Title:
CELLULOSE DERIVATIVE AND METAL ADSORBENT CONTAINING SAID CELLULOSE DERIVATIVE
Document Type and Number:
WIPO Patent Application WO/2021/245832
Kind Code:
A1
Abstract:
Provided is a cellulose derivative that has excellent storage stability and that can selectively adsorb valuable metals and toxic metals. The cellulose derivative according to the present invention has a repeating unit represented by formula (I). In formula (I), Ras are identical or different from each other, and each represent a hydrogen atom or a group represented by formula (a). In formula (a), ring Z represents a heterocyclic ring including a nitrogen atom as a heteroatom, and R1 represents a single bond or an alkylene group having 1-10 carbon atoms. The four R2s are identical or different from each other, and each represent an alkyl group having 1-10 carbon atoms. It should be noted that, of all Ras included in the cellulose derivative, at least one is a group represented by formula (a).
Inventors:
MAEDA KATSUHIRO (JP)
TANIGUCHI TSUYOSHI (JP)
NISHIMURA TATSUYA (JP)
HASEGAWA HIROSHI (JP)
MORITA FUTO (JP)
YUNOSHITA KOKI (JP)
BISWAS FONI BUSHON (JP)
MASHIO ASAMI (JP)
ENDO MASARU (JP)
ARAI TAKASHI (JP)
TANIGUCHI TSUYOSHI (JP)
NISHIMURA TATSUYA (JP)
HASEGAWA HIROSHI (JP)
MORITA FUTO (JP)
YUNOSHITA KOKI (JP)
BISWAS FONI BUSHON (JP)
MASHIO ASAMI (JP)
ENDO MASARU (JP)
ARAI TAKASHI (JP)
Application Number:
PCT/JP2020/021903
Publication Date:
December 09, 2021
Filing Date:
June 03, 2020
Export Citation:
Assignee:
UNIV NAT CORP KANAZAWA (JP)
DAICEL CORP (JP)
DAICEL CORP (JP)
International Classes:
B01J20/24; B01J20/30; C02F1/28; C08B3/14
Domestic Patent References:
| WO2020027091A1 | 2020-02-06 | |||
| WO2020027009A1 | 2020-02-06 |
Foreign References:
| CN107501416A | 2017-12-22 | |||
| CN103598187A | 2014-02-26 | |||
| JP2018083882A | 2018-05-31 | |||
| JP2009247981A | 2009-10-29 |
Other References:
KROUIT MOHAMMED; GRANET ROBERT; BRANLAND PIERRE; VERNEUIL BERNARD; KRAUSZ PIERRE: "New photoantimicrobial films composed of porphyrinated lipophilic cellulose esters", BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, ELSEVIER, AMSTERDAM, NL, vol. 16, no. 6, 1 January 1900 (1900-01-01), AMSTERDAM, NL , pages 1651 - 1655, XP028755031, ISSN: 0960-894X, DOI: 10.1016/j.bmcl.2005.12.008
RONG LIDUO; ZENG MIN; LIU HONGCHEN; WANG BIJIA; MAO ZHIPING; XU HONG; ZHANG LINPING; ZHONG YI; YUAN JINYING; SUI XIAOFENG: "Biginelli reaction on cellulose acetoacetate: a new approach for versatile cellulose derivatives", CARBOHYDRATE POLYMERS, APPLIED SCIENCE PUBLISHERS , LTD BARKING, GB, vol. 209, 1 January 1900 (1900-01-01), GB , pages 223 - 229, XP085591063, ISSN: 0144-8617, DOI: 10.1016/j.carbpol.2019.01.036
MARI GRANSTRÖM ; JARI KAVAKKA ; ALISTAIR KING ; JOHANNA MAJOINEN ; VALTTERI MäKELä ; JUHO HELAJA ; SAMI HIETALA ; TOMMI VIRTANEN: "Tosylation and acylation of cellulose in 1-allyl-3-methylimidazolium chloride", CELLULOSE, KLUWER ACADEMIC PUBLISHERS (DORDRECHT), NL, vol. 15, no. 3, 14 February 2008 (2008-02-14), NL , pages 481 - 488, XP019601518, ISSN: 1572-882X
OSTROVSKAYA V M: "New test tools for determination of trace metals using polydentate cellulose", J ANAL CHEM, vol. 361, no. 3, 1 January 1998 (1998-01-01), pages 303 - 305, XP055880294, DOI: 10.1007/s002160050888
TERADA SUSUMU, SUO UEDANA, KOICHI KONDO, KIICHI TAKEMOTO: "Adsorption of gold ions by cellulose inducer", KOBUNSHI KAGAKU, vol. 29, no. 327, 1 July 1972 (1972-07-01), pages 500 - 504, XP055880301, DOI: 10.1295/koron1944.29.500
See also references of EP 4163009A4
RONG LIDUO; ZENG MIN; LIU HONGCHEN; WANG BIJIA; MAO ZHIPING; XU HONG; ZHANG LINPING; ZHONG YI; YUAN JINYING; SUI XIAOFENG: "Biginelli reaction on cellulose acetoacetate: a new approach for versatile cellulose derivatives", CARBOHYDRATE POLYMERS, APPLIED SCIENCE PUBLISHERS , LTD BARKING, GB, vol. 209, 1 January 1900 (1900-01-01), GB , pages 223 - 229, XP085591063, ISSN: 0144-8617, DOI: 10.1016/j.carbpol.2019.01.036
MARI GRANSTRÖM ; JARI KAVAKKA ; ALISTAIR KING ; JOHANNA MAJOINEN ; VALTTERI MäKELä ; JUHO HELAJA ; SAMI HIETALA ; TOMMI VIRTANEN: "Tosylation and acylation of cellulose in 1-allyl-3-methylimidazolium chloride", CELLULOSE, KLUWER ACADEMIC PUBLISHERS (DORDRECHT), NL, vol. 15, no. 3, 14 February 2008 (2008-02-14), NL , pages 481 - 488, XP019601518, ISSN: 1572-882X
OSTROVSKAYA V M: "New test tools for determination of trace metals using polydentate cellulose", J ANAL CHEM, vol. 361, no. 3, 1 January 1998 (1998-01-01), pages 303 - 305, XP055880294, DOI: 10.1007/s002160050888
TERADA SUSUMU, SUO UEDANA, KOICHI KONDO, KIICHI TAKEMOTO: "Adsorption of gold ions by cellulose inducer", KOBUNSHI KAGAKU, vol. 29, no. 327, 1 July 1972 (1972-07-01), pages 500 - 504, XP055880301, DOI: 10.1295/koron1944.29.500
See also references of EP 4163009A4
Attorney, Agent or Firm:
GOTO & CO. (JP)
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