Field of the Disclosure

100011 This application relates generally to liquid concentrators, and more speci fically to compact, portable, cost-effective wastewater concentrators that can be easily connected to and use sources of waste heat and more specifically to compact, portable, cost-effective wastewater concentrators that simultaneously concentrate wastewater while removing contaminants dissolved within the wastewater stream.

Background

[0002] Concentration can be an effective form of treatment or pretreatment for a broad variety of wastewater streams and may be carried out within various types of commercial processing systems. At high levels of concentration, many wastewater streams may be reduced to residual material in the form of slurries containing high levels of dissolved and suspended solids. Such concentrated residual may be readily solidified by conventional techniques for disposal within landfills or, as applicable, delivered to downstream processes for further treatment prior to final disposal. Concentrating wastewater can greatly reduce freight costs and required storage capacity and may be beneficial in downstream processes where materials are recovered from the wastewater.

(0003) Characteristics of industrial wastewater streams are very broad as a result of the large number of industrial processes that produce them. Techniques for managing wastewater include: direct discharge to sewage treatment plants; pretreatment followed by discharge to sewage treatment plants; on-site or off-site processes to reclaim valuable constituents; and on- site or off-site treatment to simply prepare the wastewater for ultimate disposal. Where the wastewater source is an uncontrolled event, effective containment and recovery techniques must be included with any of these options.

[0004] An important measure of the effectiveness of a wastewater concentration process is the volume of residual produced in proportion to the volume of wastewater entering the process. In particular, low ratios of residual volume to feed volume (high levels of concentration) are the most desirable. Where the wastewater contains dissolved and/or suspended non-volatile matter, the volume reduction that may be achieved in a particular concentration process that relies on evaporation of volatiles is, to a great extent, limited by the method chosen to transfer heat to the process fluid. 10005] Generally, conventional processes that affect concentration by evaporation of water and other volatile substances use indirect heat transfer systems. Indirect heat transfer systems generally include a vessel that holds a process fluid and a plate, a bayonet tube, or a coil-type heat exchanger immersed within the process fluid. Mediums such as steam or hot oil are passed through the heat exchangers in order to transfer the heat required for evaporation.

[ 000 1 Indirect heat transfer systems that rely on heat exchangers such as plates, bayonet tubes, or coils are generally limited by the buildup of deposits of solids on the surfaces of the heat exchangers that come into direct contact with the process fluid. Also, the design of such systems is complicated by the need for a separate process to transfer heat energy to the heating medium such as a steam boiler or devices used to heat other heat transfer fluids such as hot oil heaters. This design leads to dependence on two indirect heat transfer systems to support the concentration process.

[0007] Feed streams that produce deposits on heat exchangers while undergoing processing are called fouling fluids. Where feed streams contain certain compounds, such as carbonates, for which solubility decreases with increasing temperature (i.e., inverse solubility), deposits, generally known as boiler scale, will form even at relatively low concentrations due to the elevated temperatures at the surfaces of the heat exchangers. Further, when compounds that have high solubility at elevated temperatures such as sodium chloride are present in the wastewater feed, they will also form deposits by precipitating out of the solution as the process fluid reaches high concentrations (i.e., saturation). Built up layers of solids on heat exchange surfaces act as an insulation barrier that reduces the rate of heat transfer. Additionally, solid deposits may have the potential to corrode certain materials within the heat exchanger. Such deposits, which necessitate frequent cycles of heat exchange surface cleaning to maintain process efficiency and to reduce the potential for corrosion, may be any combination of suspended solids earned into the process with the wastewater feed and solids that precipitate out of the process fluid. To counteract the loss of efficiency and to extend time between cleanings, designers of indirect heat exchange evaporators generally scale up the heat exchange surfaces. In other words, indirect heat exchange surfaces are built larger than needed to reduce cleaning cycles. Additionally, to counteract the potential for corrosion, designers typically select expensive high alloy materials for the heat exchangers. The effect of solid buildup in indirect heat exchangers imposes practical limits on the range of wastewater that might be effectively managed, especially when the range of wastewater includes fouling fluids. Therefore, processes that rely on indirect heat transfer mechanisms are generally unsuitable for concentrating wide varieties of wastewater streams and achieving low ratios of residual to feed volume.

[0008] Due to the factors listed above, designers of indirect heat exchange evaporators must balance cost, clean ing cycles, corrosion resistance, and efficiency when designing such systems. In order to extend the time between cleaning cycles, indirect heat exchange evaporators are often limited in di fferential pressure, which limits the maximum concentration of the process fluid. As a result, known indirect heat exchange evaporators are often limited to less than 20% total solids as a maximum concentration in order to reduce the rate of solid buildup on the heat exchange surfaces.

10009] Another drawback to known indirect heat exchange evaporators is the large amount of heat required to evaporate water in the wastewater. At sea level, generally 1 Btu/Lb/°F is required to heat the wastewater to its boiling point (this heat is generally called "sensible heat"). Thereafter, approximately 1 ,000 Btu/Lb is required to effect evaporation of the water (this heat is generally known as "latent heat").

[00101 Some indirect heat exchange evaporators have attempted to reduce the amount of thermal energy required to evaporate the water. In particular, a multi-stage indirect evaporative process has been developed that operates under a partial vacuum in an effort to reduce the thermal energy required. Although such designs have been somewhat effective in reducing the amount of thermal energy required, these designs are very expensive and they remain subject to the drawbacks discussed above, in particular, solid deposits and concentration limits.

[001 1 ] In addition to evaporation, some traditional wastewater treatment systems include a series of process steps, or "unit operations," that interact to provide a final treated product that is safe. Examples these types of wastewater treatment systems include conventional sewage treatment systems. Conventional sewage treatment systems include process steps, such as, dewatering, heating, microbiological digestion (aerobic and anaerobic), pH adjustment, precipitation, sludge thickening, sludge drying, and denitrificaion and filtration of treated effluent. Even with the several process steps, which are aimed at cleaning the sewage and producing a safe product, the end product of conventional sewage treatment systems is generally a sludge of some sort. Some of the resultant sludge may contain heavy metals that precipitated out of solution during the treatment process. These heavy metals may be toxic and the heavy metals are difficult to extract from the sludge. (0012] Another drawback to conventional sewage treatment systems is that the process fluid is very sensitive to variations in pH . Moreover, the process fluid may contain compounds that interfere with the microbiological digestion. In other words, the process fluid may contain compounds that are harmful to the bacteria used in the conventional sewage treatment systems.

[0013J Yet another conventional method of treating wastewater is a filtration system.

Filtration systems may use a diverse range of filtration methods to puri fy wastewater. Some examples of filtration methods are reverse osmosis, ultrafiltration, and ion exchange. Each of these filtration systems includes a certain degree of sensitivity to contaminants on membranes within the system. Thus, the membranes must be backwashed or cleaned regularly. Moreover, secondary systems may be needed to remove these contaminants, resulting in a more expensive and complex system.

Summary

[00l4j A compact liquid concentrating device may be easily connected to a source of waste heat, such as a natural gas flare or a combustion engine exhaust stack, and use this waste heat to perform a direct heat transfer concentration and contaminant removal process without the need of large and expensive containment vessels and without a lot of expensive high temperature resistant materials. The compact liquid concentrator includes a gas inlet, a gas exit and a mixing or flow corridor connecting the gas inlet and the gas exit, wherein the flow corridor includes a narrowed portion that accelerates the gas through the flow corridor. A liquid inlet located between the gas inlet and the narrowed portion of the How corridor, injects liquid into the gas stream at a point prior to the narrowed portion so that the gas-liquid mixture is thoroughly mixed within the flow corridor, causing a portion of the liquid to be evaporated or concentrated. A demister or fluid scrubber downstream of the narrowed portion, and connected to the gas exit, removes entrained liquid droplets from the gas stream and re-circulates the removed liquid to the liquid inlet through a re-circulating circuit. Fresh liquid to be concentrated is also introduced into the re-circulating circuit at a rate sufficient to offset the combined total of liquid evaporated in the flow corridor and any concentrated liquid that is withdrawn from the process.

[0015] The compact liquid concentrator described herein includes a number o f attributes that operate to cost-effectively concentrate wastewater streams having broad ranges of

characteristics. The concentrator is resistant to corrosive effects over a broad range of feed characteristics, has reasonable manufacturing and operating costs, is able to operate

continuously at high levels of concentration, and efficiently utilizes heat energy directly from a wide variety of sources. Moreover, the concentrator is compact enough to be portable, and so may be easily transported to locations where wastewater is generated through uncontrolled events and can be installed in close proximity to waste heat sources, such as natural gas well Hares. Thus, the concentrator described herein is a cost-effective, reliable and durable device that operates to continuously concentrate a broad range of di fferent types of wastewater streams, and that eliminates the use of conventional solid-surface heat exchangers found in conventional indirect heat transfer systems which lead to clogging and deposit buildups.

