Title:
COBALT COMPLEX, METHOD FOR MANUFACTURING SAME, AND METHOD FOR MANUFACTURING COBALT-CONTAINING THIN FILM
Document Type and Number:
WIPO Patent Application WO/2020/100765
Kind Code:
A1
Abstract:
Provided is a cobalt complex which is liquid at room temperature and useful for manufacturing a cobalt-containing thin film under conditions without using an oxidizing gas. A cobalt complex represented by formula (1). (L1 and L2 represent a unidentate amide ligand of formula (A), a bidentate amide ligand of formula (B) or a heteroatom-containing ligand of formula (C).) (R1 and R2 represent a C1-C6 alkyl group or a tri(C1-C6 alkyl)silyl group. A wiggly line represents an atomic bonding with a cobalt atom.) (R3 represents a tri(C1-C6 alkyl)silyl group. R4 and R5 represent a C1-C4 alkyl group. X represents a C1-C6 alkylene group.) (R6and R8 represent a C1-C6 alkyl group. R7 represents a hydrogen atom or a C1-C4 alkyl group. Y represents an oxygen atom or NR9. Z represents an oxygen atom or NR10. R9 and R10 independently represent a C1-C6 alkyl group.)
Inventors:
OIKE HIROYUKI (JP)
HAYAKAWA TEPPEI (JP)
YAMAMOTO YUKI (JP)
FURUKAWA TAISHI (JP)
TADA KEN-ICHI (JP)
HAYAKAWA TEPPEI (JP)
YAMAMOTO YUKI (JP)
FURUKAWA TAISHI (JP)
TADA KEN-ICHI (JP)
Application Number:
PCT/JP2019/043979
Publication Date:
May 22, 2020
Filing Date:
November 08, 2019
Export Citation:
Assignee:
TOSOH CORP (JP)
SAGAMI CHEM RES INST (JP)
SAGAMI CHEM RES INST (JP)
International Classes:
C07F19/00; C23C16/18; C07C49/12; C07C251/12; C07F7/10; C07F15/06
Domestic Patent References:
| WO2012060428A1 | 2012-05-10 | |||
| WO2014052316A1 | 2014-04-03 |
Foreign References:
| JP2017081857A | 2017-05-18 | |||
| JPH0314534A | 1991-01-23 | |||
| JPH02169547A | 1990-06-29 | |||
| JP2007153869A | 2007-06-21 | |||
| JP2009161513A | 2009-07-23 | |||
| JP2017081857A | 2017-05-18 | |||
| JP2016222568A | 2016-12-28 | |||
| JP2018507255A | 2018-03-15 | |||
| JP2018212049A | 2018-11-12 | |||
| JP2019022221A | 2019-02-07 | |||
| JP2019132379A | 2019-08-08 |
Other References:
SU , H. ET AL.: "Immobilization of transition metal (Fe2+, Co2+, V02+, or Cu2+) Schiff base complexes onto garaphene oxide as efficient and recyclable catalysts for epoxidation of styrene", RSC ADV., vol. 4, 2014, pages 9990 - 9996, XP055708239, DOI: 10.1039/c3ra47732k
WANG, X. ET AL.: "Oxovanadum(IV), copper (II) or cobalt(II) acetylacetone complexes immobilized on amino-functionalized CMK-3 for the aerobic epoxidation of styrene", APPL. ORGANOMETAL. CHEM., vol. 29, 2015, pages 698 - 706, XP055708241, DOI: 10.1002/aoc.3353
SUN, J. ET AL.: "Core-shell structured Fe304@Si02 supported cabalt(II) or copper(II) acetylacetonate complexes: magnetically recoverable nanocatalysts for aerobic epoxidation of styrene", CATALYSIS SCIENCE & TECHNOLOGY, vol. 4, 2014, pages 1246 - 1252, XP055708246
DATABASE Database [online] 1995, retrieved from STN Database accession no. 165406-56-4
DATABASE Database [online] 2014, retrieved from STN Database accession no. 1596799-36-8
DATABASE Database [online] 1992, retrieved from STN Database accession no. 139195-99-6
DATABASE Database [online] 1992, retrieved from STN Database accession no. 139195-95-2
DATABASE Database [online] 2014, retrieved from STN Database accession no. 1581228-67-2
PIERPONT, A. W. ET AL.: "Computational Study of Methane C-H Activation by First-Row Late Transition Metal LnM=E (M: Fe, Co, Ni) Complexes", INORG. CHEM., vol. 49, 2010, pages 2038 - 2046, XP022248190
PANDA, A. ET AL.: "Synthesis and Characterization of Three-Coordinate and Related (beta-Diketiminate Derivatives of Manganese, Iron, and Cobalt", INORG. CHEM., vol. 41, 2002, pages 3909 - 3916, XP002413781, DOI: 10.1021/ic025552s
ACS OMEGA, vol. 2, 2017, pages 5486
THERMOCHIMICA ACTA, vol. 404, 2003, pages 187
INORGANIC CHEMISTRY, vol. 53, 2014, pages 1962
THE JOURNAL OF ORGANIC CHEMISTRY, vol. 27, 1962, pages 1036
TETRAHEDRON LETTERS, vol. 48, 2007, pages 8281
THE JOURNAL OF ORGANIC CHEMISTRY, vol. 73, 2008, pages 8673
DALTON TRANSACTIONS, vol. 42, no. 11, 2013, pages 295
WANG, X. ET AL.: "Oxovanadum(IV), copper (II) or cobalt(II) acetylacetone complexes immobilized on amino-functionalized CMK-3 for the aerobic epoxidation of styrene", APPL. ORGANOMETAL. CHEM., vol. 29, 2015, pages 698 - 706, XP055708241, DOI: 10.1002/aoc.3353
SUN, J. ET AL.: "Core-shell structured Fe304@Si02 supported cabalt(II) or copper(II) acetylacetonate complexes: magnetically recoverable nanocatalysts for aerobic epoxidation of styrene", CATALYSIS SCIENCE & TECHNOLOGY, vol. 4, 2014, pages 1246 - 1252, XP055708246
DATABASE Database [online] 1995, retrieved from STN Database accession no. 165406-56-4
DATABASE Database [online] 2014, retrieved from STN Database accession no. 1596799-36-8
DATABASE Database [online] 1992, retrieved from STN Database accession no. 139195-99-6
DATABASE Database [online] 1992, retrieved from STN Database accession no. 139195-95-2
DATABASE Database [online] 2014, retrieved from STN Database accession no. 1581228-67-2
PIERPONT, A. W. ET AL.: "Computational Study of Methane C-H Activation by First-Row Late Transition Metal LnM=E (M: Fe, Co, Ni) Complexes", INORG. CHEM., vol. 49, 2010, pages 2038 - 2046, XP022248190
PANDA, A. ET AL.: "Synthesis and Characterization of Three-Coordinate and Related (beta-Diketiminate Derivatives of Manganese, Iron, and Cobalt", INORG. CHEM., vol. 41, 2002, pages 3909 - 3916, XP002413781, DOI: 10.1021/ic025552s
ACS OMEGA, vol. 2, 2017, pages 5486
THERMOCHIMICA ACTA, vol. 404, 2003, pages 187
INORGANIC CHEMISTRY, vol. 53, 2014, pages 1962
THE JOURNAL OF ORGANIC CHEMISTRY, vol. 27, 1962, pages 1036
TETRAHEDRON LETTERS, vol. 48, 2007, pages 8281
THE JOURNAL OF ORGANIC CHEMISTRY, vol. 73, 2008, pages 8673
DALTON TRANSACTIONS, vol. 42, no. 11, 2013, pages 295
Attorney, Agent or Firm:
T.S. PARTNERS et al. (JP)
Download PDF: