Title:
BIO-BASED POLYURETHANE COATED SLOW CONTROLLED RELEASE FERTILIZER FOR STEAM EXPLOSION PRETREATMENT OF CROP STRAWS, AND PREPARATION METHOD THEREFOR
Document Type and Number:
WIPO Patent Application WO/2022/227830
Kind Code:
A1
Abstract:
A bio-based polyurethane coated controlled release fertilizer, and a preparation method therefor. The method comprises the following steps: introducing saturated water vapor into a closed device, so as to crack crop straw at a high temperature and a high pressure, instantaneously reducing the pressure and crushing the straw to perform an explosion; cleaning materials after the explosion, and removing water-soluble ions and small-molecule organic matters which do not participate in film formation; pre-liquefying the pretreated materials using an acid catalyst, then upgrading using a hydrogenation catalyst, so as to convert a carbonyl compound in a bio-oil into an alcohol substance; and reacting and spraying the extracted bio-oil and isocyanate on the surface of a fertilizer, so as to prepare a bio-based polyurethane coated controlled release fertilizer. The present method solves the problem of crop straw having a complex structure and composition, the liquefied product having high impurity content and poor crosslinking degree with isocyanate, and the formed polyurethane having strong hydrophilicity, etc., and the prepared controlled-release fertilizer has good controlled release performance.
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Inventors:
LIU ZHIGUANG (CN)
YU XIAOJING (CN)
ZHANG MIN (CN)
SUN XIAO (CN)
WU LIANG (CN)
FANG FULI (CN)
TIAN HONGYU (CN)
CHEN SIYU (CN)
YU XIAOJING (CN)
ZHANG MIN (CN)
SUN XIAO (CN)
WU LIANG (CN)
FANG FULI (CN)
TIAN HONGYU (CN)
CHEN SIYU (CN)
Application Number:
PCT/CN2022/077858
Publication Date:
November 03, 2022
Filing Date:
February 25, 2022
Export Citation:
Assignee:
UNIV SHANDONG AGRICULTURAL (CN)
XINYANGFENG AGRICULTURAL TECH CO LTD (CN)
XINYANGFENG AGRICULTURAL TECH CO LTD (CN)
International Classes:
D21B1/36; C05G3/40
Domestic Patent References:
WO2018018024A1 | 2018-01-25 |
Foreign References:
CN101736646A | 2010-06-16 | |||
CN106906265A | 2017-06-30 | |||
CN102268833A | 2011-12-07 | |||
CN101173302A | 2008-05-07 | |||
CN113042096A | 2021-06-29 | |||
CN102286548A | 2011-12-21 | |||
CN102795924A | 2012-11-28 | |||
CN105646090A | 2016-06-08 |
Attorney, Agent or Firm:
SHANDONG QIZHI INTELLECTUAL PROPERTY AGENCY LTD. (CN)
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