10016] The compact liquid concentrator advantageously operates on direct heat exchange without the need for solid heat exchange surfaces. As a result, the compact liquid concentrator is not subject the drawbacks of solid deposits on heat exchange surfaces. Moreover, the compact liquid concentrator is able to operate continuously at very high levels of wastewater concentration. High turbulence in the concentrator forestalls the formation of large crystals and keeps solids suspended in solution. As a result, the compact liquid concentrator experiences very little solid buildup on surfaces. Precipitated solids may be removed from the concentrator through a side process, such as a settling tank or a vacuum belt filter, while the liquid portion is returned to the concentrator. In this way, the concentrator approaches a zero liquid discharge during continuous operation. The precipitated solids may often be deposited in a landfill for disposal.

[0017j In one embodiment of the concentrator a reagent may be added to the wastewater pre or post concentration. The reagent may chemically or mechanically react with hazardous components of the wastewater to produce non-hazardous or insoluble products. Thus, the concentrator may be useful in removing harmful substances from wastewater streams.

Brief Description of the Drawings

[0018| Fig. 1 is a perspective view of a compact liquid concentrator;

[001 9] Fig. 2 is a close up perspective view of a concentration/evaporation section of the compact liquid concentrator of Fig. 1 ;

[0020] Fig. 3 is a schematic view of the compact liquid concentrator o f Fig. 1 ; and [0021 ] Fig. 4 is a perspective view of another embodiment of a compact liquid concentrator.

Detailed Description

[0022] Fig. 1 illustrates one particular embodiment of a compact liquid concentrator 1 10, which is connected to a source of waste heat in the form of a natural gas flare from a natural gas well. General ly speaking, the compact liquid concentrator 1 10 operates to concentrate wastewater, such as flowback water from a natural gas well, using exhaust or waste heat created within a natural gas flare that burns natural gas in a manner that meets the standards set by the U.S. Environmental Protection Agency (EPA ) and/or local regulatory authority. As is known, most natural gas wells include a Hare which is used to burn excess natural gas. Typically, the gas exiting the flare is between 1200 and 1 500 degrees Fahrenheit and may reach 1800 degrees Fahrenheit. The compact liquid concentrator 1 00 is equally effective in concentrating landfill leachate or other produced waters and may be operated on exhaust gas from a landfill gas flare, a propane flare, or heat from virtual ly any other source.

1002 1 As illustrated in Fig 1 , the compact liquid concentrator 1 10 generally includes or is connected to a flare assembly 1 1 5, and includes a heat transfer assembly 1 1 7, an air

pre-treatment assembly 1 19, a concentrator assembly 120 (shown in more detail in Fig. 2), a fluid scrubber 122, and an exhaust section 124. Importantly, the flare assembly 1 1 5 includes a flare 130, which burns natural gas (or other combustible fuel) therein according to any known principles, and a flare cap assembly 132. The Hare cap assembly 1 2 may include a moveable cap 134 (e.g., a flare cap, an exhaust gas cap, etc.) which covers the top of the flare 1 30, or other type of stack (e.g., a combustion gas exhaust stack), to seal off the top of the flare 1 30 when the flare cap 134 is in the closed position, or to divert a portion of the flare gas in a partially closed position, and which allows gas produced within the flare 130 to escape to the atmosphere through an open end that forms a primary gas outlet 143, when the flare cap 134 is in an open or partially open position. The flare cap assembly 132 also includes a cap actuator, such as a motor 1 35 (see Fig. 3) which moves the flare cap 134 between the fully open and the fully closed positions. The flare cap actuator may utilize a chain drive or any other type of drive mechanism connected to the flare cap 134 to move the flare cap 134 around a pivot point. The flare cap assembly 132 may also include a counter- weight (see Fig. 3) disposed on the opposite side of the pivot point from the flare cap 1 34 to balance or offset a portion of the weight of the flare cap 134 when moving the flare cap 134 around the pivot point. The counter-weight enables the actuator to be reduced in size or power while still being capable of moving or rotating the flare cap 134 between an open position, in which the top of the flare 130 (or the primary combustion gas outlet 143) is open to the atmosphere, and a closed position, in which the flare cap 1 34 covers and essentially seals the top of the flare 130 (or the primary combustion gas outlet 143). The flare cap 134 itself may be made of high temperature resistant material, such as stainless steel or carbon steel, and may be lined or insulated with refractory material including aluminum oxide and/or zirconium oxide on the bottom portion (hereof which comes into direct contact with the hot flare ases when the flare cap 134 is in the closed position.

[00241 I desired, the flare 1 30 may include an adapter section 1 38 including the primary combustion gas outlet 143 and a secondary combustion gas out let 1 41 upstream of the primary combustion gas outlet 143. When the flare cap 1 30 is in the closed position, or in a partially closed position, combustion gas is diverted through the secondary combustion gas outlet 141 . The adapter section 138 may include a connector section 1 39 that connects the flare 1 30 (or exhaust stack) to the heat transfer section 1 1 7 using a 90 degree elbow or turn. Other connector arrangements are possible. For example, the flare 1 30 and heat transfer section 1 1 7 may be connected at virtually any angle between 0 degrees and 180 degrees. In this case, the flare cap assembly 1 2 is mounted on the top of the adaptor section 138 proximate the primary combustion gas outlet 143.

[0025] As i llustrated in Fig. 1 the heat transfer assembly 1 1 7 includes a transfer pipe 1 40, which connects to an inlet of the air pre-treatment assembly 1 19 to the flare 130 and, more particularly, to the adaptor section 138 of the flare 130. A support member 142, in the form of a vertical bar or pole, supports the heat transfer pipe 1 40 between the flare 130 and the air pre- treatment assembly 1 1 9 at a predetermined level or height above the ground. The heat transfer pipe 140 is connected to the connector section 139 or the adapter section 138 at the secondary combustion gas outlet 141 , the transfer pipe forming a portion of a fluid passageway between the adapter section 138 and a secondary process, such as a fluid concentrating process. The support member 142 may be necessary because the heat transfer pipe 140 will generally be made of metal, such as carbon or stainless steel, and may be refractory lined with materials such as aluminum oxide and/or zirconium oxide, to withstand the temperature of the gas being transferred from the flare 130 to the air pre-treatment assembly 1 19. Thus, the heat transfer pipe 140 will typically be a heavy piece of equipment. Flowever, because the flare 130, on the one hand, and the air pre-treatment assembly 1 1 and the concentrator assembly 120, on the other hand, are disposed immediately adjacent to one another, the heat transfer pipe 140 generally only needs to be of a relatively short length, thereby reducing the cost of the materials used in the concentrator 1 1 0, as well as reducing the amount of support structure needed to bear the weight of the heavy parts of the concentrator 1 10 above the ground. As i llustrated in Fig. 1 , the heat transfer pipe 140 and the air pre-treatment assembly 1 19 form an upside-down U-shaped structure. |002ί>1 I he air pre-treatment assembly 1 19 includes a vertical piping section 150 and an ambient air valve 306 (see Fig. 3) disposed at the top of the vertical piping section 1 50. The ambient air valve 306 (also referred to as a damper or bleed valve) forms a fluid passageway between the heat transfer pipe 140 (or air pre-treatment assembly 1 1 ) and the atmosphere. The ambient air valve 306 operates to allow ambient air to (low through a mesh screen 1 52 (typically wire or metal) and into the interior of the air pre-treatment assembly 1 1 9 to mix with the hot gas coming from the tlare 130. If desired, the air pre-treatment assembly 1 19 may include a permanently open section proximate to the ambient air valve 306 which always allows some amount of bleed air into the air pre-treatment assembly 1 19, which may be desirable to reduce the size of the required ambient air valve 306 and for safety reasons. A pressure blower (not shown) may be connected to the inlet side of the ambient air valve 306, if desired, to force ambient air through the ambient air valve 306. If a pressure blower is implemented, the screen 152 and permanently open section (i f implemented) may be relocated to the inlet side of the pressure blower. While the control of the ambient air 306 will be discussed in greater detail hereinafter, the ambient air valve 306 generally allows the gas from the flare 130 to be cooled to a more desirable temperature before entering into the concentrator assembly 120. The air pre- treatment assembly 1 19 may be supported in part by cross-members 1 54 connected to the support member 142. The cross-members 1 54 stabi lize the air pre-treatment assembly 1 1 9, which is also typically made of heavy carbon or stainless steel or other metal, and which may be refractory- lined to improve energy efficiency and to withstand the high temperature of the gases within this section of the concentrator 1 10. If desired, the vertical piping section 150 may be extendable to adapt to or account for flares of di ffering heights so as to make the liquid concentrator 1 10 easily adaptable to many different flares or to flares of different heights and also to improve efficiency when erecting concentrators by correcting for slight vertical and/or horizontal misalignment of components. The vertical piping section 1 50 may include a first section 1 50A (shown using dotted lines) that rides inside of a second section 1 50B thereby allowing the vertical piping section 150 to be adj ustable in length (height).

