Title:
CATALYST FOR HYDROFORMYLATION REACTION WITH HIGH ACTIVITY AND REUSABILITY, MANUFACTURING METHOD THEREFOR, AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2024/096367
Kind Code:
A1
Abstract:
The present invention relates to a catalyst for hydroformylation reactions with high activity and reusability, a manufacturing method therefor, and a use thereof. With the defects caused by the cerium oxide nanostructure thereof, the catalyst for hydroformylation reactions prevents the aggregation and structural deformation of rhodium single-atom catalysts even under high-temperature reduction conditions, thus exhibiting an excellent thermal stability effect. The catalyst possesses a higher content of Ce3+ than conventional cerium, which leads to adjusting the electron density of rhodium, thus achieving a turn over frequency (TOF) value of 15,000 or more for propylene used as a reactant, indicating a superior effect compared to traditional heterogeneous hydroformylation catalysts. Moreover, the catalyst for hydroformylation reactions can be advantageously reused as a heterogeneous catalyst.
Inventors:
AN KWANGJIN (KR)
LEE HO JEONG (KR)
OH DAEWON (KR)
LEE HO JEONG (KR)
OH DAEWON (KR)
Application Number:
PCT/KR2023/015838
Publication Date:
May 10, 2024
Filing Date:
October 13, 2023
Export Citation:
Assignee:
ULSAN NAT INST SCIENCE & TECH UNIST (KR)
International Classes:
B01J23/63; B01J21/04; B01J23/46; B01J37/00; B01J37/02; B01J37/04; B01J37/08; C07C45/50; C07C45/77
Foreign References:
| US4213921A | 1980-07-22 | |||
| KR20210048748A | 2021-05-04 |
Other References:
UOZUMI, Y. ET AL.: "Hydroformylation of Styrene Derivatives Catalyzed by Rhodium Single-Atoms Supported on CeO2", SYNFACTS, vol. 16, no. 7, 17 June 2020 (2020-06-17), pages 1
IGNACIO CUAUHTÉMOCA, GLORIA DEL ANGELA, GILBERTO TORRESB, JUAN NAVARRETEC, CARLOS ANGELES-CHAVEZC, JUAN MANUEL PADILLAA: "Synthesis and characterization of Rh/Al2O3-CeO2 catalysts: effect of the Ce4+/Ce3+ ratio on the MTBE removal", JOURNAL OF CERAMIC PROCESSING RESEARCH, INTERNATIONAL ORGANIZATION FOR CERAMIC PROCESSING, SEOUL, KR, vol. 10, no. 4, 31 August 2009 (2009-08-31), KR , pages 512 - 520, XP009554488, ISSN: 1229-9162
ALINI, S. BOTTINO, A. CAPANNELLI, G. COMITE, A. PAGANELLI, S.: "Preparation and characterisation of Rh/Al"2O"3 catalysts and their application in the adiponitrile partial hydrogenation and styrene hydroformylation", APPLIED CATALYSIS A: GENERAL, ELSEVIER, AMSTERDAM, NL, vol. 292, 18 September 2005 (2005-09-18), AMSTERDAM, NL , pages 105 - 112, XP005045148, ISSN: 0926-860X
ANONYMOUS: "Development of Rh/CeO2-Al2O3 Monoatomic Catalyst for Hydroformylation Catalysis", 2022 SPRING GENERAL ASSEMBLY & CONFERENCE ABSTRACTS, 20 April 2022 (2022-04-20), pages 1 - 5
IGNACIO CUAUHTÉMOCA, GLORIA DEL ANGELA, GILBERTO TORRESB, JUAN NAVARRETEC, CARLOS ANGELES-CHAVEZC, JUAN MANUEL PADILLAA: "Synthesis and characterization of Rh/Al2O3-CeO2 catalysts: effect of the Ce4+/Ce3+ ratio on the MTBE removal", JOURNAL OF CERAMIC PROCESSING RESEARCH, INTERNATIONAL ORGANIZATION FOR CERAMIC PROCESSING, SEOUL, KR, vol. 10, no. 4, 31 August 2009 (2009-08-31), KR , pages 512 - 520, XP009554488, ISSN: 1229-9162
ALINI, S. BOTTINO, A. CAPANNELLI, G. COMITE, A. PAGANELLI, S.: "Preparation and characterisation of Rh/Al"2O"3 catalysts and their application in the adiponitrile partial hydrogenation and styrene hydroformylation", APPLIED CATALYSIS A: GENERAL, ELSEVIER, AMSTERDAM, NL, vol. 292, 18 September 2005 (2005-09-18), AMSTERDAM, NL , pages 105 - 112, XP005045148, ISSN: 0926-860X
ANONYMOUS: "Development of Rh/CeO2-Al2O3 Monoatomic Catalyst for Hydroformylation Catalysis", 2022 SPRING GENERAL ASSEMBLY & CONFERENCE ABSTRACTS, 20 April 2022 (2022-04-20), pages 1 - 5
Attorney, Agent or Firm:
TAEBAEK INTELLECTUAL PROPERTY LAW FIRM (KR)
Download PDF: