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Title:
CYCLOTRIARYLPHOSPHINE, METHOD FOR PREPARING SAME, AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2024/060641
Kind Code:
A1
Abstract:
The present invention provides a cyclotriarylphosphine ligand represented by general formula (I), and a method for preparing same. The present invention also provides a complex of palladium in coordination with the cyclotriarylphosphine ligand. A catalytic system consisting of the cyclotriarylphosphine ligand and a palladium salt or the complex and use of the palladium complex thereof in catalyzing an organic reaction, in particular use in catalyzing a coupling reaction involving a (pseudo) halogenated aromatic hydrocarbon as the substrate, are also parts of the present invention.

Inventors:
SHI JICHENG (CN)
CHENG GUOYU (CN)
ZHANG LIXUE (CN)
ZHOU FABIN (CN)
Application Number:
PCT/CN2023/093725
Publication Date:
March 28, 2024
Filing Date:
May 12, 2023
Export Citation:
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Assignee:
DONGGUAN STEPHEN CATALYST CO LTD (CN)
International Classes:
C07F9/50; B01J31/24; C07C67/343; C07C69/76; C07D295/033; C07F9/6568; C07F9/6571
Domestic Patent References:
WO2022132048A12022-06-23
Foreign References:
CN115850329A2023-03-28
US20130217876A12013-08-22
CN110240616A2019-09-17
CN113087746A2021-07-09
CN1444590A2003-09-24
Other References:
BABER R. ANGHARAD, HADDOW MAIRI F., MIDDLETON ANN J., ORPEN A. GUY, PRINGLE PAUL G., HAYNES ANTHONY, WILLIAMS GARY L., PAPP RAINER: "Ligand Stereoelectronic Effects in Complexes of Phospholanes, Phosphinanes, and Phosphepanes and Their Implications for Hydroformylation Catalysis", ORGANOMETALLICS, AMERICAN CHEMICAL SOCIETY, vol. 26, no. 3, 1 January 2007 (2007-01-01), pages 713 - 725, XP093149286, ISSN: 0276-7333, DOI: 10.1021/om060912v
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