the above amounts. [00141] Preferably, the azeotrope or azeotrope-like composition has a boiling point of about 34.9°C + 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00142] Stated alternatively, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 30 wt.%, about 70 wt.% or about 80 wt.%, or as great as about 90 wt.%, about 96 wt.% or about 98 wt.% 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane, or within any range defined between any two of the foregoing values, and the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 2 wt.%, about 4 wt.% or about 10 wt.%, or as great as about 20 wt.%, about 30 wt.% or about 70 wt.% pentane, or within any range defined between any two of the foregoing values. In one embodiment, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, about 34 wt.% and 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 66 wt.% of pentane. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 34.9°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00143] The present disclosure also provides a composition comprising the azeotrope or azeotrope-like composition. For example, there is provided a composition comprising at least about 5 wt.% of the azeotrope or azeotrope-like composition, or at least about 15 wt.% of the azeotrope or azeotrope-like composition, or at least about 50 wt.% of the azeotrope or azeotrope-like composition, or at least about 70 wt.% of the azeotrope or azeotrope-like composition, or at least about 90 wt.% of the azeotrope or azeotrope-like composition. X. Azeotrope or azeotrope-like compositions of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) and cyclopentane [00144] The present composition provides for compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and cyclopentane, alternatively compositions consisting essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and cyclopentane, and alternatively compositions consisting of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) and cyclopentane. [00145] In the above compositions, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) may be present in an amount preferably from about 27 wt.% to about 70 wt.%, preferably from about 38 wt.% to about 59 wt.%, or preferably about 49 wt.%. The cyclopentane may be present in an amount preferably from about 30 wt.% to about 73 wt.%, preferably from about 41 wt.% to about 62 wt.%, or preferably about 51 wt.%. [00146] It has also been found that 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane (HFIP-TFE) forms homogeneous, minimum boiling azeotrope and azeotrope-like compositions or mixtures with cyclopentane, and the present disclosure provides homogeneous azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cyclopentane. The azeotrope or azeotrope- like compositions may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and cyclopentane, or the azeotrope or azeotrope-like compositions may consist of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cyclopentane. [00147] The present disclosure provides an azeotrope or azeotrope-like composition which comprises effective amounts of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cyclopentane to form an azeotrope or azeotrope-like composition. As used herein, the term “effective amount” is an amount of each component which, when combined with the other component, results in the formation of an azeotrope or azeotrope-like mixture. [00148] The present azeotrope or azeotrope-like compositions may consist essentially of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cyclopentane, or consist of combinations of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cyclopentane. [00149] The present disclosure also provides a method of forming an azeotrope or azeotrope-like composition by mixing, combining, or blending, effective amounts of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cyclopentane. Any of a wide variety of methods known in the art for combining two or more components to form a composition can be used in the present methods. For example, 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and cyclopentane can be mixed, blended, or otherwise combined by hand and/or by machine, as part of a batch or continuous reaction and/or process, or via combinations of two or more such steps. Both 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and cyclopentane are commercially available and can be procured from several different vendors. The components can be provided in the required amounts, for example by weighing and then combining the amounts. [00150] Preferably, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, from about 27 wt.% to about 70 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane, preferably from about 38 wt.% to about 59 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, or preferably about 49 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane, and preferably from about 30 wt.% to about 73 wt.% cyclopentane, from about 41 wt.% to about 62 wt.% cyclopentane, or preferably about 51 wt.% cyclopentane. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 45.8°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00151] In other words, the azeotrope or azeotrope-like composition may comprise from about 27 wt.% to about 70 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 30 wt.% to about 73 wt.% cyclopentane, or from about 38 wt.% to about 59 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 41 wt.% to about 62 wt.% cyclopentane, or about 49 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 51 wt.% cyclopentane. The azeotrope or azeotrope-like composition may consist essentially of 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and cyclopentane in the above amounts, or consist of 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and cyclopentane in the above amounts. [00152] Preferably, the azeotrope or azeotrope-like composition has a boiling point of about 45.8°C + 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00153] Stated alternatively, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 30 wt.%, about 70 wt.% or about 80 wt.%, or as great as about 90 wt.%, about 96 wt.% or about 98 wt.% 1,1,1,3,3,3-hexafluoro- 2-(2,2,2-trifluoroethoxy)propane, or within any range defined between any two of the foregoing values, and the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, as little as about 2 wt.%, about 4 wt.% or about 10 wt.%, or as great as about 20 wt.%, about 30 wt.% or about 70 wt.% cyclopentane, or within any range defined between any two of the foregoing values. In one embodiment, the azeotrope or azeotrope-like composition comprises, consists essentially of, or consists of, about 49 wt.% and 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and about 51 wt.% of cyclopentane. Preferably, the azeotrope or azeotrope-like composition of the present disclosure has a boiling point of about 45.8°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00154] The present disclosure also provides a composition comprising the azeotrope or azeotrope-like composition. For example, there is provided a composition comprising at least about 5 wt.% of the azeotrope or azeotrope-like composition, or at least about 15 wt.% of the azeotrope or azeotrope-like composition, or at least about 50 wt.% of the azeotrope or azeotrope-like composition, or at least about 70 wt.% of the azeotrope or azeotrope-like composition, or at least about 90 wt.% of the azeotrope or azeotrope-like composition. XI. Multiple-component azeotrope or azeotrope-like compositions involving 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane (HFIP-TFE) [00155] Binary, or two-component, azeotrope or azeotropic compositions comprising, consisting essentially of, or consisting of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and one other component are described above. [00156] However, the present disclosure also contemplates and encompasses azeotrope or azeotropic compositions comprising, consisting essentially of, or consisting of, 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and two or more other components which are selected from those discussed above in Sections II-X. For example, the present disclosure also contemplates and encompasses a ternary azeotrope or azeotropic composition of 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane, trans-1,2- dichloroethylene, and isopropanol. XII. Heat Transfer Fluids 1. Introduction [00157] The present azeotropic or azeotrope-like compositions, having components in the relative weight ranges disclosed herein, may be used as heat transfer fluids. [00158] The heat transfer fluid may specifically include azeotrope or azeotrope-like compositions comprising 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and at least one of trans-1,2-dichloroethyylene, ethanol, isopropanol, cis-1,2-dichloroethylene, methanol, diisopropylether, acetone, pentane, and cyclopentane. [00159] When the heat transfer fluid is used in thermal management (e.g. in electronic cooling), it is referred to as a thermal management fluid. When the heat transfer fluid is used in a heat transfer system (e.g. a vapor compression heat transfer system), it is referred to as a refrigerant. [00160] The heat transfer fluid may comprise the azeotrope or azeotrope-like composition in an amount of at least about 5% by weight, or at least about 15% by weight, or at least about 50% by weight, or at least about 70% by weight, or at least about 90% by weight or at least 95 % by weight or at least 99% by weight or the heat transfer fluid may consist essentially of or consist of the azeotrope or azeotrope-like composition. [00161] Preferably, the heat transfer fluid (and therefore also the thermal management fluid