[0027] Generally speaking, the air pre-treatment assembly 1 19 operates to mix ambient air provided through the ambient air valve 306 beneath the screen 152 and the hot gas flowing from the flare 130 through the heat transfer pipe 140 to create a desired temperature of gas at the inlet of the concentrator assembly 120.

[0028| The liquid concentrator assembly 120 includes a lead-in section 156, having a reduced cross-section at the bottom end thereof, which mates the bottom of the piping section 1 50 to a quencher 159 of the concentrator assembly 120. The concentrator assembly 120 also includes a first fluid inlet 1 60, which injects new or untreated liquid to be concentrated, such as ftowback water from a natural gas well, into the interior of the quencher 1 59. While not shown in Fig. 1 , the inlet 160 may include a coarse sprayer with a large nozzle for spraying the untreated liquid into the quencher 1 59. Because the liquid being sprayed into the quencher 159 at this point in the system is not yet concentrated, and thus has large amount of water therein, and because the sprayer is a coarse sprayer, the sprayer nozzle is not subject to fouling or being clogged by the small particles within the liquid. As will be understood, the quencher 1 59 operates to quickly reduce the temperature of the gas stream (e.g., from about 900 degrees Fahrenheit to less than 200 degrees Fahrenheit) while performing a high degree of evaporation on the liquid injected at the inlet 160. I f desired, a temperature sensor 308 (see Fig. 3) may be located at or near the exit of the piping section 150 or in the quencher 1 59 and may be used to control the position of the ambient air valve to thereby control the temperature of the gas present at the inlet of the concentrator assembly 120.

1002 1 As shown in Figs. 1 and 2, the quencher 1 59 is connected to liquid injection chamber which is connected to a nan-owed portion or a venturi section 162 which has a narrowed cross section with respect to the quencher 1 59 and which has a venturi plate 1 63 (shown in dotted line) disposed therein. The venturi plate 1 63 creates a narrow passage through the venturi section 162, which creates a large pressure drop between the entrance and the exit of the venturi section 162. This large pressure drop causes turbulent gas flow and shearing forces within the quencher 1 59 and the top or entrance of the venturi section 162, and causes a high rate of gas flow out of the venturi section 162, both of which lead to thorough mixing of the gas and liquid in the venturi section 162. The position of the venturi plate 163 may be controlled with a manual control rod 165 (see Fig. 2) connected to the pivot point of the plate 163, or via an automatic positioner that may be driven by an electric motor or pneumatic cylinder.

(0030] A re-circulating pipe 166 extends around opposite sides of the entrance of the venturi section 162 and operates to inject partially concentrated (i.e., re-circulated) liquid into the venturi section 162 to be further concentrated and/or to prevent the formation of dry particulate within the concentrator assembly 1 20 through multiple fluid entrances located on one or more sides of the flow corridor. While not explicitly shown in Figs. 1 and 2, a number of pipes, such as three pipes of, for example, ½ inch diameter, may extend from each of the opposites legs of the pipe 166 partially surrounding the venturi section 162, and through the walls and into the interior of the venturi section 162. Because the liquid being ejected into the concentrator 1 10 at this point is re-circulated liquid, and is thus either partially concentrated or bei ng maintained at a particular equilibrium concentration and more prone to plug a spray nozzle than the less concentrated liquid injected at the inlet 1 60, this liquid may be directly injected without a sprayer so as to prevent clogging. However, i f desired, a baffle in the form of a Hat plate may be disposed in front of each of the openings of the ½ diameter pipes to cause the liquid being injected at this point in the system to hit the baffle and disperse into the concentrator assembly 1 20 as smaller droplets. In any event, the configuration of this re-circulating system distributes or disperses the re-circulating liquid better within the gas stream flowing through the

concentrator assembly 1 0.

[00311 The combined hot gas and liquid flows in a turbulent manner through the venturi section 162. As noted above, the venturi section 162, which has a moveable venturi plate 163 disposed across the width of the concentrator assembly 120, causes turbulent flow and complete mixture of the liquid and gas, causing rapid evaporation of the discontinuous liquid phase into the continuous gas phase. Because the mixing action caused by the venturi section 162 provides a high degree of evaporation, the gas cools substantially in the concentrator assembly 120, and exits the venturi section 162 into a flooded elbow 164 at high rates of speed. In fact, the temperature of the gas-liquid mixture at this point may be about 160 degrees Fahrenheit. In one embodiment, the total length of the concentrator assembly may be 20 feet or less, particularly between about 4 feet to about 12 feet, and more particularly between about 5 feet and about 10 feet. In one embodiment, the maximum cross sectional area of the venturi section 162 may be about 25 square feet or less, particularly between about 2 square feet and about 16 square feet, and more particularly between about 3 square feet and about 8 square feet. The above described dimensions produce an efficient and sufficient amount of turbulence in the gas/l iquid flow that enhances heat and mass transfer between the gas and the liquid particles because these dimensions result in the formation of a signi ficant amount of interfacial area between the gas and liquid phases. In one embodiment, in which 8.75 gallons per minute of wastewater that contained approximately 26% total solids by weight was introduced into the concentrator 1 10, while 85 gallons per minute of concentrated wastewater was continually recirculated from the sump 172 (for a total of approximately 93.75 gallons per minute of fluid total), along with approximately 14,000 cubic feet per minute of combustion gas, created approximately 5.26 acres/minute of total interfacial area between the gas and liquid phases (assuming an average liquid particle size of approximately 1 1 0 microns in diameter). This amount of interfacial area far exceeds the interfacial area achievable in known indirect heat exchanger evaporation systems.

[0032 ] A weir arrangement (not sho n) w ithin the bottom of the Hooded elbow 164 maintains a constant level of partially or fully concentrated re-circulated liquid disposed therein. Droplets of re-circulated liquid that are entrained in the gas phase as the gas-liquid mixture exits the venturi section 1 62 at high rates of speed arc thrown outward onto the surface of the recirculated liquid held within the bottom of the flooded elbow 164 by centri fugal force generated when the gas-liquid mixture is forced to turn 90 degrees to flow into the fluid scrubber 122. Significant numbers of l iquid droplets entrained within the gas phase that impinge on the surface of the re-circulated liquid held in the bottom of the flooded elbow 1 64 coalesce and join with the re-circulated liquid thereby increasing the volume of re-circulated liquid in the bottom of the flooded elbow 164 causing an equal amount of the re-circulated liquid to overflow the weir arrangement and flow by gravity into the sump 1 72 at the bottom of the fluid scrubber 122. Thus, interaction of thc gas-liquid stream with the liquid within the flooded elbow 164 removes liquid droplets from the gas-liquid stream, and also prevents suspended particles within the gas- liquid stream from hitting the bottom of the flooded elbow 164 at high velocities, thereby preventing erosion of the metal that forms the portions of side walls located beneath the level of the weir arrangement and the bottom of the flooded elbow 1 64.

[0033] After leaving the flooded elbow 164, the gas-liquid stream in which evaporated liquid and some liquid and other particles still exist, flows through the fluid scrubber 122 which is, in this case, a cross-flow fluid scrubber. The fluid scrubber 122 includes various screens or filters which serve to remove entrained liquids and other particles from the gas-liquid stream. In one particular example, the cross flow scrubber 122 may include an initial coarse impingement baffle 1 69 at the input thereof, which is designed to remove liquid droplets in the range of 50 to 100 microns in size or higher. Thereafter, two removable filters in the form of chevrons 1 70 are disposed across the fluid path through the fluid scrubber 122, and the chevrons 170 may be progressively sized or configured to remove liquid droplets of smaller and smaller sizes, such as 20-30 microns and less than 10 microns. Of course, more or fewer filters or chevrons could be used.

|0034J As is typical in cross flow scrubbers, liquid captured by the filters 169 and 1 70 and the overflow weir arrangement within the bottom of the flooded elbow 164 drain by gravity into the reservoir or sump 1 72 located at the bottom of the fluid scrubber 122. The sump 1 72, which may hold, for example, approximately 200 gallons of liquid, thereby collects concentrated fluid containing dissolved and suspended solids removed from the gas-liquid stream and operates as a reservoir for a source of re-circulating concentrated liquid back to the concentrator assembly 120 to be further treated and/or to prevent the formation of dry particulate within the concentrator assembly 120. In one embodiment, the sump 172 may include a sloped V-shaped bottom 1 71 having a V-shaped groove 1 75 extending from the back of the fluid scrubber 122 (furthest away from the flooded elbow 1 64) to the front of the fluid scrubber 122 (closest to the flooded elbow 164), wherein the V-shaped groove 1 75 is sloped such that the bottom of the V-shaped groove 175 is lower at the end of the fluid scrubber 122 nearest the flooded elbow 164 than at an end farther away from the flooded elbow 164. in other words, the V-shaped bottom 171 may be sloped with the lowest point of the V-shaped bottom 171 proximate the exit port 1 73 and/or the pump 182. Additionally, a washing circuit 177 (see Fig. 3) may pump concentrated fluid from the sump 172 to a sprayer 179 within the cross flow scrubber 122, the sprayer 179 being aimed to spray liquid at the V-shaped bottom 1 71. Alternatively, the sprayer 179 may spray un- concentrated liquid or clean water at the V-shaped bottom 171. The sprayer 1 79 may periodically or constantly spray liquid onto the sur face of the V-shaped bottom 171 to wash solids and prevent solid buildup on the V-shaped bottom 1 71 or at the exit port 173 and/or the pump 1 82. As a result of this V-shaped sloped bottom 1 71 and washing circuit 1 77, liquid collecting in the sump 1 72 is continuously agitated and renewed, thereby maintaining a relatively constant consistency and maintaining solids in suspension. If desired, the spraying circuit 1 77 may be a separate circuit using a separate pump with, for example, an inlet inside of the sump 172, or may use a pump 1 82 associated with a concentrated liquid re-circulating circuit described below to spray concentrated fluid from the sump 1 72 onto the V-shaped bottom 171.

