Title:
CATALYST COMPOSITION FOR HYDROGENATION AND HYDROGENATION METHOD USING CATALYST COMPOSITION FOR HYDROGENATION
Document Type and Number:
WIPO Patent Application WO/2014/046017
Kind Code:
A1
Abstract:
A catalyst composition for hydrogenation, which contains components (A)-(D), with the mass ratio ((C)/(A)) being 0.1-4.0 and the mass ratio ((D)/(A)) being 0.01-1.00.
(A) a titanocene compound represented by formula (1)
(In formula (1), each of R5 and R6 represents one group selected from among a hydrogen atom, a C1-C12 hydrocarbon group, an aryloxy group, an alkoxy group, a halogen group and a carbonyl group; and each of R1 and R2 represents one group selected from among a hydrogen atom and a C1-C12 hydrocarbon group, excluding the cases where both R1 and R2 are hydrogen atoms or C1-C12 hydrocarbon groups.)
(B) a reducing agent which is composed of a compound containing an element that is selected from among Li, Na, K, Mg, Zn, Al and Ca
(C) an unsaturated compound having a molecular weight of 400 or less
(D) a polar compound
Inventors:
ARAKI YOSHIFUMI (JP)
SASAYA EIJI (JP)
NITTA KATSUNORI (JP)
SASAYA EIJI (JP)
NITTA KATSUNORI (JP)
Application Number:
PCT/JP2013/074749
Publication Date:
March 27, 2014
Filing Date:
September 12, 2013
Export Citation:
Assignee:
ASAHI KASEI CHEMICALS CORP (JP)
International Classes:
B01J31/22; C08F8/04; C07F7/28
Domestic Patent References:
WO2002002650A1 | 2002-01-10 |
Foreign References:
JPH0841081A | 1996-02-13 | |||
JPH0833846A | 1996-02-06 | |||
JPH02172537A | 1990-07-04 | |||
JP2010059415A | 2010-03-18 | |||
JPH0827216A | 1996-01-30 | |||
JP2003524515A | 2003-08-19 | |||
US20080146733A1 | 2008-06-19 | |||
JPS6133132A | 1986-02-17 | |||
JPS6453851A | 1989-03-01 | |||
JPS6128507A | 1986-02-08 | |||
JPS62209103A | 1987-09-14 | |||
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JPH01275605A | 1989-11-06 | |||
JPH02172537A | 1990-07-04 | |||
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JPH0833846A | 1996-02-06 | |||
JPH0841081A | 1996-02-13 | |||
JP2004269665A | 2004-09-30 |
Other References:
YIN-HENG FAN ET AL.: "Extremely active catalysts for the hydrogenation of terminal alkenes", JOURNAL OF CATALYSIS, vol. 205, pages 294 - 298, XP027233419
Attorney, Agent or Firm:
INABA, Yoshiyuki et al. (JP)
Yoshiyuki Inaba (JP)
Yoshiyuki Inaba (JP)
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