or refrigerant) has a low GWP. For example, the heat transfer fluid may have a GWP of not greater than about 1000, or not greater than about 700, or not greater than about 500, or not greater than about 300, or not greater than about 150. [00162] The present disclosure also provides a heat transfer composition comprising a refrigerant. [00163] The heat transfer composition may comprise at least about 5% by weight, or at least about 15% by weight, or at least about 50% by weight, or at least about 70% by weight, or at least about 90% by weight of the refrigerant. [00164] The heat transfer composition may include other components for the purpose of enhancing or providing certain functionality to the composition. [00165] Preferably, the heat transfer composition comprises a lubricant. The lubricant lubricates the refrigeration compressor using the refrigerant. The lubricant may be present in the heat transfer composition in amounts of from about 5% to about 30% by weight of heat transfer composition. Lubricants such as Polyol Esters (POEs), Poly Alkylene Glycols (PAGs), PAG oils, polyvinyl ethers (PVEs), and poly(alpha-olefin) (PAO) and combinations thereof may be used in the heat transfer compositions of the present disclosure. [00166] Preferred lubricants include POEs and PVEs, more preferably POEs. Of course, different mixtures of different types of lubricants may be used. For example, the lubricant may be a PAG if the refrigerant is used in mobile air conditioning applications. [00167] The heat transfer composition of the present disclosure may consist essentially of or consist of a refrigerant and lubricant as described above. [00168] Commercially available mineral oils include Witco LP 250 (registered trademark) from Witco, Zerol 300 (registered trademark) from Shrieve Chemical, Sunisco 3GS from Witco, and Calumet R015 from Calumet. Commercially available alkyl benzene lubricants include Zerol 150 (registered trademark). Commercially available esters include neopentyl glycol dipelargonate, which is available as Emery 2917 (registered trademark) and Hatcol 2370 (registered trademark). Other useful esters include phosphate esters, dibasic acid esters, and fluoroesters. [00169] The heat transfer composition may include a compatibilizer for the purpose of aiding compatibility and/or solubility of the lubricant. Suitable compatibilizers may include propane, butanes, pentanes, and/or hexanes. When present, the compatibilizer is preferably present in an amount of from about 0.5% to about 5% by weight of the heat transfer composition. Combinations of surfactants and solubilizing agents may also be added to the present compositions to aid oil solubility, as disclosed by U.S. Patent No.6,516,837, the disclosure of which is incorporated by reference. 2. Uses and systems [00170] The heat transfer fluid, thermal management fluid, refrigerant and heat transfer compositions of the disclosure may be used for heating and/or cooling. [00171] Thus, the present disclosure provides a method of heating or cooling a fluid or body using a heat transfer fluid, thermal management fluid, refrigerant or heat transfer compositions. [00172] Thermal management [00173] The heat transfer fluid may be used as a thermal management fluid. [00174] In nearly every modern application of electronics, the dissipation of heat is an important consideration. For example, in portable and hand-held devices, the desire to miniaturize while adding functionality increases the thermal power density, which increases the challenge of cooling the electronics within them. As computational power increases within desktop computers, datacenters and telecommunications centers, so does the heat output. Power electronic devices such as the traction inverters in plug-in electric or hybrid vehicles, wind turbines, train engines, generators and various industrial processes make use of transistors that operate at ever higher currents and heat fluxes. [00175] Therefore, the present disclosure relates to an electronic device comprising a thermal management fluid. [00176] The thermal management fluid is designed to transfer heat from a heat- generating component in the electronic device to a heat exchanger (e.g. a condenser) in the electronic device. The thermal management fluid may be recirculated passively or actively, for example by using mechanical equipment such as a pump. Passive recirculating systems work by transferring heat from the heat-generating component to the thermal management fluid until it typically is vaporized, allowing the heated vapor to proceed to a condenser at which it can transfer its heat to the condenser surface and condense back into a liquid, and then allowing the condensed liquid to reflow into the thermal management fluid in contact with the heat-generating component. Passive thermal management systems can include, for example, single phase or two-phase immersion cooling. It will be appreciated that the thermal management fluid may be recirculated in a pumped two-phase system. [00177] The thermal management fluid is typically used in a closed system in the electronic device, which may include at least two heat exchangers. When the thermal management fluid is used to cool the heat- generating component, heat can be transferred from the component to the fluid, usually through a heat exchanger in contact with at least a part of the component or the heat can be transferred to circulating air which can conduct the heat to a heat exchanger that is in thermal contact with the thermal management fluid. Alternatively, the fluid can contact the heat generating component directly. The fluid then, as a warmed fluid or as a vapor, can be circulated to a heat exchanger which takes the heat from the fluid and transfers it to the outside environment. After this heat transfer, the cooled thermal management fluid (cooled or condensed) is recycled. [00178] The electronic device includes a heat-generating component. The heat- generating component can be any component that includes an electronic element that generates heat. Exemplary heat-generating components include semiconductor integrated circuits (ICs), electrochemical cells, power transistors, resistors, and electroluminescent elements. The heat generating component can include, but is not limited to microprocessors, wafers used to manufacture semiconductor devices, power control semiconductors, electrical distribution switch gear, power transformers, circuit boards, multi-chip modules, packaged or unpackaged semiconductor devices, semiconductor integrated circuits, fuel cells, lasers (conventional or laser diodes), light emitting diodes (LEDs), and electrochemical cells, e.g. used for high power applications such as, for example, hybrid or electric vehicles. [00179] Suitable electronic devices include personal computers, microprocessors, servers, cell phones, tablets, digital home appliances (e.g. televisions, media players, games consoles etc.) and personal digital assistants. Datacenters, which are a collection of computer systems and associated components, such as telecommunications and storage systems that generally include redundant or backup power, redundant data communications connections, environmental controls (including, for example, air conditioning and fire suppression), and security devices, are also within the scope of the electronic devices of the disclosure. The electronic device may be a hybrid or electric vehicle. It will also be appreciated that the electric device may be a wind turbine, train engine, or generator. [00180] Uses of refrigerant and heat transfer compositions [00181] The disclosure also provides a heat transfer system comprising a refrigerant or a heat transfer composition. It will be appreciated that the heat transfer systems described herein may be vapor compression systems having an evaporator, a condenser and a compressor in fluid communication. [00182] The refrigerant or heat transfer composition of the disclosure may be used as a secondary fluid. [00183] It will be appreciated that the refrigerant or heat transfer composition of the disclosure may be used in a variety of different heat transfer applications. [00184] Organic Rankine Cycle [00185] The refrigerant or heat transfer composition of the disclosure may be used in an organic Rankine cycle (ORC). In the context of ORC, the refrigerant used in these systems may also be categorized as the “working fluid”. [00186] Rankine cycle systems are known to be a simple and reliable means to convert heat energy into mechanical shaft power. [00187] In industrial settings, it may be possible to use flammable working fluids such as toluene and pentane, particularly when the industrial setting has large quantities of flammables already on site in processes or storage. However, for instances where the risk associated with use of a flammable and/or toxic working fluid is not acceptable, such as power generation in populous areas or near buildings, it is necessary to use non-flammable and/or non-toxic refrigerants as the working fluid. There is also a drive in the industry for these materials to be environmentally acceptable in terms of GWP. [00188] The process for recovering waste heat in an Organic Rankine cycle involves pumping liquid-phase working fluid through a boiler where an external (waste) heat source, such as a process stream, heats the working fluid causing it to evaporate into a saturated or superheated vapor. This vapor is expanded through a turbine wherein the waste heat energy is converted into mechanical energy. Subsequently, the vapor phase working fluid is condensed to a liquid and pumped back to the boiler in order to repeat the heat extraction cycle. [00189] Therefore, the disclosure