Claim of Priority

[0001] This application claims priority to U.S. Patent Application No. 16/840,892 filed on April 6, 2020, the entire contents of which are hereby incorporated by reference.

Background

[0002] The production of crude oil and other hydrocarbons starts with the drilling of a wellbore into a hydrocarbon reservoir. In many cases, the hydrocarbon reservoir is a narrow layer of material in the subterranean environment, making efficient targeting of the wellbore important for productivity. Accordingly, identifying the reservoir layer is important for determining the wellbore location, and drilling the wellbore to that location, for example, by directional drilling.

[0003] A depositional environment in which the rock of the reservoir layer, and surrounding layers, formed is helpful for identifying the reservoir layer and locating a reservoir within the reservoir layer. The depositional environment is the environment in which the material forming the sedimentary rock and sand of the layers of the subterranean environment formed, such as in a river bed, a shoreline, or a lake, among others. Summary

[0004] In an implementation described herein, a method is provided for determining a depositional environment of a sample of a subterranean environment. The method includes measuring intensities for a crystallographic plane (CP) 100 peak and a CP 101 peak for quartz in a diffractogram, calculating a ratio of the intensities of the CP 100 peak to the CP 101 peak, and identifying a depositional environment for the sample from the ratio.

[0005] In another implementation described herein, a method is provided for determining a placement of a well in a reservoir. The method includes obtaining a sample of rock from a facies in a wellbore, grinding the sample to form a powder, and mounting the powder in a sample holder and inserting the sample holder in an x-ray diffraction instrument. An intensity is determined of a peak for a crystallographic plane (CP) 100 of quartz in the sample. An intensity is determined of the peak for a CP 101 of quartz in the sample. A ratio of the intensities for the CP 100 peak and the CP 101 peak is calculated. The ratio is compared to a correlation between ratios and depositional environments. The depositional environment for the sample is identified. The placement of the wellbore in the reservoir is determined, based, at least in part, on the depositional environment.

Brief Description of Drawings [0006] Figure 1 is a schematic drawing of a method for drilling a well to a reservoir layer in a subterranean environment.

[0007] Figure 2 is a drawing of different layers of material in a subterranean environment.

[0008] Figure 3 is a drawing of the depositional environment that may be used to form a single layer found in the subterranean environment, described with respect to Fig. 2.

[0009] Figures 4A and 4B are process flow diagrams of a method 400 for determining a depositional environment from the intensity ratio of the CP 100 and 101 scattering peaks for quartz. [0010] Figure 5 is a diffractogram of CP 100 peaks of quartz samples from different depositional environments.

[0011] Figure 6 is a diffractogram of CP 101 peaks of the quartz samples from different depositional environments described with respect to Fig. 5.

[0012] Figure 7 is a diffractogram showing the intensity levels of other crystallographic planes of quartz for the samples of Fig. 5.

[0013] Figure 8 is a diffractogram showing the intensity levels of other crystallographic planes of quartz for the samples of Fig. 5.

Detailed Description

[0014] Techniques are provided herein for determining depositional environments using ratios of the relative X-ray diffraction peak intensities from the 100 and 101 crystallographic planes (CP) of quartz. As described herein, the techniques are able to distinguish between the depositional environments of the Unayzah (Permo- Carboniferous). This provides a simpler method than petrography for screening samples, such as rock samples from subterranean facies, to determine depositional environments.

[0015] The CP 100 and CP 101 are used because they represent the strongest diffraction peaks associated with quartz. The CP 100/101 ratio may be useful for this determination as the quartz median grain diameters are related to the energy and provenance of the depositional environment, and quartz is the dominant mineral composing the matrices of these rocks. Powder X-ray diffraction results indicate the matrices consist mainly of quartz (96%), with minor components including potassium feldspar (microcline) and plagioclase (albite), dolomite, anhydrite, halite and hematite (2%). Clay minerals may also be present in minor amounts, and include illite, mixed layer illite/smectite (I/S), kaolinite, and chlorite (2%). Because peak intensities are utilized, care has been exercised toward ensuring the baselines of the diffraction patterns have not been influenced by these minor mineral constituents.

