Title:
BORATE-BASED BASE GENERATOR, AND BASE-REACTIVE COMPOSITION COMPRISING SUCH BASE GENERATOR
Document Type and Number:
WIPO Patent Application WO/2015/111640
Kind Code:
A1
Abstract:
The present invention addresses the problem of providing: a compound that is capable of forming a composition having good shelf life such that even if the compound is stored long term in a state of being mixed with a base-reactive compound such as an epoxy compound, reaction with the base-reactive compound does not occur, and that is capable of generating a strong base (a guanidine, biguanide, phosphazene, or phosphonium) when irradiated with light (active energy rays) or heated; a base generator comprising the compound; and a base-reactive composition comprising the base generator and the base-reactive compound. The present invention relates to a compound represented by general formula (A), a base generator comprising the compound, a base-reactive composition characterized in comprising the base generator and a base-reactive compound, and the like. (In the formula, R1 is an alkyl group; an arylalkynyl group optionally substituted by a halogen atom, alkyl group, alkoxy group, or alkylthio group; an alkenyl group; a 2-furylethynyl group; a 2-thiophenylethynyl group; or a 2,6-dithianyl group. R2 through R4 are each independently an alkyl group; an arylalkynyl group optionally substituted by a halogen atom, alkyl group, alkoxy group, or alkylthio group; an aryl group optionally substituted by a halogen atom, alkyl group, alkoxy group, or alkylthio group; a furanyl group; a thienyl group; or an N-alkyl-substituted pyrrolyl group. Z+ is an ammonium cation comprising a guanidinium group, biguanidium group, or phosphazenium group, or a phosphonium cation.)
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Inventors:
SAKAI NOBUHIKO (JP)
YANABA KOSUKE (JP)
YANABA KOSUKE (JP)
Application Number:
PCT/JP2015/051593
Publication Date:
July 30, 2015
Filing Date:
January 22, 2015
Export Citation:
Assignee:
WAKO PURE CHEM IND LTD (JP)
International Classes:
C07F5/02; C07C279/26; C07D233/48; C07D487/04; C07F9/22; C07F9/24; C09K3/00
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Other References:
SCHWESINGER, REINHARD ET AL.: "Extremely base- resistant organic phosphazenium cations", CHEMISTRY - A EUROPEAN JOURNAL, vol. 12, no. 2, 2005, pages 429 - 437, XP055214822
SCHMIDPETER, ALFRED ET AL.: "Phosphazenes. XXX. Ammonolysis of chlorophosphoranes, Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie", ORGANISCHE CHEMIE, BIOCHEMIE, BIOPHYSIK, BIOLOGIE, vol. 24, no. 7, 1969, pages 799 - 810, XP055214827
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See also references of EP 3098226A4
SCHMIDPETER, ALFRED ET AL.: "Phosphazenes. XXX. Ammonolysis of chlorophosphoranes, Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie", ORGANISCHE CHEMIE, BIOCHEMIE, BIOPHYSIK, BIOLOGIE, vol. 24, no. 7, 1969, pages 799 - 810, XP055214827
J. POLYM. SCI., PART A: POLYM. CHEM., vol. 32, 1994, pages 1793
J. AM. CHEM. SOC., vol. 117, 1995, pages 11369 - 11370
MACROMOLECULES, vol. 31, 1998, pages 951 - 954
MACROMOLECULES, vol. 31, 1998, pages 6476 - 6480
MACROMOLECULES, vol. 32, 1999, pages 328 - 330
J. AM. CHEM. SOC., vol. 130, 2008, pages 8130
J. PHOTOPOLYM. SCI. TECH., vol. 25, 2012, pages 497 - 499
TETRAHEDRON LETT., vol. 39, 1998, pages 2743
CHEM. BER., vol. 117, 1984, pages 1900 - 1912
See also references of EP 3098226A4
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