relates to the use of a refrigerant or heat transfer composition of the disclosure in an Organic Rankine Cycle. [00190] The disclosure also provides a process for converting thermal energy to mechanical energy in a Rankine cycle, the method comprising the steps of i) vaporizing a working fluid with a heat source and expanding the resulting vapor, then ii) cooling the working fluid with a heat sink to condense the vapor, wherein the working fluid is a refrigerant or heat transfer composition of the disclosure. [00191] The mechanical work may be transmitted to an electrical device such as a generator to produce electrical power. [00192] The heat source may be provided by a thermal energy source selected from industrial waste heat, solar energy, geothermal hot water, low pressure steam, distributed power generation equipment utilizing fuel cells, prime movers, or an internal combustion engine. The low pressure steam is a low pressure geothermal steam or is provided by a fossil fuel powered electrical generating power plant. [00193] It will be appreciated that the heat source temperatures can vary widely, for example from about 90ºC to >800ºC, and can be dependent upon a myriad of factors including geography, time of year, etc. for certain combustion gases and some fuel cells. Systems based on sources such as waste water or low pressure steam from, e.g., a plastics manufacturing plants and/or from chemical or other industrial plant, petroleum refinery, and the like, as well as geothermal sources, may have source temperatures that are at or below about 100°C, and in some cases as low as about 90°C or even as low as about 80°C. Gaseous sources of heat such as exhaust gas from combustion process or from any heat source where subsequent treatments to remove particulates and/or corrosive species result in low temperatures may also have source temperatures that are at or below about 130°C, at or below about 120°C, at or below about 100°C, at or below about 100°C, and in some cases as low as about 90°C or even as low as about 80°C. [00194] However, it is preferred that the heat source has a temperature of at least about 200°C, for example of from about 200°C to about 400°C. [00195] Heat pump [00196] The refrigerant or heat transfer composition of the disclosure may be used in a heat pump system. [00197] The present disclosure provides a method of heating a fluid or body using a heat pump, said method comprising the steps of (a) condensing a refrigerant composition of the disclosure in the vicinity of the fluid of body or be heated, and (b) evaporating said refrigerant. [00198] Examples of heat pumps include heat pump tumble driers, reversible heat pumps, and air-to-air heat pumps. The heat pump may also be a heat pump water heater. It will be appreciated that the heat pump may be a high temperature heat pump. By “high temperature heat pump”, it is meant a heat pump that is able to generate temperatures of at least about 80°C, preferably at least about 90°C, more preferably at least about 100°C. [00199] It will be appreciated the heat pump may comprise a suction line/liquid line heat exchanger (SL-LL HX). [00200] Secondary Loop System [00201] The refrigerant or heat transfer compositions of the present disclosure may be used as secondary fluid in a secondary loop system. [00202] A secondary loop system contains a primary vapor compression system loop that uses a primary refrigerant and whose evaporator cools the secondary loop fluid. The secondary fluid then provides the necessary cooling for an application. The secondary fluid must be non-flammable and have low-toxicity since the fluid in such a loop is potentially exposed to humans in the vicinity of the cooled space. In other words, the refrigerant or heat transfer composition of the present disclosure may be used as a “secondary fluid” in a secondary loop system. [00203] The primary fluid used in the primary loop (vapor compression cycle, external/outdoors part of the loop) may be selected from but not limited to HFO-1234ze(E), HFO-1234yf, propane, R455A, R32, R466A, R44B, R290, R717, R452B, R448A, and R449A, preferably HFO-1234ze(E), HFO-1234yf, or propane. [00204] The secondary loop system may be used in refrigeration or air conditioning applications. [00205] In other words, the secondary loop system may be a secondary loop refrigeration system or a secondary loop air conditioning system. [00206] Examples of where secondary loop refrigeration systems may be used include a low temperature refrigeration system, a medium temperature refrigeration system, a commercial refrigerator, a commercial freezer, an industrial freezer, an industrial refrigerator, and a chiller. [00207] Examples of where secondary loop air conditioning systems may be used include in mobile air conditioning systems. Mobile air-conditioning systems including air conditioning of road vehicles such as automobiles, trucks and buses, as well as air conditioning of boats, and trains. For example, where a vehicle contains a battery or electric power source. Alternatively, the secondary loop air conditioning system may be a stationary air conditioning system. Examples of stationary air conditioning systems include a chiller, particularly a positive displacement chiller, more particularly an air cooled or water cooled direct expansion chiller, which is either modular or conventionally singularly packaged, a residential air conditioning system, particularly a ducted split or a ductless split air conditioning system, a residential heat pump, a residential air to water heat pump/hydronic system, an industrial air conditioning system a commercial air conditioning system, particularly a packaged rooftop unit and a variable refrigerant flow (VRF) system; a commercial air source, water source or ground source heat pump system. [00208] It will be appreciated the secondary loop air conditioning or refrigeration system may comprise a suction line/liquid line heat exchanger (SL-LL HX). [00209] Methods [00210] The heat transfer fluids, thermal management fluid, refrigerant or heat transfer compositions of the disclosure may be used as a for existing fluids. [00211] For example, the thermal management fluid of the disclosure may be used as a replacement for existing fluids such as HFC-4310mee, HFE-7100 and HFE-7200. The replacement may be in existing systems, or in new systems. [00212] For example, the refrigerants of the disclosure may be used as a replacement for existing refrigerants such as HFC-245fa, HFC-134a, HFC-404A and HFC-410A. The refrigerant may be used in applications in which the existing refrigerant was previously used. Alternatively, the refrigerant may be used to retrofit an existing refrigerant in an existing system. [00213] The disclosure provides a method of replacing an existing refrigerant in a heat transfer system, said method comprising the steps of (a) removing at least a portion of said existing refrigerant from said system, and subsequently (b) introducing into said system a refrigerant of the disclosure. The existing refrigerants may be selected from HFC-245fa, HFC-134a, HFC-404A and HFC-410A. [00214] Step (a) may involve removing at least about 5 wt.%, at least about 10 wt.%, at least about 15 wt.%, at least about 50 wt.% at least about 70 wt.%, at least about 90 wt.%, at least about 95 wt.%, at least about 99 wt.% or at least about 99.5 wt.% of said existing refrigerant from said system prior to step (b). [00215] The method may optionally comprise the step of flushing said system with a solvent after conducting step (a) and prior to conducting step (b). Example 6 – Heat Transfer Fluid for Electronics Components [00216] Azeotrope or azeotrope-like compositions are prepared in accordance with Sections II-XII above, respectively. [00217] The compositions are used as heat transfer fluids in the form of refrigerants or working fluids in systems wherein the heat generating components are semiconductor integrated circuits (ICs), electrochemical cells, power transistors, resistors, and electroluminescent elements, such as microprocessors, wafers used to manufacture semiconductor devices, power control semiconductors, electrical distribution switch gear, power transformers, circuit boards, multi-chip modules, packaged or unpackaged semiconductor devices, semiconductor integrated circuits, fuel cells, lasers (conventional or laser diodes), light emitting diodes (LEDs), and electrochemical cells, e.g. used for high power applications such as, for example, hybrid or electric vehicles. The compositions demonstrate effective heat transfer properties. Example 7 – Heat Transfer Fluid for Electronics Components [00218] Azeotrope or azeotrope-like compositions are prepared in accordance with Sections II-XII above, respectively. [00219] The compositions are used as heat transfer fluids in the form of refrigerants or working fluids in electronic devices including personal computers, microprocessors, servers, cell phones, tablets, digital home appliances (e.g. televisions, media players, games consoles etc.), personal digital assistants, Datacenters, hybrid or electric vehicles, wind turbine, train engine, or generator, preferably wherein the electronic device is a hybrid or electric vehicle. The compositions demonstrate effective heat transfer properties. Example 8 – Heat Transfer Fluids for ORCs [00220] Azeotrope or azeotrope-like compositions are prepared in accordance with Sections II-XII above, respectively. [00221] The compositions are used as heat transfer fluids in the form of refrigerants or working fluids in a process for converting thermal energy to mechanical energy in an Organic Rankine Cycle (ORC), the method comprising the steps of i) vaporizing a working fluid with a heat source and expanding the resulting vapor, then ii) cooling the working fluid with a heat sink to condense the vapor. The compositions demonstrate effective heat transfer properties. Example 9 – Heat Transfer Fluids for Heat Pumps [00222] The present azeotropic or azeotrope-like compositions, having components in the relative weight ranges disclosed herein, may be used as heat transfer fluids for heat pumps. Azeotrope or azeotrope-like compositions are prepared in accordance with Sections II-XII above, respectively. [00223] The compositions are used as heat transfer fluids in the form of refrigerants or working fluids in a method of heating a fluid or body using a heat pump including the steps of (a) condensing a refrigerant in the vicinity of the fluid of body or be heated, and (b) evaporating said refrigerant. The compositions demonstrate effective heat transfer properties. Example 10 – Heat Transfer Fluid for Secondary Loop Systems [00224] Azeotrope or azeotrope-like compositions are prepared in accordance with Sections II-XII above, respectively. [00225] The compositions are used as heat transfer fluids in the form of refrigerants or working fluids in a primary vapor compression system loop that uses a primary refrigerant and whose evaporator cools a secondary loop fluid with the secondary refrigeration loop system selected from a low temperature refrigeration system, a medium temperature refrigeration system, a commercial refrigerator, a commercial freezer, an industrial freezer, an industrial refrigerator and a chiller. The compositions demonstrate effective heat transfer properties. XIII. Blowing Agents [00226] The present azeotropic or azeotrope-like compositions, having components in the relative weight ranges disclosed herein, may be used as blowing agents for thermosetting foams including but not limited to polyurethane foams, polyisocyanurate foams and phenolic foams. The azeotropic or azeotrope-like compositions may also be used as blowing agents for thermoplastic foams selected from but not limited to polyethylene foams, polypropylene foams, polystyrene foams and polyethylene terephthalate foams. [00227] The present disclosure includes methods and systems which include using one or more of the azeotropic or azeotrope-like compositions disclosed herein as a blowing agents without the presence of any substantial amount of additional components. However, one or more compounds or components that are not within the scope of the azeotropic or azeotrope-like compositions disclosed herein are optionally, but preferably, included in the blowing agent compositions of the present disclosure. Such additional compounds include, but are not limited to, other compounds which also act as blowing agents, (hereinafter referred to for convenience as co-blowing agents), surfactants, polymer modifiers, toughening agents, colorants, dyes, solubility enhancers, rheology modifiers, plasticizing agents, flammability suppressants, antibacterial agents, viscosity reduction modifiers, fillers, vapor pressure modifiers, nucleating agents, catalysts, and the like. In certain preferred embodiments, dispersing agents, cell stabilizers, surfactants, and other additives may also be incorporated into the blowing agent compositions of the present disclosure. [00228] Some surfactants are optionally but preferably added to serve as cell stabilizers. Some representative materials are sold under the names of DC-193, B-8404, and L5340 which are, generally, polysilozane polyoxyalkylene block co-polymers such as those disclosed in U.S Pat. Nos.2,834,748, 2,917,480, and 2,846,458, each of which is incorporated herein by reference. Other optional additives for the blowing agent mixture may include flame retardants such as tri(2-chloro-ethyl)phosphate, tri(2-chloropropyl)phosphate, tri(2,3,-dibromopropyl)-phosphate, various halogenated aromatic compounds, antimony oxide, aluminum trihydrate, polyvinyl chloride, and the like. [00229] With respect to nucleating agents, all known compounds and materials having nucleating functionality are available for use in the present disclosure, including particularly talc. [00230] Of course, other compounds and/or components that modulate a particular property of the compositions (such as cost for example) may also be included in the present azeotropic or azeotrope-like compositions, and the presence of all such compounds and components is within the broad scope of the disclosure. [00231] Thus, in addition to the azeotropic or azeotrope-like compositions disclosed herein, one or more co-blowing agents may also be included. The co-blowing agent in accordance with the present disclosure can comprise a physical blowing agent, a chemical blowing agent (which preferably in certain embodiments comprises water), or a blowing agent having a combination of physical and chemical blowing agent properties. It will also be appreciated that the blowing agents included in the present compositions, include the compounds disclosed herein as well as the co-blowing agent, may exhibit properties in addition to those required to be characterized as a blowing agent. For example, it is contemplated that the blowing agent composition of the present disclosure may include components which also impart some beneficial property to the blowing agent composition or to the foamable composition to which it is added. [00232] Although it is contemplated that a wide range of co-blowing agents may be used in accordance with the present disclosure, in certain embodiments it is preferred that the blowing agent compositions of the present disclosure include one or more HFCs as co- blowing agents, more preferably one or more C1-C4 HFCs, and/or one or more hydrocarbons, more preferably C4-C6 hydrocarbons. For example, with respect to HFCs, the present blowing agent compositions may include one or more of difluoromethane (HFC-32), fluoroethane (HFC-161), difluoroethane (HFC-152), trifluoroethane (HFC-143), tetrafluoroethane (HFC-134), pentafluoroethane (HFC-125), pentafluoropropane (HFC-245), hexafluoropropane (HFC-236), heptafluoropropane (HFC-227ea), pentafluorobutane (HFC- 365), hexafluorobutane (HFC-356) and all isomers of all such HFC's. With respect to hydrocarbons, the present blowing agent compositions may include in certain preferred embodiments, for example, iso, normal and/or cyclopentane for thermoset foams and butane or isobutane for thermoplastic foams. Of course other materials, such as water, CO 2, CFCs (such as trichlorofluoromethane (CFC-11) and dichlorodifluoromethane (CFC-12)), hydrochlorocarbons (HCCs such as dichloroethylene (preferably trans-dichloroethylene), ethyl chloride and chloropropane), HCFCs, Cl-C5 alcohols (such as, for example, ethanol and/or propanol and/or butanol), Cl-C4 aldehydes, Cl-C4 ketones, Cl-C4 ethers (including ethers (such as dimethyl ether and diethyl ether), diethers (such as dimethoxy methane and diethoxy methane)), and methyl formate including combinations of any of these may be included, although such components are contemplated to be not preferred in many embodiments due to negative environmental impact. [00233] Any of the methods well known in the art, such as those described in “Polyurethanes Chemistry and Technology,” Volumes I and II, Saunders and Frish, 1962, John Wiley and Sons, New York, N.Y., which is incorporated herein by reference, may be used or adapted for use in accordance with the foam embodiments of the present disclosure. [00234] The relative amount of any of the above noted additional co-blowing agents, as well as any additional components which may be included in present compositions, can vary widely within the general broad scope of the present disclosure according to the particular application for the composition, and all such relative amounts are considered to be within the scope hereof. [00235] It will be appreciated by those skilled in the art, especially in view of the disclosure contained herein, that the order and manner in which the blowing agent of the present disclosure is formed and/or added to the foamable composition does not generally affect the operability of the present disclosure. For example, in the case of extrudable foams, it is possible that the various components of the blowing agent, and even the components of the present composition, be not mixed in advance of introduction to the extrusion equipment, or even that the components are not added to the same location in the extrusion equipment. Thus, in certain embodiments it may be desired to introduce one or more components of the blowing agent at first location in the extruder, which is upstream of the place of addition of one or more other components of the blowing agent, with the expectation that the components will come together in the extruder and/or operate more effectively in this manner. Nevertheless, in certain embodiments, two or more components of the blowing agent are combined in advance and introduced together into the foamable composition, either directly or as part of premix which is then further added to other parts of the foamable composition. XIV. Foamable Compositions [00236] One aspect of the present disclosure provides foamable compositions. As is known to those skilled in the art, foamable compositions generally include one or more components capable of forming foam. As used herein, the term “foam foaming agent” is used to refer to a component, or a combination of components, which are capable of forming a foam structure, preferably a generally cellular foam structure. [00237] In certain embodiments, the one or more components capable of forming foam comprise a thermosetting composition capable of forming foam and/or foamable compositions. Examples of thermosetting