[0016] Further, the sample preparation procedures have been selected to minimize preferred orientation. To evaluate potential preferred orientation, other quartz peak intensities of 112 and 211 compared to that 100 and 101 have also been evaluated. In general, the grinding and packing process of a powdered sample into the sample holder may result in a preferred orientation in some cases, which is seen in higher order diffractions. This effect is related to the broadening of the peak due to weakening of the crystal lattice, termed microstrain. During grinding, microstrain may be created in the crystals. Thereby, decreasing the peak intensities and broadening the area of the quartz diffraction peaks. Accordingly, a micronizer used for XRD samples should be utilized. If a different grinding technique is used between the samples, differences in microstrain may make the analysis of the ratios problematic. Checking the intensities at a higher angle from the diffraction pattern to see if these differ, mainly those from the 112 and 211 crystallographic planes, can be used to determine if some of the intensities recorded could be the result of preferred orientation due to sample preparation.

[0017] Figure 1 is a schematic drawing of a method 100 for drilling a well to a reservoir layer in a subterranean environment. In the method 100, a drilling rig 102 at the surface 104 is used to drill a wellbore 106 to the reservoir layer 108. In this illustration, the reservoir layer 108 is bounded by an upper layer 110, such as a layer of cap rock, and a lower layer 112, such as a layer containing water.

[0018] As used herein, a facies is a body of rock that has related characteristics, such as a single type of sedimentary sandstone, a single type of sedimentary shale, and the like. Further, the depositional environment of the body of rock, as discussed further with respect to Fig. 3, may provide the related characteristics that define a facies. Certain types of facies are more likely to be associated with the presence of hydrocarbons, such as sandstone, and other porous rock. Porous rock layers allow hydrocarbons to migrate to traps, for example, forming reservoirs below an impervious layer of rock, such as the upper layer 110, in this example. In other examples, facies with a high porosity, but a low permeability, may trap hydrocarbons in the pores, forming a tight reservoir.

[0019] The reservoir layer 108 is unlikely to have a uniform distribution of hydrocarbons. For example, one facies 114 in the reservoir layer 108 may have substantially higher amounts of hydrocarbons than another facies 116 in the reservoir layer 108. Accordingly, the determination of the depositional environment of the facies 114 and 116 present in the reservoir layer 108 and in the layers around the reservoir layer 108, such as the upper layer 110 and the lower layer 112, may help in locating facies with higher hydrocarbon content, termed reservoirs, and in determining the placement of the wellbore 106 in the reservoir layers and the reservoirs to improve hydrocarbon production. [0020] The determination of the depositional environments of the facies in the layers of the subterranean environment may be combined with other types of information used for the identification of reservoir layers and the location of reservoirs within these layers. For example, seismic data collected from seismic analyses can indicate the likely presence of reservoirs, while the depositional environments of the facies may provide further information on locations of reservoirs in a reservoir layer. Accordingly, seismic data may be used along with the data on depositional environments to geosteer a well in a reservoir. Further, a seismic analyses may be performed to determine a location for drilling an exploratory well for collecting core samples, as described further with respect to Fig. 2. [0021] Figure 2 is a drawing of different layers of material in a subterranean environment 200. Like numbered items are as described with respect to Fig. 1. In Fig. 2, a drilling rig 202 is used to drill an exploratory well 204 into the subterranean environment 200. Cuttings and core samples may be taken from the exploratory well 204 to determine the characteristics of layers in the subterranean environment 200, such as layers 110, 112, 206, 208, and 210. It may be noted that for simplicity’s sake, the layers are shown as discrete surfaces within the subterranean environment 200. However, it should be clear that each of the layers shown often represents a continuum of material from layers above and layers below, although some, such as the upper layer 110 may be a discrete surface, for example, a cap rock.

