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Title:
BIO-BASED POLYURETHANE COATED SLOW CONTROLLED RELEASE FERTILIZER FOR STEAM EXPLOSION PRETREATMENT OF CROP STRAWS, AND PREPARATION METHOD THEREFOR
Document Type and Number:
WIPO Patent Application WO/2022/227830
Kind Code:
A1
Abstract:
A bio-based polyurethane coated controlled release fertilizer, and a preparation method therefor. The method comprises the following steps: introducing saturated water vapor into a closed device, so as to crack crop straw at a high temperature and a high pressure, instantaneously reducing the pressure and crushing the straw to perform an explosion; cleaning materials after the explosion, and removing water-soluble ions and small-molecule organic matters which do not participate in film formation; pre-liquefying the pretreated materials using an acid catalyst, then upgrading using a hydrogenation catalyst, so as to convert a carbonyl compound in a bio-oil into an alcohol substance; and reacting and spraying the extracted bio-oil and isocyanate on the surface of a fertilizer, so as to prepare a bio-based polyurethane coated controlled release fertilizer. The present method solves the problem of crop straw having a complex structure and composition, the liquefied product having high impurity content and poor crosslinking degree with isocyanate, and the formed polyurethane having strong hydrophilicity, etc., and the prepared controlled-release fertilizer has good controlled release performance.

Inventors:
LIU ZHIGUANG (CN)
YU XIAOJING (CN)
ZHANG MIN (CN)
SUN XIAO (CN)
WU LIANG (CN)
FANG FULI (CN)
TIAN HONGYU (CN)
CHEN SIYU (CN)
Application Number:
PCT/CN2022/077858
Publication Date:
November 03, 2022
Filing Date:
February 25, 2022
Export Citation:
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Assignee:
UNIV SHANDONG AGRICULTURAL (CN)
XINYANGFENG AGRICULTURAL TECH CO LTD (CN)
International Classes:
D21B1/36; C05G3/40
Domestic Patent References:
WO2018018024A12018-01-25
Foreign References:
CN101736646A2010-06-16
CN106906265A2017-06-30
CN102268833A2011-12-07
CN101173302A2008-05-07
CN113042096A2021-06-29
CN102286548A2011-12-21
CN102795924A2012-11-28
CN105646090A2016-06-08
Attorney, Agent or Firm:
SHANDONG QIZHI INTELLECTUAL PROPERTY AGENCY LTD. (CN)
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