compositions include polyurethane and polyisocyanurate foam compositions, and also phenolic foam compositions. This reaction and foaming process may be enhanced through the use of various additives such as catalysts and surfactant materials that serve to control and adjust cell size and to stabilize the foam structure during formation. Furthermore, is contemplated that any one or more of the additional components described above with respect to the blowing agent compositions of the present disclosure could be incorporated into the foamable composition of the present disclosure. In such thermosetting foam embodiments, one or more of the present compositions are included as or part of a blowing agent in a foamable composition, or as a part of a two or more part foamable composition, which preferably includes one or more of the components capable of reacting and/or foaming under the proper conditions to form a foam or cellular structure. [00238] In certain other embodiments of the present disclosure, the one or more components capable of foaming comprise thermoplastic materials, particularly thermoplastic polymers and/or resins. Examples of thermoplastic foam components include polyolefins, such as for example monovinyl aromatic compounds of the formula Ar—CHCH2 wherein Ar is an aromatic hydrocarbon radical of the benzene series such as polystyrene (PS). Other examples of suitable polyolefin resins in accordance with the disclosure include the various ethylene resins including the ethylene homopolymers such as polyethylene and ethylene copolymers, polypropylene (PP) and polyethyleneterepthalate (PET). In certain embodiments, the thermoplastic foamable composition is an extrudable composition. [00239] It is contemplated that all presently known and available methods and systems for forming foam are readily adaptable for use in connection with the present disclosure. For example, the methods of the present disclosure generally require incorporating a blowing agent in accordance with the present disclosure into a foamable or foam forming composition and then foaming the composition, preferably by a step or series of steps which include causing volumetric expansion of the blowing agent in accordance with the present disclosure. In general, it is contemplated that the presently used systems and devices for incorporation of blowing agent and for foaming are readily adaptable for use in accordance with the present disclosure. In fact, it is believed that one advantage of the present disclosure is the provision of an improved blowing agent which is generally compatible with existing foaming methods and systems. [00240] Thus, it will be appreciated by those skilled in the art that the present disclosure comprises methods and systems for foaming all types of foams, including thermosetting foams, thermoplastic foams and formed-in-place foams. Thus, one aspect of the present disclosure is the use of the present blowing agents in connection conventional foaming equipment, such as polyurethane foaming equipment, at conventional processing conditions. The present methods therefore include masterbatch type operations, blending type operations, third stream blowing agent addition, and blowing agent addition at the foam head. [00241] The preferred method for these foams generally comprises introducing a blowing agent in accordance with the present disclosure into a thermoplastic material, preferably thermoplastic polymer such as polyolefin, and then subjecting the thermoplastic material to conditions effective to cause foaming. For example, the step of introducing the blowing agent into the thermoplastic material may comprise introducing the blowing agent into a screw extruder containing the thermoplastic, and the step of causing foaming may comprise lowering the pressure on the thermoplastic material and thereby causing expansion of the blowing agent and contributing to the foaming of the material. [00242] It will be appreciated by those skilled in the art, especially in view of the disclosure contained herein, that the order and manner in which the blowing agent of the present disclosure is formed and/or added to the foamable composition does not generally affect the operability of the present disclosure. For example, in the case of extrudable foams, it is possible that the various components of the blowing agent, and even the components of the foamable composition, be not be mixed in advance of introduction to the extrusion equipment, or even that the components are not added to the same location in the extrusion equipment. Moreover, the blowing agent can be introduced either directly or as part of a premix, which is then further added to other parts of the foamable composition. [00243] Thus, in certain embodiments it may be desired to introduce one or more components of the blowing agent at first location in the extruder, which is upstream of the place of addition of one or more other components of the blowing agent, with the expectation that the components will come together in the extruder and/or operate more effectively in this manner. Nevertheless, in certain embodiments, two or more components of the blowing agent are combined in advance and introduced together into the foamable composition, either directly or as part of premix which is then further added to other parts of the foamable composition. [00244] One embodiment of the present disclosure relates to methods of forming foams, and preferably polyurethane and polyisocyanurate foams. The methods generally comprise providing a blowing agent composition of the present disclosures, adding (directly or indirectly) the blowing agent composition to a foamable composition, and reacting the foamable composition under the conditions effective to form a foam or cellular structure, as is well known in the art. Any of the methods well known in the art, such as those described in “Polyurethanes Chemistry and Technology,” Volumes I and II, Saunders and Frisch, 1962, John Wiley and Sons, New York, N.Y., which is incorporated herein by reference, may be used or adapted for use in accordance with the foam embodiments of the present disclosure. In general, such preferred methods comprise preparing polyurethane or polyisocyanurate foams by combining an isocyanate, a polyol or mixture of polyols, a blowing agent or mixture of blowing agents comprising one or more of the present compositions, and other materials such as catalysts, surfactants, and optionally, flame retardants, colorants, or other additives. [00245] It is convenient in many applications to provide the components for polyurethane or polyisocyanurate foams in pre-blended formulations. Most typically, the foam formulation is pre-blended into two components. The isocyanate and optionally certain surfactants and blowing agents comprise the first component, commonly referred to as the “A” component. The polyol or polyol mixture, surfactant, catalysts, blowing agents, flame retardant, and other isocyanate reactive components comprise the second component, commonly referred to as the “B” component. Accordingly, polyurethane or polyisocyanurate foams are readily prepared by bringing together the A and B side components either by hand mix for small preparations and, preferably, machine mix techniques to form blocks, slabs, laminates, pour-in-place panels and other items, spray applied foams, froths, and the like. Optionally, other ingredients such as fire retardants, colorants, auxiliary blowing agents, and even other polyols can be added as one or more additional streams to the mix head or reaction site. Most preferably, however, they are all incorporated into one B-component as described above. [00246] The present methods and systems also include forming a one component foam, preferably polyurethane foam, containing a blowing agent formed of an azeotropic or azeotrope-like compositions in accordance with the present disclosure. In certain preferred embodiments, a portion of the blowing agent is contained in the foam forming agent, preferably by being dissolved in a foam forming agent which is liquid at the pressure within the container, a second portion of the blowing agent is present as a separate gas phase. In such systems, the contained/dissolved blowing agent performs, in large part, to cause the expansion of the foam, and the separate gas phase operates to impart propulsive force to the foam forming agent. Such one component systems are typically and preferably packaged in a container, such as an aerosol type can, and the blowing agent of the present disclosure thus preferably provides for expansion of the foam and/or the energy to transport the foam/foamable material from the package, and preferably both. In certain embodiments, such systems and methods comprise charging the package with a fully formulated system (preferably isocyanate/polyol system) and incorporating a gaseous blowing agent in accordance with the present disclosure into the package, preferably an aerosol type can. [00247] Any of the methods well known in the art, such as those described in “Polyurethanes Chemistry and Technology,” Volumes I and II, Saunders and Frisch, 1962, John Wiley and Sons, New York, N.Y., which is incorporated herein by reference, may be used or adapted for use in accordance with the foam forming embodiments of the present disclosure. [00248] It is contemplated also that in certain embodiments it may be desirable to utilize the present compositions when in the supercritical or near supercritical state as a blowing agent. [00249] The disclosure also relates to all foams, (including but not limited to closed cell foam, open cell foam, rigid foam, flexible foam, integral skin and the like) prepared from a polymer foam formulation containing a blowing agent comprising the compositions of the disclosure. Applicants have found that one advantage of the foams, and particularly thermoset foams such as polyurethane foams, in accordance with the present disclosure is the ability to achieve, preferably in connection with thermoset foam embodiments, exceptional thermal performance, such as can be measured by the K-factor or lambda, particularly and preferably under low temperature conditions. Although it is contemplated that the present foams, particularly thermoset foams of the present disclosure, may be used in a wide variety of applications, in certain preferred embodiments the present disclosure comprises appliance foams in accordance with the present disclosure, including refrigerator foams, freezer foams, refrigerator/freezer foams, panel foams, and other cold or cryogenic manufacturing applications. [00250] The foams in accordance with the present disclosure, in certain preferred embodiments, provide one or more exceptional features, characteristics and/or properties, including: thermal insulation efficiency (particularly for thermoset foams), dimensional stability, compressive strength, aging of thermal insulation properties, all in addition to the low ozone depletion potential and low global warming potential associated with many of the preferred blowing agents of the present disclosure. In certain highly preferred embodiments, the present disclosure provides thermoset foam, including such foam formed into foam articles, which exhibit improved thermal conductivity relative to foams made using the same blowing agent. [00251] In other preferred embodiments, the present foams exhibit improved mechanical properties relative to foams produced with blowing agents outside the scope of the present disclosure. For example, certain preferred embodiments of the present disclosure provide foams and foam articles having a compressive strength which is superior to, and preferably at least about 10 relative percent, and even more preferably at least about 15 relative percent greater than a foam produced under substantially identical conditions by utilizing a blowing agent consisting of cyclopentane. Furthermore, it is preferred in certain embodiments that the foams produced in accordance with the present disclosure have compressive strengths that are on a commercial basis comparable to the compressive strength produced by making a foam under substantially the same conditions except wherein the blowing agent consists of HFC-245fa. In certain preferred embodiments, the foams of the present disclosure exhibit a compressive strength of at least about 12.5% yield (in the parallel and perpendicular directions), and even more preferably at least about 13% yield in each of said directions. Example 11 [00252] Three appliance polyurethane foams are made, each one being formed using substantially the same materials, procedures and equipment, with the exception that different blowing agents are used. The polyol system in a commercially available, appliance- type formulation adapted for use with a liquid blowing agent of any of the azeotropic or azeotrope-like compositions disclosed herein. A foam machine is used to form the foam. The blowing agents are used in essentially equal molar concentrations. The azeotropic or azeotrope-like compositions disclosed herein may be used in combination with cyclopentane and HFC-245fa as co-blowing agents for a thermoset foam. After formation, each form is cut into samples suitable for measuring K-factors, which surprisingly are not affected deleteriously. Example 12 [00253] A further experiment was performed using the same formulation as in Example 18. The foam is prepared by handmix with each component used in essentially molar concentrations. A measurement of the K-factors demonstrated no deleterious effect as a result of the use of the azeotropic or azeotrope-like blowing agents. Example 13 [00254] This example illustrates the use of blowing agent in accordance with two preferred embodiments of the present disclosure, namely the use of the present azeotropic or azeotrope-like compositions and the production of polystyrene foam. A testing apparatus and protocol has been established as an aid to determining whether a specific blowing agent and polymer are capable of producing a foam and the quality of the foam. Ground polymer (Dow Polystyrene 685D) and blowing agent consisting essentially of the present azeotropic or azeotrope-like compositions are combined in a vessel. A sketch of the vessel is illustrated below. The vessel volume is 200 cubic centimeters and is made from two pipe flanges and a section of 2-inch diameter schedule 40 stainless steel pipe 4 inches long. The vessel is placed in an oven, with temperature set from about 190°F to about 285°F, preferably for polystyrene at 265°F and remains there until temperature equilibrium is reached.

[00255] The pressure in the vessel is then released, quickly producing a foamed polymer. The blowing agent plasticizes the polymer as it dissolves into it. The resulting density of the two foams thus produced using this method is suitable for polystyrene. Example 14 [00256] This example demonstrates the performance of the present azeotropic or azeotrope-like compositions as blowing agents for polystyrene foam formed in a twin screw type extruder. The apparatus employed in this example is a Leistritz twin screw extruder having the following characteristics: [00257] 30 mm co-rotating screws [00258] L:D Ratio = 40:1 [00259] The extruder is divided into 10 sections, each representing a L:D of 4:1. The polystyrene resin was introduced into the first section, the blowing agent was introduced into the sixth section, with the extrudate exiting the tenth section. The extruder operated primarily as a melt/mixing extruder. A subsequent cooling extruder is connected in tandem, for which the design characteristics were: [00260] Leistritz twin screw extruder [00261] 40 mm co-rotating screws [00262] L:D Ratio 40:1 [00263] Die: 5.0 mm circular [00264] Polystyrene resin, namely Nova Chemical –general extrusion grade polystyrene identified as Nova 1600, is feed to the extruder under the conditions indicated above. The resin has a recommended melt temperature of 375°F to 525°F. The pressure of the extruder at the die is about 1320 pounds per square inch (psi), and the temperature at the die is about 115°C. [00265] A blowing agent consisting essentially of the present azeotropic or azeotrope- like compositions is added to the extruder at the location indicated above, with about 0.5% by weight of talc included, on the basis of the weight of the total blowing agent, as a nucleating agent. Foam is produced using the blowing agent at concentrations of 10% by weight, 12% by weight, and 14% by weight, in accordance with the present disclosure. The foam, of approximately 30 millimeters in diameter, is visually of very good quality with good density, very fine cell size, with no visible or apparent blow holes or voids. Example 15 [00266] The procedure of Example 14 is repeated except that the foaming agent comprises about 50% by weight of any of the present azeotropic or azeotrope-like compositions and about 50% by weight HFC-245fa and nucleating agent in the concentration as indicated in Example 21. The resulting foams, of approximately 30 millimeters in diameter, are visually of very good quality, fine cell structure, with on visible or apparent voids. Example 16 [00267] The procedure of Example 14 is repeated except that the foaming agent comprises about 80% by weight of the present azeotropic or azeotrope-like compositions and about 20% by weight HFC-245fa and nucleating agent in the concentration as indicated in Example 21. The resulting foams, of approximately 30 millimeters in diameter, are visually of very good quality, fine cell structure, with on visible or apparent voids. Example 17 [00268] The procedure of Example 16 is repeated except that the nucleating agent is omitted. The resulting foams, of approximately 30 millimeters in diameter, are visually of very good quality, fine cell structure, with on visible or apparent voids. Example 18 [00269] This example illustrates the use of blowing agents in accordance with one of the preferred embodiments of the disclosure, namely the use of the present azeotropic or azeotrope-like compositions, and the production of polyol foams in accordance with the present disclosure. The components of a polyol form formulation are prepared in accordance with the following table: [00270] The foam is prepared by first mixing the ingredients thereof, but without the addition of a blowing agent. Two Fisher-Porter tubes are each filled with about 52.6 grams of the polyol mixture (without blowing agent) and sealed and placed in a refrigerator to cool and form a slight vacuum. Using gas burets, about 20 grams of any of the present azeotropic or azeotrope-like compositions is added to each tube, and the tubes are then placed in an ultrasound bath in warm water and allowed to sit for 30 minutes. The solution produced is hazy, and a vapor pressure measurement at room temperature indicates a vapor pressure of about 70 psig indicating that the blowing agent is not in solution. The tubes are then placed in a freezer at 27°F for 2 hours. The vapor pressure was again measured and found to be 14 psig. The isocyanate mixture, about 90 grams is placed into a metal container and placed in a refrigerator and allowed to cool to about 50°F. The polyol tubes were then opened and weighed into a metal mixing container (about 100 grams of polyol blend are used). The isocyanate from the cooled metal container is then immediately poured into the polyol and mixed with an