[0022] The cuhings and core samples removed from the exploratory well 204 may be used in a petrography analysis to determine the depositional environment of the various facies, such as facies 212, 214, and 216 shown for the layer 210, or facies 114 and 116 in the reservoir layer 108. Actually, hundreds of cubing and core samples are received used to determine depositional models, for example, by means of performing thin section (TS) slides. However, TS slide processing may take hours to days to perform. Accordingly, the techniques described herein can be used as an initial analysis to determine the depositional model for the facies of the subject samples. This method is based on diffractograms (plots of XRD measurements) which may be produced in a short period of time. The peak intensities of crystallographic planes for quartz can be quickly computed from the diffractograms.

[0023] Figure 3 is a drawing of the depositional environment 300 that may be used to form a single layer found in the subterranean environment, described with respect to Fig. 2. Higher energy environments often result in smaller particle size, which correlates to a change in the ratio of the CP 100/101 intensities for quartz. The highest energy environment in the sample studied was a shoreline environment 302 of a lake 304, wherein wave action may contribute to smaller particle size material. The shoreline environment 302 gives rise to deposits of shoreline lake facies in layers in the subterranean environment.

[0024] The next highest energy environment in the depositional environment 300 is the riparian, or fluvial environment 306. The fluvial environment 306 provides significant energy to particulates from water flowing through the riverbed, which results in the reduction of particle size. The fluvial environment 306 gives rise to deposits of fluvial facies in layers in the subterranean environment.

[0025] The next highest energy environment in the depositional environment 300 is the coastal dunes environment 308. The coastal dunes environment 308 has less wave action than the shoreline environment 302, but may have substantial winds coming off the lake 304. These winds may result in smaller particle sizes from abrasion.

[0026] The lowest energy environment in the depositional environment 300 of Fig. 3 is the inland dunes, or dunes environment 310. The dunes environment 310 is generally not subjected to forces from the river flow in the fluvial environment 306, the wave action in the shoreline environment 302, or the higher winds of the coastal dunes environment 308. Accordingly, the particle sizes in the dunes facies may be larger than in the other environments. [0027] As described herein, the results indicate the CP 100/101 ratio changes according to the depositional environments, for example, as determined by petrography. In order of the increasing energy of the depositional environment, the shoreline lake facies has aratio of between about 0.14 and about 0.16, or about 0.15, the fluvial facies has a ratio of between about 0.22 and about 0.24, or about 0.23, the coastal dune facies has a ratio of between about 0.26 and about 0.31, or about 0.28, and the dune facies has a ratio of between about 0.30 and about 0.39, between about 0.39 and about 0.55, about 0.34, about 0.41, or about 0.47.

[0028] Figures 4A and 4B are process flow diagram of a method 400 for determining a depositional environment from the intensity ratio of the CP 100 and 101 scattering peaks for quartz. The method begins at block 402, when a sample the analysis is obtained. The sample may be a thin slice cut from a core taken from an exploratory well, or may be a cuttings sample taken from a drilling operation. In an example, the sample was taken from the same material used for petrographical analysis, allowing calibration to be performed with the same samples. [0029] At block 404, the sample was prepared by grinding using a micronizing mill. In a micronizing mill, the crystal lattice is preserved during the grinding process. [0030] At block 406, the powder is mounted in an x-ray diffraction sample holder. The powder amount was prepared by tamping the loose powder in the slide cavity of the x-ray diffraction sample holder with a razor blade having a sharp edge, in order to minimize preferred orientation.

[0031] The same preparation technique of milling and slide preparation, e.g., packing of the sample holder, was used for all samples. For example, the same milling time was used for all samples. This was performed to prevent differences that could be related to the broadening of peaks due to weakening of the crystal latice by micro strain.

[0032] At block 408, the sample holder is inserted in the XRD instrument and a diffractogram is generated. From the diffractogram, the intensities of the CP 100 and CP 101 peaks for quartz are measured. The analysis, the [0033] At block 410, the ratio of the CP 100/101 intensity peaks is calculated. The relative intensities utilized are based on the peak heights to compute the ratio to determine depositional environments.

[0034] At block 412, the ratio of the CP 100/101 intensity peaks is compared to a calibration determined from petrographic analysis of the depositional environments.

As discussed further with respect to Fig. 3, the use of the CP 100/101 intensity ratio to determine depositional environments is based on an assumption that the quartz median grain diameters are related to the energy and provenance of the depositional environment, and that quartz is the dominant mineral composing the matrices of these rocks. The ratio is based on the strongest diffraction peaks associated with quartz. Because peak intensities are utilized, care has been exercised toward ensuring the baselines of the diffraction patterns have not been influenced by the minor mineral constituents and sample preparation. Also, to further evaluate potential preferred orientation, other quartz peak intensities for CP 112 and CP 211 compared to that of CP 100 and CP 101 have also been evaluated. The measurements of the ratios of these peaks may allow for a determination of the effects of sample preparation.

[0035] Thin section slides are generally used to determine relative geological description and facies/depositional models in petrography. The subject samples utilized in the techniques described herein were also used in petrography to separately identify the depositional models, along with detailed core description in a sedimentological workflow. The petrography performed on these samples was correlated with the grain size and facies. X-Ray Diffraction was used on the same samples as a separate technique to determine the mineralogical composition of the samples. The XRD patterns providing with crystallographic planes of minerals was used to measure the peak intensities in order to calculate the intensity ratios of the CP 100 and CP 101 peaks of quartz.

[0036] In this present work, the depositional environments were identified separately using petrography by means of thin sections along with detailed core description in a sedimentological workflow. X-Ray Diffraction was used on the same samples as a separate technique to determine the mineralogical composition of the samples. The integration of all tools resulted to describe these depositional environments using the relative intensities of the crystallographic planes. Petrography performed on these samples to correlate to the claims made concerning grain size and depositional environment.

[0037] At block 414, the depositional environment for the sample is determined from the comparison to the calibration. Results indicate that the ratio of the intensities of the CP 100/101 peaks are changing according to the depositional environments determined by petrography. This is shown further in the results of Table 2. Two different intervals were run for the dune facies. The results for both intervals were similar, and higher than other depositional environments.

[0038] Table 2: determination of ratios for peak intensities of CP 100 and CP 101 compared to depositional environments.

[0039] The ability of the technique to discern between different depositional environments is described further with respect to the plots of Figs. 5-10. These plots are diffractograms of powder samples, formed using the sample preparation techniques described with respect to Figs. 4A-4B. The milling time was performed in a micronizing mill for about 5 minutes for each sample. A micronizing mill that may be used in the present techniques is the XRT Mill McCrone, available from the McCrone Group, Inc., of Westmont, IL. The x-ray diffraction was run on Rikagu ULTIMA IV powder X-Ray diffractometer, available from the Rigaku Corporation of Tokyo, Japan. The source was a CuKa emitter (40 kV, 40 mA). The diffraction interval was 3°-70° (2Q), with a step size increment of 0.02°.

[0040] Figure 4B is a simplified process flow diagram of the method 400. Like numbered items are as described with respect to Fig. 4A. [0041] Figure 5 is a diffractogram 500 of CP 100 peaks 502 of quartz samples from different depositional environments. In the diffractogram 500, the x-axis 504 is the position of the x-ray head in degrees 2-theta, and the y-axis 506 is the intensity of the emission in counts per second.

[0042] In the diffractogram 500, samples from four depositional environments, C- 1: coastal dune, C-4: dune, C-3 and C-5:fluvial, were run. As can be seen from the diffractograms 500, strong differences in intensity levels of the CP 100 peaks 502 for samples from the different depositional environments. This indicates that the intensity levels may be used to identify the depositional environments. Further runs, not shown, were performed to complete the correlation. [0043] Figure 6 is a diffractogram 600 of CP 101 peaks 602 of the quartz samples from different depositional environments described with respect to Fig. 5. Like numbered items are as described with respect to Fig. 5. As for the CP 100 peaks 502 shown in Fig. 5, the CP 101 peaks 602 of the quartz samples show strong differences in intensity levels. Accordingly, the intensity level for each of the depositional environments, shown as the CP 100 peaks 502 of Fig. 5, was ratioed with the corresponding intensity level for the CP 101 peaks 602 of Fig. 6.

