Title:
CATALYST LOADED BODY, CATALYST FOR VAPOR-PHASE OXIDATION OF ORGANIC COMPOUND USING SAME, AND VAPOR-PHASE OXIDATION METHOD
Document Type and Number:
WIPO Patent Application WO/2024/048582
Kind Code:
A1
Abstract:
[Problem] The present invention provides a means which is capable of oxidizing an organic compound in a vapor phase using a nitroxyl radical as a catalyst. [Solution] A catalyst loaded body is obtained by loading a carrier with a compound that has an oxidation-reduction mechanism described below together with a promoter that contains a transition metal. In the formula, X- represents a counter anion; and the broken line represents a bonding position with another atom.
Inventors:
ITO MASASHI (JP)
OUME AMI (JP)
UCHIMURA MASANOBU (JP)
NISHIHARA HIROTOMO (JP)
YOSHII TAKEHARU (JP)
WAKABAYASHI KEIGO (JP)
IWABUCHI YOSHIHARU (JP)
SASANO YUSUKE (JP)
HIRASAWA NORIYASU (JP)
SEGAWA RYOSUKE (JP)
KONNO TOMOHIRO (JP)
OUME AMI (JP)
UCHIMURA MASANOBU (JP)
NISHIHARA HIROTOMO (JP)
YOSHII TAKEHARU (JP)
WAKABAYASHI KEIGO (JP)
IWABUCHI YOSHIHARU (JP)
SASANO YUSUKE (JP)
HIRASAWA NORIYASU (JP)
SEGAWA RYOSUKE (JP)
KONNO TOMOHIRO (JP)
Application Number:
PCT/JP2023/031215
Publication Date:
March 07, 2024
Filing Date:
August 29, 2023
Export Citation:
Assignee:
NISSAN MOTOR (JP)
UNIV TOHOKU (JP)
UNIV TOHOKU (JP)
International Classes:
B01J31/28; C07B61/00; C07C45/39; C07C49/08; C07D207/46; C07D211/94; C07D451/00; C07D451/14
Foreign References:
| CN113083361A | 2021-07-09 | |||
| CN111085267A | 2020-05-01 | |||
| CN111233817A | 2020-06-05 | |||
| US20200283918A1 | 2020-09-10 | |||
| CN109499609A | 2019-03-22 | |||
| JP2012250160A | 2012-12-20 |
Other References:
CHANDRA PRAKASH, JONAS ALAIN M., FERNANDES ANTONY E.: "Spatial Coordination of Cooperativity in Silica-Supported Cu/TEMPO/Imidazole Catalytic Triad", ACS CATALYSIS, AMERICAN CHEMICAL SOCIETY, US, vol. 8, no. 7, 6 July 2018 (2018-07-06), US , pages 6006 - 6011, XP093145091, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b01399
TIAN YANGWU, GUO XIAQUN, LI MEICHAO, LI CHUNMEI, HU XINQUAN, JIN LIQUN, SUN NAN, HU BAOXIANG, SHEN ZHENLU: "SBA-15 Supported 1-Methyl-2-azaadamanane N -Oxyl (1-Me-AZADO) as Recyclable Catalyst for Oxidation of Alcohol", ORGANIC LETTERS, AMERICAN CHEMICAL SOCIETY, US, vol. 23, no. 10, 21 May 2021 (2021-05-21), US , pages 3928 - 3932, XP093145092, ISSN: 1523-7060, DOI: 10.1021/acs.orglett.1c01058
SASANO YUSUKE, KOGURE NAOKI, NAGASAWA SHOTA, KASABATA KOKI, IWABUCHI YOSHIHARU: "2-Azaadamantane N -oxyl (AZADO)/Cu Catalysis Enables Chemoselective Aerobic Oxidation of Alcohols Containing Electron-Rich Divalent Sulfur Functionalities", ORGANIC LETTERS, AMERICAN CHEMICAL SOCIETY, US, vol. 20, no. 19, 5 October 2018 (2018-10-05), US , pages 6104 - 6107, XP093145094, ISSN: 1523-7060, DOI: 10.1021/acs.orglett.8b02528
TIAN YANGWU, GUO XIAQUN, LI MEICHAO, LI CHUNMEI, HU XINQUAN, JIN LIQUN, SUN NAN, HU BAOXIANG, SHEN ZHENLU: "SBA-15 Supported 1-Methyl-2-azaadamanane N -Oxyl (1-Me-AZADO) as Recyclable Catalyst for Oxidation of Alcohol", ORGANIC LETTERS, AMERICAN CHEMICAL SOCIETY, US, vol. 23, no. 10, 21 May 2021 (2021-05-21), US , pages 3928 - 3932, XP093145092, ISSN: 1523-7060, DOI: 10.1021/acs.orglett.1c01058
SASANO YUSUKE, KOGURE NAOKI, NAGASAWA SHOTA, KASABATA KOKI, IWABUCHI YOSHIHARU: "2-Azaadamantane N -oxyl (AZADO)/Cu Catalysis Enables Chemoselective Aerobic Oxidation of Alcohols Containing Electron-Rich Divalent Sulfur Functionalities", ORGANIC LETTERS, AMERICAN CHEMICAL SOCIETY, US, vol. 20, no. 19, 5 October 2018 (2018-10-05), US , pages 6104 - 6107, XP093145094, ISSN: 1523-7060, DOI: 10.1021/acs.orglett.8b02528
Attorney, Agent or Firm:
IBC (JP)
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