[0035] As illustrated in Fig. 1 , a return line 1 80, as well as the pump 182, operates to recirculate fluid removed from the gas-liquid stream from the sump 1 72 back to the concentrator 120 and thereby complete a fluid or liquid re-circulating circuit. Likewise, a pump 184 may be provided within an input line 1 86 to pump new or untreated liquid, such as flowback water from a natural gas well, to the input 160 of the concentrator assembly 120. Also, one or more sprayers (not shown) may be disposed inside the fluid scrubber 122 adjacent the chevrons 170 and may be operated periodically to spray clean water or a portion of the wastewater feed on the chevrons 170 to keep them clean.

[0036] Concentrated liquid also may be removed from the bottom of the fluid scrubber 122 via the exit port 1 73 and may be further processed or disposed of in any suitable manner in a side-arm process or secondary re-circulating circuit 181 . In particular, the concentrated liquid removed by the exit port 1 73 contains a certain amount o f suspended solids, which preferably may be separated from the liquid portion of the concentrated liquid and removed from the system using the secondary re-circulating circuit 1 8 1 . In one example, the concentrated fl uid may include from between about 50% to about 60% total solids. Concentrated liquid removed from the ex it port 173 may be transported through the secondary re-circulating circuit 1 81 to one or more solid/liquid separating devices 183, such as gravity settling tanks, vibrating screens, rotary vacuum filters, horizontal belt vacuum filters, belt presses, fi lter presses, and/or hydro- cyclones. The solid/liquid separating device 1 83 may provide a zone of low turbulence that favors crystallization of precipitates, which may cause particles of suspended solids to enlarge, settle more rapidly and separate more readily. After the suspended solids and liquid portion of the concentrated wastewater are separated by the solid/liquid separating device 183, the liquid portion of the concentrated wastewater with suspended particles substantially removed may be returned to the sump 1 72 for further processing in the first or primary re-circulating circuit connected to the concentrator. The solid portion of the concentrated wastewater, which in one embodiment may include approximately 80% total solids or more, may be removed from the system through extraction port 215 and disposed of by depositing the solid portion in a landfill, for example. Alternatively, the solid portion of the concentrated wastewater may undergo further processing to recover salable materials, such as road salt, or ingredients for drilling mud.

[00 71 The gas, which flows through and out of the fluid scrubber 122 with the liquid and suspended solids removed therefrom, exits out of piping or ductwork at the back of the fluid scrubber 122 ( downstream of the chevrons 1 70) and flows through an induced draft fan 190 of the exhaust assembly 124, from where it is exhausted to the atmosphere in the form of the cooled hot inlet gas mixed with the evaporated water vapor. Of course, an induced draft fan motor 192 is connected to and operates the fan 1 90 to create negative pressure within the fluid scrubber 1 22 so as to ultimately draw gas from the flare 1 30 through the transfer pipe 140, the air pre-treatment assembly 1 19 and the concentrator assembly 120. The induced draft fan 1 90 needs only to provide a slight negative pressure within the fluid scrubber 122 to assure proper operation of the concentrator 1 10.

[0038J While the speed of the induced draft fan 190 can be varied by a device such as a variable frequency drive operated to create varying levels of negative pressure within the fluid scrubber 122 and thus can usually be operated within a range of gas flow capacity to assure complete gas flow from the flare 130, i f the gas being produced by the flare 130 is not of sufficient quantity, the operation of the induced draft fan 190 cannot necessarily be adjusted to assure a proper pressure drop across the fluid scrubber 1 22 itself. That is, to operate efficiently and properly, the gas flowing through the fluid scrubber 122 must be at a sufficient (minimal) flow rate at the input of the fluid scrubber 1 22. Typically this requirement is controlled by keepi ng at least a preset minimal pressure drop across the fluid scrubber 122. However, i f the flare 1 30 is not producing at least a minimal level of gas, increasing the speed of the induced draft fan 190 will not be able to create the required pressure drop across the fluid scrubber 1 22.

(0039] To compensate for this situation, the cross How scrubber 1 22 is designed to include a gas re-circulating circuit which can be used to assure that enough gas is present at the input of the fluid scrubber 1 22 to enable the system to acquire the needed pressure drop across the fluid scrubber 122. In particular, the gas re-circulating circuit includes a gas return line or return duct 196 which connects the high pressure side of the exhaust assembly 124 (e.g., downstream of the induced draft fan 190) to the input of the fluid scrubber 1 22 (e.g., a gas input of the fluid scrubber 122) and a baffle or control mechanism 198 disposed in the return duct 196 which operates to open and close the return duct 1 96 to thereby fluidly connect the high pressure side of the exhaust assembly 124 to the input of the fluid scrubber 122. During operation, when the gas entering i nto the fluid scrubber 122 is not of sufficient quantity to obtain the minimal required pressure drop across the fluid scrubber 1 22, the baffle 198 (which may be, for example, a gas valve, a damper such as a louvered damper, etc.) is opened to direct gas from the high pressure side of the exhaust assembly 124 (i.e., gas that has traveled through the induced draft fan 1 90) back to the input of the fluid scrubber 122. This operation thereby provides a sufficient quantity of gas at the input of the fluid scrubber 122 to enable the operation of the induced draft fan 190 to acquire the minimal required pressure drop across the fluid scrubber 122.

[0040] Referring back to Fig. 2, it will be seen that the front the flooded elbow 164 of the concentrator assembly 120 also includes a quick opening access door 200, which allows easy access to the inside o f the flooded elbow 1 4. However, similar quick opening access doors could be located on any desired part of the fluid concentrator 1 10, as most of the elements of the concentrator 1 0 operate under negative pressure.

(00411 The combination of features i llustrated in Figs. 1 and 2 makes for a compact fluid concentrator 1 10 that uses waste heat in the form of gas resulting from the operation of a natural gas flare, which waste heat would otherwise be vented directly to the atmosphere. Importantly, the concentrator 1 10 uses only a minimal amount of expensive high temperature resistant material to provide the piping and structural equipment required to use the high temperature gases exiting from the flare 1 30. For example, the small length of the transfer pipe 140, which is made o f the most expensive materials, is minimized, thereby reducing the cost and weight of the fluid concentrator 1 10. Moreover, because of the small size of the heat transfer pipe 140, only a single support member 142 is needed thereby further reducing the costs of building the concentrator 1 1 0. Still further, the fact that the air pre-treatment assembly 1 19 is disposed directly on top of the fluid concentrator assembly 120, with the gas in these sections flowing downward towards the ground, enables these sections of the concentrator 1 1 to be supported directly by the ground or by a skid on which these members are mounted. This configuration keeps the concentrator 1 10 disposed very close to the Hare 1 30, making it more compact.

Likewise, this configuration keeps the high temperature sections of the concentrator 1 10 (e.g., the top o f the Hare 130, the heat transfer pipe 140 and the air pre-treatment assembly 1 19) above the ground and away from accidental human contact, leading to a safer configuration. In fact, due to the rapid cooling that takes place in the venturi section 162 of the concentrator assembly 120, the venturi section 162, the flooded elbow 1 64 and the fluid scrubber 122 are typically cool enough to touch without harm (even when the gases exiting the flare 130 are at 1800 degrees Fahrenheit). Rapid cooling of the gas-liquid mixture allows the use of generally lower cost materials that are easier to fabricate and that are corrosion resistant. Moreover, parts

downstream of the flooded elbow 164, such as the fluid scrubber 122, induced draft fan 190, and exhaust section 1 24 may be fabricated from materials such as fiberglass.

[0042] The fluid concentrator 1 10 is also a very fast-acting concentrator. Because the concentrator 1 10 is a direct contact type of concentrator, it is not subject to deposit buildup, clogging and fouling to the same extent as most other concentrators. Still further, the ability to control the flare cap 134 to open and close, depending on whether the concentrator 1 10 is being used or operated, allows the flare 130 to be used to bum gas without interruption when starting and stopping the concentrator 1 10. More particularly, the flare cap 134 can be quickly opened at any time to allow the flare 130 to simply burn gas as normal while the concentrator 1 10 is shut down. On the other hand, the flare cap 134 can be quickly closed when the concentrator 1 10 is started up, thereby diverting hot gasses created in the flare 1 30 to the concentrator 1 1 0, and allowing the concentrator 1 10 to operate without interrupting the operation of the flare 130. In either case, the concentrator 1 10 can be started and stopped based on the operation of the flare cap 134 without interrupting the operation of the flare 130.

[0043] If desired, the flare cap 134 may be opened to a partial amount during operation of the concentrator 1 10 to control the amount of gas that is transferred from the flare 130 to the concentrator 1 10. This operation, in conj unction with the operation o f the ambient air valve, may be useful in controlling the temperature of the gas at the entrance of the venturi section 1 62.

[00441 Moreover, due to the compact configuration of the air pre- treatment assembly 1 1 , the concentrator assembly 120 and the fluid scrubber 1 22, parts of the concentrator assembly 1 20, the fluid scrubber 122, the draft fan 190 and at least a lower portion of the exhaust section 124 can be permanently mounted on (connected to and supported by) a skid or plate. The upper parts o f the concentrator assembly 120, the air pre-treatment assembly 1 1 9 and the heat transfer pipe 1 40, as well as a top portion of the exhaust stack, may be removed and stored on the skid or plate for transport, or may be transported in a separate truck. Because of the manner in which the low er portions of the concentrator 1 10 can be mounted to a skid or plate, the concentrator 1 10 is easy to move and install. In particular, during set up of the concentrator 1 1 0, the skid, with the fluid scrubber 122, the flooded elbow 164 and the draft fan 190 mounted thereon, may be offloaded at the site at which the concentrator 1 10 is to be used by simply offloading the skid onto the ground or other containment area at which the concentrator 1 10 is to be assembled. Thereafter, the venturi section 162, the quencher 1 59, and the air pre-treatment assembly 1 19 may be placed on top of and attached to the flooded elbow 164. The piping section 1 50 may then be extended in height to match the height of the flare 1 30 to which the concentrator 1 10 is to be connected. In some cases, this may first require mounting the flare cap assembly 132 onto a pre-existing flare 1 0. Thereafter, the heat transfer pipe 140 may be raised to the proper height and attached between the flare 130 and the air pre-treatment assembly 1 19, while the support member 142 is disposed in place. For concentrators in the range of 10,000 to 30,000 gallons per day evaporative capacity, it is possible that the entire flare assembly 1 1 5 may be mounted on the same skid or plate as the concentrator 120.

[0045] Because most of the pumps, fluid lines, sensors and electronic equipment are disposed on or are connected to the fluid concentrator assembly 1 20, the fluid scrubber 1 22 or the draft fan assembly 190, setup of the concentrator 1 10 at a particular site requires only minimal plumbing, mechanical, and electrical work at the site. As a result, the concentrator 1 10 is relatively easy to install and to set up at (and to disassemble and remove from) a particular site. Moreover, because a majority of the components of the concentrator 1 10 are permanently mounted to the skid, the concentrator 1 10 can be easily transported on a truck or other delivery vehicle and can be easily dropped off and installed at particular location, such as next to a landfill flare. 100461 Fig. 3 illustrates a schematic diagram of a control system 300 that may be used to operate the concentrator 1 10 of Fig. 1 . As illustrated in Fig. 3, the control system 300 includes a controller 302, which may be a form of digital signal processor type of controller, a

programmable logic controller (PLC) which may run, for example, ladder logic based control, or any other type of controller. The controller 302 is, of course, connected to various components within the concentrator 1 10, In particular, the controller 302 is connected to the flare cap drive motor 135, which controls the opening and closing operation of the flare cap 134. The motor 135 may be set up to control the flare cap 1 34 to move between a fully open and a fully closed position. However, if desired, the controller 302 may control the drive motor 135 to open the flare cap 134 to any of a set of various di fferent controllable positions between the fully opened and the fully closed position. The motor 135 may be continuously variable if desired, so that the flare cap 134 may be positioned at any desired point between fully open and fully closed.

(00471 Additionally, the controller 302 is connected to and controls the ambient air inlet valve 306 disposed in the air pre-treatrnent assembly 1 19 of Fig. 1 upstream of the venturi section 162 and may be used to control the pumps 182 and 184 which control the amount of and the ratio of the injection of new liquid to be treated and the re-circulating liquid being treated within the concentrator 1 10. The controller 302 may be operatively connected to a sump level sensor 3 1 7 (e.g., a float sensor, a non-contact sensor such as a radar or sonic unit, or a differential pressure cell). The controller 302 may use a signal from the sump level sensor 31 7 to control the pumps 182 and 184 to maintain the level of concentrated fluid within the sump 172 at a predetermined or desired level. Also, the controller 302 may be connected to the induced draft fan 190 to control the operation of the fan 190, which may be a single speed fan, a variable speed fan or a continuously controllable speed fan. In one embodiment, the induced draft fan 190 is driven by a variable frequency motor, so that the frequency of the motor is changed to control the speed of the fan. Moreover, the controller 302 is connected to a temperature sensor 308 disposed at, for example, the inlet of the concentrator assembly 120 or at the inlet of the venturi section 162, and receives a temperature signal generated by the temperature sensor 308. The temperature sensor 308 may alternatively be located downstream of the venturi section 162 or the temperature sensor 308 may include a pressure sensor for generating a pressure signal.

[0048J During operation and at, for example, the initiation of the concentrator 1 10, when the flare 130 is actually running and is thus burning natural gas, the controller 302 may first turn on the induced draft fan 190 to create a negative pressure within the fluid scrubber 122 and the concentrator assembly 120. The controller 302 may then or at the same time, send a signal to the motor 1 35 to close the flare cap 1 34 either partially or completely, to direct waste heat from the flare 130 into the transfer pipe 140 and thus to the air pre-treatment assembly 1 19. Based on the temperature signal from the temperature sensor 308, the controller 302 may control the ambient air valve 306 (typically by closing this valve partially or completely) and/or the flare cap actuator to control the temperature of the gas at the inlet of the concentrator assembly 120. Generally speaking, the ambient air valve 306 may be biased in a fully open position (i.e., may be normally open) by a biasing element such as a spring, and the controller 302 may begin to close the valve 306 to control the amount of ambient air that is diverted into the air pre-treatment assembly 1 1 (due to the negative pressure in the air pre-treatment assembly 1 19), so as to cause the mixture of the ambient air and the hot gases from the flare 130 to reach a desired

temperature. Additionally, if desired, the controller 302 may control the position of the flare cap 134 (anywhere from fully open to fully closed) and may control the speed of the induced draft fan 190, to control the amount of gas that enters the air pre-treatment assembly 1 19 from the flare 130. As will be understood, the amount of gas flowing through the concentrator 1 10 may need to vary depending on ambient air temperature and humidity, the temperature of the flare gas, the amount of gas exiting the flare 130, etc. The controller 302 may therefore control the temperature and the amount of gas flowing through the concentrator assembly 120 by controlling one or any combination of the ambient air control valve 306, the position of the flare cap 134 and the speed of the induced draft fan 190 based on, for example, the measurement of the temperature sensor 308 at the inlet of the concentrator assembly 120. This feedback system is desirable because, in many cases, the air coming out of a flare 130 is between 1200 and 1800 degrees Fahrenheit, which may be too hot, or hotter than required for the concentrator 1 10 to operate efficiently and effectively.

[0049| In any event, as illustrated in Fig. 3, the controller 302 may also be connected to a motor 310 which drives or controls the position of the venturi plate 163 within the narrowed portion of the concentrator assembly 120 to control the amount of turbulence caused within the concentrator assembly 120. Still further, the controller 302 may control the operation of the pumps 182 and 1 84 to control the rate at which (and the ratio at which) the pumps 182 and 184 provide re-circulating liquid and new waste fluid to be treated to the inputs of the quencher 1 59 and the venturi section 1 62. In one embodiment, the controller 302 may control the ratio of the re-circulating fluid to new fluid to be about 10: 1 , so that if the pump 1 84 is providing 8 gallons per minute of new liquid to the input 160, the re-ci rculating pump 1 82 is pumping 80 gallons per minute. Additionally, or alternatively, the controller 302 may control the flow of new liquid to be processed into the concentrator ( via the pump 1 84) by maintaining a constant or predetermined level of concentrated liquid in the sump 1 72 using, for example, the level sensor 3 1 7. Of course, the amount of liquid in the sump I 72 will be dependent on the rate of concentration in the concentrator, the rate at which concentrated liquid is pumped from or otherwise exists the sump 1 72 via the secondary re-circulating circuit and the rate at which liquid from the secondary re-circulating circuit is provided back to the sump 1 72 , as well as the rate at which the pump 1 82 pumps liquid from the sump 172 for delivery to the concentrator via the primary re-circulating circuit.

[0050| I f desired, one or both of the ambient air valve 306 and the flare cap 1 34 may be operated in a fail-safe open position, such that the flare cap 1 34 and the ambient air valve 306 open in the case of a failure of the system (e.g., a loss of control signal) or a shutdown of the concentrator 1 10. In one case, the flare cap motor 1 35 may be spring loaded or biased with a biasing element, such as a spring, to open the flare cap 1 34 or to allow the flare cap 1 34 to open upon loss of power to the motor 1 35. Alternatively, the biasing element may be the counterweight 1 37 on the flare cap 134 may be so positioned that the flare cap 134 itself swings to the open position under the applied force of the counter-weight 1 37 when the motor 1 35 loses power or loses a control signal. This operation causes the flare cap 134 to open quickly, either when power is lost or when the controller 302 opens the flare cap 134, to thereby allow hot gas within the flare 1 30 to exit out of the top of the flare 1 30. Of course, other manners of causing the flare cap 1 34 to open upon loss of control signal can be used, including the use of a torsion spring on the pivot point 136 of the flare cap 1 34, a hydraulic or pressurized air system that pressurizes a cylinder to close the flare cap 1 34, loss of which pressure causes the flare cap 1 34 to open upon loss of the control signal, etc.

[0051 ) Thus, as will be noted from the above discussion, the combination of the flare cap 1 34 and the ambient air valve 306 work in unison to protect the engineered material incorporated into the concentrator 1 1 0, as whenever the system is shut down, the flare cap and the air valve 306 automatically immediately open, thereby isolating hot gas generated in the flare 1 30 from the process while quickly admitting ambient air to cool the process.

[0052] Moreover, in the same manner, the ambient air valve 306 may be spring biased or otherwise configured to open upon shut down of the concentrator 1 10 or loss of signal to the valve 306. This operation causes quick cooling of the air pre-treatment assembly 1 1 9 and the concentrator assembly 1 20 when the flare cap 1 34 opens. Moreover, because of the quick opening nature of the ambient air valve 306 and the flare cap 134, the controller 302 can quickly shut down the concentrator 1 10 without having to turn off or effect the operation of the flare 1 30.

(0053) Furthermore, as illustrated in the Fig, 3, the controller 302 may be connected to the venturi plate motor 3 1 0 or other actuator which moves or actuates the angle at which the venturi plate 1 3 is disposed within the venturi section 1 62. Using the motor 3 1 0, the controller 302 may change the angle of the venturi plate 1 3 to alter the gas flow through the concentrator assembly 120, thereby changing the nature of the turbulent flow of the gas through concentrator assembly 1 20, which may provide for better mixing of the liquid and gas therein and obtain better or more complete evaporation of the liquid. In this case, the controller 302 may operate the speed of the pumps 182 and 1 84 in conjunction with the operation of the venturi plate 163 to provide for optimal concentration of the wastewater being treated. Thus, as will be understood, the controller 302 may coordinate the position of the venturi plate 163 with the operation of the flare cap 134, the position of the ambient air or bleed valve 306, and the speed of the induction fan 1 0 to maximize wastewater concentration (turbulent mixing) without fully drying the wastewater so as to prevent formation of dry particulates. The controller 302 may use pressure inputs from the pressure sensors to position the venturi plate 1 63. Of course, the venturi plate 163 may be manually controlled or automatical ly controlled.

[0054] The controller 302 may also be connected to a motor 312 which controls the operation of the damper 198 in the gas re-circulating circuit of the fluid scrubber 122. The controller 302 may cause the motor 312 or other type of actuator to move the damper 1 98 from a closed position to an open or to a partially open position based on, for example, signals from pressure sensors 313, 3 1 5 disposed at the gas exit and the gas entrance of the fluid scrubber 122, respectively. The controller 302 may control the damper 1 98 to force gas from the high pressure side of the exhaust section 124 (downstream of the induced draft fan 190) into the fluid scrubber entrance to maintain a predetermined minimum pressure difference between the two pressure sensors 31 3, 315. Maintaining this minimum pressure di fference assures proper operation of the fluid scrubber 122. Of course, the damper 198 may be manually controlled instead or in addition to being electrically controlled.

[0055] As will be understood, the concentrator 1 10 described herein directly utilizes hot waste gases in processes after the gases have been thoroughly treated to meet emission standards, and so seamlessly separates the operational requirements of the process that generates the waste heat from the process which utilizes the waste heat in a simple, reliable and effective manner. 100561 While the liquid concentrator 1 10 has been described above as being connected to a natural gas Hare to use the waste heat generated in the natural gas flare, the liquid concentrator 1 10 can be easily connected to other sources of waste heat. For example, another embodiment of the concentrator 1 10 may be connected to an exhaust stack of a combustion engine plant and to use the waste heat from the engine exhaust to perform liquid concentration. While, in yet another embodiment, the engine within the plant may operate on land fill gas to produce electricity, the concentrator 1 10 can be connected to run with exhaust from other types of engines, including other types of combustion engines, such as those that operate on gasoline, diesel fuel, propane, natural gas, etc.

[0057] Removal of Contaminants from Wastewater and/or Combustion Gas

10058 [ Embodiments of the concentrators and processes described above can be readily modified to accommodate the removal of contaminants from the wastewater being concentrated and also from the combustion gas employed to concentrate that wastewater. Such modifications are contemplated to be particularly advantageous where the contaminants sought to be removed are among those whose emissions are typically regulated by governmental authorities.

Examples of such contaminants include barium and other harmful materials (e.g., calcium, iron, magnesium potassium, sodium, strontium, sulfate, etc.) dissolved in flowback water from natural gas wells. Additionally, fouling substances, such as scaling metals, may be removed from flowback water. Described below are modifications that may be made to the embodiments of the concentrators and processes described above to accommodate removal of barium or other harmful materials or scaling metals, but the description is not intended to be limiting to the removal of only such contaminants.

[0059) For example, two methods of removal of contaminants from wastewater include pre- concentration treatment and post-concentration treatment. More particularly, contaminants may be scrubbed by injecting a reagent or stabilizing compound into the wastewater that reacts chemically or mechanically with the contaminant prior to wastewater concentration, or contaminants may be scrubbed by mixing a stabilizing compound into the concentrated wastewater after concentration.

|0060] In the pre-conccntration treatment method, contaminants may be either sequestered or stabilized. In pre-concentration sequestration, a reagent (e.g., sodium sulfate) is mixed with the wastewater prior to concentration and the reagent chemically reacts with the contaminant to form an insoluble chemical compound (e.g., barium sulfate) that precipitates out of solution. The insoluble chemical compound may settle out of the concentrated wastewater, for example, in the settling tank 1 83 (Fig. 1 ). Once the insoluble chemical compound settles out of the concentrated wastewater in the settli ng tank, the insoluble chemical compound may be drawn off, along with other solids, for example, through the extraction port 21 5.

10061 j In pre-concentration stabi lization, a stabi lizing compound is mixed with the wastewater prior to concentration and the stabi lizing compound reacts chemically or

mechanically with the contaminant to render the contaminant non-hazardous or insoluble. For example, the stabil izing compound may encase the contaminant in a crystalline matrix that is insoluble. Thus, the contaminant is also rendered insoluble. Once stabilized, the contaminant and stabilizing compound may be extracted, for example, from the settling tank 183, similar to pre-concentration sequestration.

[0062] Post-concentration stabilization includes mixing a stabilizing compound with the concentrated wastewater in the settling tank 183. The stabilizing compound reacts chemically or mechanically to render the contaminant non-hazardous or insoluble, similar to the pre- concentration stabilization. The stabilized contaminant may be removed, for example, from the settling tank 183 and through the extraction port 21 5.

10063 J Both the pre-concentration and post-concentration removal methods described above may be used to remove high levels of dissolved barium (e.g., barium chloride) from flowback water. Barium is a known hazardous material that is occasionally found dissolved in flowback water from natural gas wells. Flowback water from natural gas wells in the Marcellus Shale Bed (located in the vicinity of the northern Appalachian Mountains) contains high levels of dissolved barium. Additionally, this flowback water contains extremely high levels of total dissolved solids, in the range of 250,000 parts per million (ppm) or 25% by weight, or higher. Such high levels of dissolved solids are extremely difficult to concentrate via conventional methods.

However, these high levels of dissolved solids are treatable with the concentrator disclosed herein. Soluble barium compounds, such as those found in some flowback water, are highly poisonous if ingested. As a result, disposal of barium compounds is often regulated by state or federal authorities.

[0064J As described above, two examples of methods of barium removal from flowback water using the disclosed concentrator are pre-concentration treatment and post-concentration treatment. In pre-treatment sequestering certain chemical reagents are added to the flowback water before the flowback water is injected into the concentrator causing chemical reactions with the barium ions to form insoluble barium compounds. In pre or post-concentration stabilization barium compounds are mechanically or chemically prevented from reacting chemically with other compounds to produce unwanted barium compounds, such as barium compounds that are soluble.

[0065] Pre-Concentration Barium Sequestration

(0066) As discussed above, flowback water from natural gas wells can contain high levels of dissolved barium compounds. One such dissolved barium compound is barium chloride. A method o f removing the barium from the flowback water involves chemically reacting the barium chloride with another substance to produce a relatively insoluble barium compound. One way to accomplish this reaction is to introduce a reagent comprising a sulfate ion into the flowback water. A particularly useful reagent is sodium sulfate. Other useful reagents include, but are not limited to, aluminum sulfate, ammonium sulfate, magnesium sulfate, potassium sulfate, and sulfuric acid. The sul fate ion from the reagent reacts with the barium ion to form barium sulfate (BaSO,}). Barium sulfate is highly insoluble and precipitates out of solution rapidly. One advantage to the pre-concentration sequestration of barium by precipitating barium sul fate is that barium sulfate may be disposed o relatively inexpensively by depositing the barium sulfate in a landfill.

10067] Barium sulfate will not leach from a landfill back into groundwater due to the high insolubility of barium sulfate, even in the presence of strong acids. In fact, in spite of barium's toxicity to humans, barium sulfate is used in the medical community to diagnose certain digestive tract illnesses because the barium sulfate shows up on x-rays and because the barium sulfate will not dissolve even in the presence of stomach acid. Thus, barium sulfate passes harmlessly though the digestive tract. This high insolubility of barium sulfate leads to solid waste containing barium sulfate passing the Toxicity Characteristic Leaching Procedure (TCLP) administered by the Environmental Protection Agency (EPA). The EPA requires certain wastes to pass the TCLP test before approving such wastes for disposal in landfills. Barium is one waste product required to pass the TCLP test. TCLP is one of the Federal EPA test methods that are used to exclude leachable toxic substances from landfills. The TCLP test is outlined in EPA publication SW-846, entitled "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods," which is hereby incorporated by reference herein. If a substance passes the TCLP test, that substance is classi fied as non-hazardous and may be disposed of in a landfill . Another EPA test used to exclude potentially dangerous substances from landfills is the Paint Filter Test. 10068 J Referring again to Figs, 1 and 2, to implement one of the bari um removal methods described above, the concentrator section 1 20 may include a reagent inlet 1 S7 that is connected to a supply of reagent in a tank 193 (e.g., sodium sulfate, sulfuric acid, aluminum sul fate, ammonium sulfate, magnesium sulfate, or potassium sulfate, etc.) by a reagent supply line 1 89. A reagent pump 191 may pressurize the reagent supply line 1 89 with reagent material from the tank 193 so that the reagent material is ejected into the concentrator section 120 (e.g., upstream of, or proximate to, the venturi 162) to mix with the exhaust gas from the flare 130 or generator and flowback water injected by the inlet 160. The reagent pump 191 may be operatively connected to the control ler 302 (see Fig. 3) and the controller 302 may operate the reagent pump 1 91 to meter reagent based on gas and flowback water flow rates to ensure proper ratios and mixing. When mixed with the flowback water in the concentrator section 120, the reagent reacts with dissolved barium ions to form bari um sulfate, which rapidly precipitates out of solution in solid form. Due to the ability of the concentrator 1 10 to handle very high levels of total solids, the precipitated barium sulfate is maintained in suspension and eventually ends up in the settling tank 183 along with other materials that make up a solid portion of the concentrated flowback water. Solid and liquid portions of the concentrated flowback water separate from one another in the settling tank 183. I f the solid portions, which may contain up to about 20% liquid, need further separation, some of the solid portion may be drawn off from the settling tank 1 83 through line 221 and directed to a further separation device, such as a rotary belt vacuum filter 223. Liquid from the rotary belt vacuum fi lter 223 may be returned to the concentrator via line 225 into the sump 172 of the demister 122. Solids may be removed from the rotary belt vacuum filter 223 through an exit line 227 for disposal, for example in a landfill. Alternatively, solids removed from the rotary belt vacuum filter 223 may be puri fied and sold, for example to mining companies, as drilling mud.

10069] Alternatively, a pre-concentration sequestration process may involve mixing the reagent with the flowback w ater upstream of the flowback water inlet 160, for example in a sequential mixing and settling tank 201 (See Fig. 4). In this case, reagent material may be supplied to the sequential mixing and settling tank 201 from a supply of reagent material in a tank 203 via a reagent supply line 195. A reagent supply pump 205 may supply the reagent material under pressure to the sequential mixing and settling tank 201 . The reagent supply pump 205 may be operatively connected to the controller 302 (see Fig. 3 ) and the controller 302 may operate the reagent supply pump 205 to meter reagent based on gas and flowback water flow rates to ensure proper ratios and mixing. Barium precipitates out of solution as barium sulfate, as described above, and may be drawn out of the mixing and settling tank 201 through a line 207, prior to introduction into the concentrator. The solid portion, which may include up to about 20% liquid, may be further separated in a solid/l iquid separating device, such as a rotary belt vacuum filter 23 1 or other separating device. Thereafter, barium sulfate may be drawn off through a line 233 and may be further processed, purified, and sold, for example to dri lling companies for use in drilling mud.

10070] Because the reagent supplied to react with the dissolved barium ions may also react with other dissolved compounds in the flowback water, such as calcium, greater quantities of reagent may be needed than would otherwise be needed to react with the barium alone. For example, in some cases between approximately 150% and 600% more reagent may be mixed with the flowback water than would be required by the amount of barium in the flowback water alone. Preferably between 200% and 500% more reagent may be used, and more preferably approximately 400% more reagent may be used. By providing excess amounts of reagent, almost all dissol ved barium will precipitate out of the flowback water. Some other dissolved reactive materials that may be found in llowback water include, calcium, magnesium, and strontium. In some cases, the product o f the reagent reaction with these additional metals may result in commercially salable products. As a result, these additional products may also be drawn off through the line 233 for further processing. Alternatively, these additional products may simply be fed into the concentrator with the flowback water, as the concentrator is capable of handling large amounts of suspended solids, as described above.

10071 1 Pre or Post Concentration Stabilization

|0072j Another way to remove barium from llowback water is to chemically or mechanically stabilize the barium either before or after the flowback water is concentrated. If the barium is not treated before concentration, the dissolved barium ions may react with other chemicals in the llowback water to fonn compounds that will precipitate out of solution when concentrations of the compounds reach saturation. Some of these barium compounds are water soluble and must be stabilized prior to extraction from the concentrator system. These barium compounds may be stabilized, for example, in the settling tank 1 83. The barium compounds may be mechanically or chemically stabilized. With mechanical stabilization, the barium compounds are incased in glass, or other crystalline structure so that the barium compounds cannot react with other materials, or cannot dissolve in solution. In chemical stabilization, a reagent is provided into the settling tank that reacts with the barium compounds to produce insoluble compounds. In either case, the stabilizing compound may be pumped into the settling tank 1 83 from a tank 21 1 (see Fig. 1 ) via a pipeline 21 3, for example. The stabilized compounds may be drawn out of the settling tank 1 83 via the extraction port 2 15. In th is case, the stabilized bari um compounds are insoluble and wi l l not leach out in the presence o f strong acids. As a result, the stabilized barium compounds wi ll pass the TC LP test.

1007 1 Alternatively, the stabilizing reagent may be added to the wastewater before the wastewater is introduced into the concentrator 1 10 through the wastewater inlet 1 60 using, for example, the concentrator of Fig. 4 by pumping stabilizing agent from the tank 203 into the mixing and settling tank 201 . In this case, the stabilizing agent may prevent certain chemical reactions of the barium that would result in soluble barium compounds. The stabilizing agent could also be introduced into the concentrator 1 1 0 separately from the wastewater using, for example, the concentrator of Fig. 1 by pumping stabilizing agent from the tank 197 (Fig. 4) into port 1 99, so that the stabilizing agent and the wastewater mix in the concentrating section 120 of the concentrator 1 10. In these cases, the insoluble solids formed by reaction between the barium and the stabilizing agent ultimately end up in the settling tank 1 83, where the insoluble barium compounds may be further processed as described above.

Example test results

[0074] The following paragraphs describe actual test results of one embodiment of the disclosed concentrator when used to concentrate samples of llowback water containing dissolved barium. These test results are examples only and are not meant to limit the disclosed concentrator, or operation of the disclosed concentrator, in any way.

(0075] In a first test, the disclosed concentrator was used to concentrate flowback water from a natural gas well located in Pennsylvania. The chemical breakdown of the flowback water is listed below in Table 1 .