air mixer with double propellers at 3000 RPM for 10 seconds. The blend immediately begins to froth with agitation and is then poured into an 8x8x4 inch box and allowed to foam. Because of the froth, a cream time cannot be measured. The foam has a 4 minute gel time and a 5 minute task free time. [00271] The foam is then allowed to cure for 2 days at room temperature. [00272] The foam is then cut into samples suitable for measuring physical properties and is found to have a density and K-factor suitable for polyol foam. XV. Solvents [00273] The present azeotropic or azeotrope-like compositions, having components in the relative weight ranges disclosed herein, may be used as solvent compositions. The solvent compositions may be in the form of a sprayable aerosol compositions and may be used for applications including degreasing or removal of coatings such as paints and adhesives. [00274] The solvent compositions may be an aerosol and/or a sprayable composition, and may have a Global Warming potential (GWP) of not greater than about 1000. [00275] The solvent compositions may be used in methods of removing a contaminant from an article comprising contacting the contaminated article with the solvent composition. The article may be selected from the group consisting of a metal, a glass, silica, and alumina. [00276] The solvent compositions may be used in methods of removing a coating from an article comprising contacting the contaminated article with the solvent composition. The coating may be selected from the group consisting of a paint and an adhesive. Example 19 [00277] Solvent compositions including the present azeotropic or azeotrope-like compositions are loaded into aerosol cans. An aerosol valve is crimped into place on each can and a propellant is added through the valves to achieve a pressure in the cans of about 20 PSIG. The compositions are then sprayed onto surfaces demonstrating that the compositions are useful as an aerosol. [00278] Additionally, the aerosol compositions are sprayed onto surfaces which include oil, grease, dirt, or solder flux, and are effective in solvating and removing such materials. Example 20 [00279] Solvent compositions including the present azeotropic or azeotrope-like compositions are loaded into aerosol cans. Aerosol valves are crimped into place and a propellant is added through the valves to achieve a pressure in the cans of about 20 PSIG. The compositions are then sprayed onto metal coupons soiled with solder flux. The flux is removed and the coupons are visually clean. Example 21 [00280] Example 20 above is repeated, except the coupons are soiled with mineral oils, silicon oils, cutting oils, or other lubricants. Optionally, the cleaning agents are applied neat. After spraying, the coupons are visually clean. Similar results are demonstrated in each case. Example 22 [00281] Mixtures are prepared containing the present azeotropic or azeotrope-like compositions. Several stainless-steel coupons are soiled with mineral oil. Then these coupons are immersed in the mixtures. The mixtures remove the oils in a short period of time. The coupons are observed visually and look clean. This demonstrates the ability to clean in a vapor degreaser or dip cleaning system. Example 23 [00282] Aerosol solvents are prepared containing the present azeotropic or azeotrope-like compositions. Kester 1544 Rosin Soldering Flux is placed on stainless-steel coupons and heated to approximately 300-400 °F, which simulates contact with a wave soldier normally used to solder electronic components in the manufacture of printed circuit boards. The coupons are then sprayed with the solvents and removed after 15 seconds without rinsing. Results show that the coupons appeared clean by visual inspection. Example 24 [00283] The present azeotropic or azeotrope-like compositions are used as solvating agents for removing paints, coatings and adhesives from surfaces. The solvating agents are effective for solvating the paints, coatings and adhesives and allowing the removal of same from the surfaces. Example 25 [00284] The present azeotropic or azeotrope-like compositions are used to first solvate a paint, silicone, oil, adhesive, or other material to be coated on a substrate. A substrate that is to be coated is then dipped, sprayed, or otherwise allowed to come in contact with the solvent/coating mixture. The solvent is then allowed to volatize from the surface leaving behind the desired material on the surface. [00285] As used herein, the phrase “within any range defined between any two of the foregoing values” literally means that any range may be selected from any two of the values listed prior to such phrase regardless of whether the values are in the lower part of the listing or in the higher part of the listing. For example, a pair of values may be selected from two lower values, two higher values, or a lower value and a higher value. [00286] It should be understood that the foregoing description is only illustrative of the present disclosure. Various alternatives and modifications can be devised by those skilled in the art without departing from the disclosure. Accordingly, the present disclosure is intended to embrace all such alternatives, modifications and variances that fall within the scope of the appended claims.

ASPECTS [00287] Aspect 1 is a composition consisting essentially of from about 20 wt.% to about 55 wt.% 1,1,1,3,3,3-hexafluoro-2(2,2,2-trifluoroethoxy)propane and from about 45 wt.% to about 80 wt.% trans-1,2-dichloroethylene. [00288] Aspect 2 is the composition as claimed in Aspect 1, wherein said composition consists essentially of from about 29 wt.% to about 45 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and from about 55 wt.% to about 71 wt.% trans-1,2-dichloroethylene. [00289] Aspect 3 is the composition as claimed in Aspect 1 or Aspect 2, wherein said composition consists essentially of about 34 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 66 wt.% trans-1,2-dichloroethylene. [00290] Aspect 4 is the composition of any one of Aspects 1 to 3, wherein the composition has a boiling point of about 44.20°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00291] Aspect 5 is a composition comprising a composition consisting essentially of from about 20 wt.% to about 55 wt.% 1,1,1,3,3,3-hexafluoro-2(2,2,2-trifluoroethoxy)propane and from about 45 wt.% to about 80 wt.% trans-1,2-dichloroethylene. [00292] Aspect 6 is a composition consisting essentially of from about 75 wt.% to about 97 wt.% 1,1,1,3,3,3-hexafluoro-2(2,2,2-trifluoroethoxy)propane and from about 3 wt.% to about 25 wt.% ethanol. [00293] Aspect 7 is the composition as claimed in Aspect 6, wherein said composition consists essentially of from about 79 wt.% to about 95 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and from about 5 wt.% to about 21 wt.% ethanol. [00294] Aspect 8 is the composition as claimed in Aspect 6 or 7, wherein said composition consists essentially of about 91 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 9 wt.% ethanol. [00295] Aspect 9 is the composition in any one of Aspects 6 to 8, wherein the composition has a boiling point of about 66.77°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00296] Aspect 10 is a composition comprising a composition consisting essentially of from about 75 wt.% to about 97 wt.% 1,1,1,3,3,3-hexafluoro-2(2,2,2-trifluoroethoxy)propane and from about 3 wt.% to about 25 wt.% ethanol. [00297] Aspect 11 is a composition consisting essentially of from about 80 wt.% to about 99 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 1 wt.% to about 20 wt.% isopropanol [00298] Aspect 12 is the composition as claimed in Aspect 11, wherein said composition consists essentially of from about 85 wt.% to about 95 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 5 wt.% to about 15 wt.% isopropanol. [00299] Aspect 13 is the composition as claimed in Aspect 11 or 12, wherein said composition consists essentially of about 92 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 8 wt.% isopropanol. [00300] Aspect 14 is the composition as claimed in any one of Aspects 11 to 13, wherein the composition has a boiling point of about 69.60°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00301] Aspect 15 is a composition comprising a composition consisting essentially of from about 80 wt.% to about 99 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 1 wt.% to about 20 wt.% isopropanol. [00302] Aspect 16 is a composition consisting essentially of from about 30 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 35 wt.% to about 70 wt.% cis-1,2-dichloroethylene. [00303] Aspect 17 is the composition as claimed in Aspect 16, wherein said composition consists essentially of about 44 wt.% to about 62 wt.% 1,1,1,3,3,3-hexafluoro-2- (2,2,2-trifluoroethoxy)propane and from about 38 wt.% to about 56 wt.% cis-1,2- dichloroethylene. [00304] Aspect 18 is the composition as claimed in Aspect 16 or Aspect 17, wherein said composition consists essentially of about 58 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 42 wt.% cis-1,2-dichloroethylene. [00305] Aspect 19 is the composition of any one of Aspects 16 to 18, wherein the composition has a boiling point of about 56.7°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00306] Aspect 20 is a composition comprising a composition consisting essentially of from about 30 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 35 wt.% to about 70 wt.% cis-1,2-dichloroethylene. [00307] Aspect 21 is a composition consisting essentially of from about 75 wt.% to about 93 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 7 wt.% to about 25 wt.% methanol. [00308] Aspect 22 is the composition as claimed in Aspect 21, wherein said composition consists essentially of from about 80 wt.% to about 89 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 11wt.% to about 20 wt.% methanol. [00309] Aspect 23 is the composition as claimed in Aspect 21 or Aspect 22, wherein said composition consists essentially of about 86 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 14 wt.% methanol. [00310] Aspect 24 is the composition of any one of Aspects 21 to 23, wherein the composition has a boiling point of about 53.4°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00311] Aspect 25 is a composition comprising a composition consisting essentially of from about 75 wt.% to about 93 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 7 wt.% to about 25 wt.% methanol. [00312] Aspect 26 is a composition consisting essentially of from about 35 wt.% to about 66 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 34 wt.% to about 65 wt.% diisopropyl ether. [00313] Aspect 27 is the composition as claimed in Aspect 26, wherein said composition consists essentially of from about 42 wt.% to about 57 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 43 wt.% to about 58 wt.% diisopropyl ether. [00314] Aspect 28 is the composition as claimed in Aspect 26 or Aspect 27, wherein said composition consists essentially of about 49 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 51 wt.% diisopropyl ether. [00315] Aspect 29 is the composition of any one of Aspects 26 to 28, wherein the composition has a boiling point of about 64.2°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00316] Aspect 30 is a composition comprising a composition consisting essentially of from about 35 wt.% to about 66 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 34 wt.% to about 65 wt.% diisopropyl ether. [00317] Aspect 31 is a composition consisting essentially of from about 33 wt.% to about 64 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 36 wt.% to about 67 wt.% acetone. [00318] Aspect 32 is the composition as claimed in Aspect 31, wherein said composition consists essentially of from about 34 wt.% to about 49 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 51 wt.% to about 66 wt.% acetone. [00319] Aspect 33 is the composition as claimed in Aspect 31 or 32, wherein said composition consists essentially of about 35 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 65 wt.% acetone. [00320] Aspect 34 is the composition in any one of Aspects 31-33, wherein the composition has a boiling point of about 64.2°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00321] Aspect 35 is a composition comprising a composition consisting essentially of from about 33 wt.% to about 64 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 36 wt.% to about 67 wt.% acetone. [00322] Aspect 36 is a composition consisting essentially of from about 22 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 35 wt.% to about 78 wt.% pentane. [00323] Aspect 37 is the composition as claimed in Aspect 36, wherein said composition consists essentially of from about 28 wt.% to about 50 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 50 wt.% to about 72 wt.% pentane. [00324] Aspect 38 is the composition as claimed in Aspect 36 or 37, wherein said composition consists essentially of about 34 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 66 wt.% pentane. [00325] Aspect 39 is the composition in any one of Aspects 36 to 38, wherein the composition has a boiling point of about 34.9°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00326] Aspect 40 is a composition comprising a composition consisting essentially of from about 22 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 35 wt.% to about 78 wt.% pentane. [00327] Aspect 41 is a composition consisting essentially of from about 27 wt.% to about 70 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 30 wt.% to about 73 wt.% cyclopentane. [00328] Aspect 42 is the composition as claimed in Aspect 41, wherein said composition consists essentially of from about 38 wt.% to about 59 wt.% 1,1,1,3,3,3- hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 41 wt.% to about 62 wt.% cyclopentane. [00329] Aspect 43 is the composition as claimed in Aspect 41 or 42, wherein said composition consists essentially of about 49 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2- trifluoroethoxy)propane and about 51 wt.% cyclopentane. [00330] Aspect 44 is the composition in any one of Aspects 41 to 43, wherein the composition has a boiling point of about 45.8°C ± 0.01°C at a pressure of about 14.7 psia ± 0.2 psia. [00331] Aspect 45 is a composition comprising a composition consisting essentially of from about 22 wt.% to about 65 wt.% 1,1,1,3,3,3-hexafluoro-2-(2,2,2-trifluoroethoxy)propane and from about 35 wt.% to about 78 wt.% cyclopentane. [00332] Aspect 46 is a method for cooling a heat generating component in an electronic device, the electronic device comprising a thermal management fluid comprising any of the compositions in Aspects 1-45, the method comprising transferring heat from the heat-generating component to the thermal management fluid and circulating said thermal management fluid in said system. [00333] Aspect 47 is the method of Aspect 46, wherein the thermal management fluid is in direct contact with the heat generating component. [00334] Aspect 48 is the method of any of Aspects 46-47 wherein the heat generating component is selected from semiconductor integrated circuits (ICs), electrochemical cells, power transistors, resistors, and electroluminescent elements, such as microprocessors, wafers used to manufacture semiconductor devices, power control semiconductors, electrical distribution switch gear, power transformers, circuit boards, multi-chip modules, packaged or unpackaged semiconductor devices, semiconductor integrated circuits, fuel cells, lasers (conventional or laser diodes), light emitting diodes (LEDs), and electrochemical cells, e.g. used for high power applications such as, for example, hybrid or electric vehicles. [00335] Aspect 49 is the method of any of Aspects 46-48, wherein said electronic device is selected from personal computers, microprocessors, servers, cell phones, tablets, digital home appliances (e.g., televisions, media players, games consoles etc.), personal digital assistants, datacenters, hybrid or electric vehicles, wind turbine, train engine, or generator. [00336] Aspect 50 is the method of Aspect 49, wherein the electronic device is a hybrid or electric vehicle. [00337] Aspect 51 is a process for converting thermal energy to mechanical energy in a Rankine cycle, the method comprising the steps of i) vaporizing a working fluid with a heat source and expanding the resulting vapor, then ii) cooling the working fluid with a heat sink to condense the vapor, wherein the working fluid comprises at least about 50% by weight of any of the compositions of Aspects 1-45. [00338] Aspect 52 is a high temperature heat pump comprising a heat transfer fluid, wherein the heat transfer fluid comprises any of the compositions of Aspects 1-45. [00339] Aspect 53 is a secondary loop system comprising a refrigerant comprising any of the compositions of Aspects 1-45. [00340] Aspect 54 is a heat transfer composition comprising a heat transfer fluid and a lubricant, wherein the heat transfer fluid comprises any of the compositions of Aspects 1- 45. [00341] Aspect 55 is the heat transfer fluid of Aspect 54, wherein the lubricant comprises at least one polyol ester (POE). [00342] Aspect 56 is a method of replacing an existing refrigerant in a heat transfer system, the method comprising the steps of (a) removing at least a portion of said existing refrigerant from said system and subsequently (b) introducing into said system a refrigerant comprising an azeotrope or azeotrope-like composition comprising any of the compositions of Aspects 1-45. [00343] Aspect 57 is a solvent composition comprising an azeotrope or azeotrope-like composition of any of Aspects 1-45. [00344] Aspect 58 is an aerosol and/or a sprayable composition comprising the solvent composition of Aspect 57. [00345] Aspect 59 is a method of removing a contaminant from an article comprising contacting the contaminated article with the solvent composition of Aspect 57 or Aspect 58. [00346] Aspect 60 is the method of Aspect 59, wherein the article is selected from the group consisting of a metal, a glass, silica, and alumina. [00347] Aspect 61 is a method of removing a coating from an article comprising contacting the contaminated article with the solvent composition of Aspect 57 or Aspect 58. [00348] Aspect 62 is the method of Aspect 61, wherein the coating is selected from the group consisting of a paint and an adhesive. [00349] Aspect 63 is the solvent composition of Aspect 57, wherein the solvent composition has a Global Warming potential (GWP) of not greater than about 1000. [00350] As used herein, the phrase “within any range defined between any two of the foregoing values” literally means that any range may be selected from any two of the values listed prior to such phrase regardless of whether the values are in the lower part of the listing or in the higher part of the listing. For example, a pair of values may be selected from two lower values, two higher values, or a lower value and a higher value. [00351] It should be understood that the foregoing description is only illustrative of the present disclosure. Various alternatives and modifications can be devised by those skilled in the art without departing from the disclosure. Accordingly, the present disclosure is intended to embrace all such alternatives, modifications and variances that fall within the scope of the appended claims.