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Title:
CATALYST FOR METHANATION REACTION, METHOD FOR PRODUCING CATALYST FOR METHANATION REACTION, AND METHOD FOR PRODUCING METHANE
Document Type and Number:
WIPO Patent Application WO/2016/013488
Kind Code:
A1
Abstract:
This catalyst for methanation reaction is used for the purpose of methanizing carbon dioxide through a reaction with hydrogen. This catalyst for methanation reaction comprises: a stabilized zirconia carrier having a crystal structure of a tetragonal system, in which Ca and Ni are taken; and Ni in a metal state, which is supported by the stabilized zirconia carrier. This catalyst for methanation reaction contains, in atom% based on metals in elemental state, (A) 6-62 atom% of Zr that constitutes the stabilized zirconia carrier, (B) 1-20 atom% of Ca taken in the crystal structure and (C) 30-90 atom% of Ni taken in the crystal structure and Ni supported by the stabilized zirconia carrier in total, with the atomic ratio of Ca/(Zr + Ca) being 0.14-0.25.

Inventors:
HASHIMOTO KOJI (JP)
TAKANO HIROYUKI (JP)
IZUMIYA KOUICHI (JP)
KUMAGAI NAOKAZU (JP)
Application Number:
PCT/JP2015/070437
Publication Date:
January 28, 2016
Filing Date:
July 16, 2015
Export Citation:
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Assignee:
HITACHI SHIPBUILDING ENG CO (JP)
International Classes:
B01J23/78; B01J37/16; C07C1/12; C07C9/04; C07B61/00
Foreign References:
JP2010022944A2010-02-04
JP2011206770A2011-10-20
JP2009034650A2009-02-19
CN102151570A2011-08-17
Other References:
TAKANO HIROYUKI ET AL.: "The effect of heat treatment on the performance of the Ni/(Zr-Sm oxide) catalysts for carbon dioxide methanation", APPL. SURF. SCI., vol. 257, no. 19, 15 July 2011 (2011-07-15), pages 8171 - 8176, XP055390003
See also references of EP 3170554A4
Attorney, Agent or Firm:
OKAMOTO, HIROYUKI (JP)
Hiroyuki Okamoto (JP)
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