Hydroxide mg/l ND

Total mg/l ND

Ammonia as N mg/l

Total Kjeldahl N mg/l

BOD (5 Day) mg/l 150

CO D mg/l 20,000

TOC mg/l 1,250

Anions

Chloride mg/l 160,000

Flouride mg/l 0.22

Nitrogen Nitrate as N mg/l

Total Ortho Phosphate as P mg/l

Total Phosphorous mg/l

Sulfate mg/l ND

Sulfide mg/l

Metals (SW1311)

Aluminum mg/l

Antimony mg/l

Arsenic mg/l 0.022

Barium mg/l 7,700

Beryllium mg/l

Boron mg/l

Cadmium mg/l 0.0094

Calcium mg/l

Cerium mg/l

Chromium mg/l 0.036

Cobalt mg/l

Copper mg/l

Iron mg/l

Lead mg/l 0.025

Magnesium mg/l

Manganese mg/l

Molybdenum mg/l

Nickel mg/l

Potassium mg/l

Mercury mg/l ND

Radium mg/l

Selenium mg/l 0.34

Silicon mg/l

Silver mg/l ND

Sodium mg/l

Strontium mg/l 6,400

Thallium mg/l

Tin mg/l

Titanium mg/l

77

Table 1

10076] As illustrated in Table 1 , the flowback sample included approximately 260,000 mg/l total solids (see line 3 of Table 1 ). After processing, a heavy slurry was extracted from the grav ity settling tank including over 800.000 mg/l total solids. Supernatant liquid from the gravity settling tank was re-circulated into the concentrator as described above. The concentrator experienced no deleterious effects from scaling or blockages. Stack tests on the exhaust slack indicated that gaseous emissions remained within the permitted ranges established by local regulatory authorities. In other words, the disclosed concentrator does not significantly change the chemical makeup of gas emissions from existing exhaust stacks. As a result of this first test, the disclosed concentrator proved its ability to process liquids with extremely high levels of total solids.

10077] Several more tests were conducted on the wastewater sample of Table 1 . Two test runs are summarized below in Table 2, Test 2A and Test 2B. In Test 2A, the wastewater was pretreated with approximately 45 g/1 of Na ₂ S0 ₄ . During Test 2 A the pH of the wastewater was varied from about 1 to about 4. In Test 2B, the wastewater was treated with approximately 22.5 g/1 of Na ₂ S0 ₄ (or about half the amount of Na ₂ S0 ₄ of Test 2A) and the pH of the wastewater was varied from about 1 to about 4. The test results for Test 2A and 2B are summarized below in Table 2.

Barium 100% 100% 99% 100% 81 % 65% 62% 69%

Calcium 30% 30% 35% ^"" 22% ^~ 15% 20% 20% 18%

Iron 58% 79% 87% 75% 54% 84% 88% 75%

Magnesium 7% 0% 7% 5% 0% 7% 0% 2%

Potassium 21 % 21 % 28% 23% 17% 17% 21 % 18%

Sodium -24% -24% -17% -22% -20% -15% -13% -16%

Strontium 78% 76% 78% 77% 37% 35% 35% 36%

Sulfate

Initial pH 4,88 4.87 4.88 4.88 4.88 4,89 4.85 4.87

I H2S04 Added (mis) 0.9 0.2 0,05 0.38 0.9 0.12 0.05 0.36 pH after Acid Addition 1 .51 2,1 3.39 2.33 1.5 2.36 3.23 2.36 pH after Sodium Sulfate

1 .69 2.32 3.59 2.53 1.56 2.48 3.33 2.46

Addition ^*

Amt Sodium Sulfate

4.5 4.5 4.5 4.50 2.25 2.25 2.25 2.25 Added (g/100mls feed)

Amount

mg 44 10 2 19 44 6 2 17 Acid added

Amount

S04 in mg 43 10 2 18 43 6 2 17 H2S04

Amount

S04 in mg 3042 3042 3042 3042 1521 1521 1521 1521 Na2S04

Total S04

mg 3085 3052 3045 3061 1564 1527 1524 1538 added

S04 mg 771 771 760 767 624 498 476 533

Required for

Conversion

of Removed %of S04

25% 25% 25% 25% 40% 33% 31 % 35% Ba to added

BaS04

S04 mg 460 449 460 457 219 208 208 212

Required for

Conversion %of S04

of Removed 15% 15% 15% 15% 14% 14% 14% 14% added

Sr to SrS04

S04 mg 1440 1440 1680 1520 720 960 960 880

Required for

Conversion

of Removed %of S04

47% 47% 55% 50% 46% 63% 63% 57% Ca to added

CaS04

Sulfate in

%of S04

Removed 87% 87% 95% 90% 100% 109% 108% 106% added

Ba, Sr, Ca

Sulfate in mg 290 330 340 320 1 1 0 0 4 Filtrate %of S04

9% 1 1 % 1 1 % 10% 1 % 0% 0% 0% added

Sulfate in

Removed of

97% 98% 106% 101 % 103% 1 10% 108% 107% Ba, Sr, Ca + Consumed

Filtrate

Table 2

(0078] As illustrated in Table 2, the wastewater feed contained approximately 1 1 ,000 mg/1 of barium (see line 5 of Table 2). Almost all of the barium was precipitated out of solution with the addition of sodium sulfate in Test 2A. More particularly, at a pH of between 1 and 2, only 0.5 mg/1 of barium remained in solution, at a pH of between 2 and 3, only 0.36 mg/1 of barium remained in solution, and at a pH of between 3 and 4, only 160 mg/1 of barium remained in solution (see line 5 of Table 2). Approximately 4 times the theoretical amount of sodium sulfate was mixed with the wastewater because the sulfate reacts also with other chemical compounds in the wastewater. The excess sodium sulfate ensures that virtually all of the barium precipitates out of solution, especially at lower pH levels.

[0079] During another test, one embodiment of the concentrator was used to concentrate wastewater from a known difficult-to-treat source of wastewater. The difficult-to-treat wastewater included the chemical makeup illustrated below in Table 3.

Table 3

[0080) The wastewater was treated to zero liquid discharge and solids produced by the treatment process passed both the Paint Filter and TCLP tests. Results of the this test are summarized below in Table 4 in which results of several samples are listed, (e.g., sample IDs 01 -09) Test

Sample ID

01 02 03 04 and 05 06 08 and 09 Procedure

Pretreatment Pretreatment Pretreatment

Filtrate Pretreatment Filtrate After Solid After

Residual Residual

Current Filtrate After Adding 2101b Addition of

Filtrate Solids

(Feed+210lb Acid Addition Sodium All

Sulfate) Sulfate Acid+Sulfate

Units mg/L mg/L mg/L mg/L mg/L mg/L

SW-846 pH pH 5,84 < 0.160 < 0,050 < 0.020 9045C

Sulfate, SW-846 Colorimetric Sulfate 100 180 860 410 9038

Total Metals SW-846 by ICP Barium 3400 6.3 13 46 89 220 6010B

Total Metals SW-846 by ICP Calcium 23000 23000 16000 25000 39000 13000 6010B

Total Metals SW-846 by ICP Iron 2.7 72 98 170 230 87 6010B

Total Metals SW-846 by ICP Magnesium 2200 2100 2100 800 4700 1200 6010B

Total Metals SW-846 by ICP Potassium 440 410 380 ND 950 330 6010B

Total Metals SW-846 by ICP Sodium 55000 55000 59000 110000 39000 230000 6010B

Total Metals SW-846 by ICP Strontium 5200 2300 730 1600 1300 6700 6010B

Table 4

[00811 In this test, sodium sulfate was again used as the pre-treatment reagent. Concentrated wastewater was sent to a gravity settling tank. Solids were drawn out of the gravity settling tank and were further separated in a vacuum belt filtration system. This process yielded a zero liquid discharge rate from the concentrator. All supernatant liquid was re-circulated through the concentrator as described above. The resultant solids passed both the Paint Filter and TCLP tests. Table 4 summarizes the chemical makeup of the solids before and after concentration. As illustrated above, barium levels were not reduced to zero in this test. However, current

regulations allow up to 100 mg 1 of detectable barium, thus the resultant solids passed the TCLP test.

[0082] With the barium level in pre-treated wastewater liquid feed at 46 mg I (see line 6 of Table 4), solids that settled out of the feed liquid passed the TCLP with non-detectable amounts of barium. When pre-treated feed was passed through the concentrator and solids were removed from the vacuum belt fi lter, the liquid phase from which the solids were removed contained 220 mg/1 o f Barium (see line 6 of Tabic 4) while the collected solids passed both the Paint Filter Test and the TC LP test with non-detectable levels of barium.

[0083] While certain representative embodiments and details have been shown for purposes of illustrating the invention, it will be apparent to those skilled in the art that various changes in the methods and apparatus disclosed herein may be made without departing from the scope of the invention. For example, the disclosed concentrator may be used to scrub contaminants other than barium from wastewater. In particular, other contaminants may be scrubbed from wastewater by injecting a reagent from the reagent tank either into the wastewater upstream of wastewater injection into the venturi section, or into the venturi section simultaneously with the wastewater. Additionally, other contaminants may be chemically or mechanically stabi lized by either injecting a reagent or stabilizing substance into the wastewater upstream of wastewater injection into the venturi section, or injecting a reagent or stabilizing substance into the settling tank.