[0044] Figure 7 is a diffractogram 700 showing the intensity levels of other crystallographic planes of quartz for the samples of Fig. 5. These crystallographic planes include the CP 112 (d=1.81A) peaks 702, CP 211 (d=1.54) peaks 704, and CP 022 (d=1.76) peaks 706.

[0045] The CP 112 peaks 702, CP 211 peaks 704, and CP 022 peaks 706 show similar intensity levels. This indicates that intensity at higher angles from the diffraction pattern are not affected by sample preparation.

[0046] Figure 8 is a diffractogram 800 showing an expanded view of the peaks of Fig. 7. Like numbered items are as described with respect to Fig. 7. As can be seen in Fig. 8, the expanded view confirms that the intensity levels of these peaks show similar intensities. [0047] As the techniques for determining the depositional environment using the ratio of the intensities of the CP 100 and CP 101 peaks of quartz x-ray are faster than the petrography techniques using thin slices, the number of samples that can be analyzed is substantially increased. For example, the number of samples that can be analyzed by petrography per day, may be about 6 to 10 samples per day. By comparison, the XRD analysis may be performed on 24 to 48 samples per day. Thus, the speed of sample analysis may be improved by at least a factor of 3 the operations in case of urgent exploration procedures.

[0048] In an implementation described herein, a method is provided for determining a depositional environment of a sample of a subterranean environment. The method includes measuring intensities for a crystallographic plane (CP) 100 peak and a CP 101 peak for quartz in a diffractogram, calculating a ratio of the intensities of the CP 100 peak to the CP 101 peak, and identifying a depositional environment for the sample from the ratio. [0049] In an implementation, the method includes obtaining the sample from a core sample. In an implementation, the method includes obtaining the sample from cuttings from the drilling process. In an implementation, the method includes micronizing the sample and loading the sample in an x-ray diffraction sample holder. [0050] In an implementation, the method includes comparing peak intensities for other crystallographic planes to measure effects of sample preparation. In an implementation, the method includes comparing peak intensities for CP 112 peaks for samples from different depositional environments to measure effects of sample preparation. In an implementation, the method includes comparing peak intensities for CP 211 peaks for samples from different depositional environments to measure effects of sample preparation.

[0051] In an implementation, the method includes correlating intensity ratios to depositional environment by determining the depositional environment for each of a plurality of sample, and measuring the intensity for the CP 100 peak and the CP 101 peak for each of the plurality of samples. The ratio of the intensity of the CP 100 peak to the CP 101 peak for each of the plurality of samples is calculated. The intensity ratio for each of the plurality of samples is correlated to the depositional environment.

[0052] In an implementation, the depositional environment for each of the plurality of samples is determined through a petrographic analysis. In an implementation, a plurality of samples obtained from cuttings generated during a well drilling is screened for depositional environment.

[0053] In an implementation, a reservoir layer is identified based, at least in part, on the depositional environment of the sample. In an implementation, a reservoir is located based, at least in part, on the depositional environment of the sample. In an implementation, a wellbore is drilled to a reservoir based, at least in part, on the depositional environment of the sample.

[0054] In an implementation, the method includes performing a seismic analyses of a potential location for a reservoir. In an implementation, data from the seismic analyses is used to locate a site for drilling an exploratory well to collect core samples. [0055] In another implementation described herein, a method is provided for determining a placement of a well in a reservoir. The method includes obtaining a sample of rock from a facies in a wellbore, grinding the sample to form a powder, and mounting the powder in a sample holder and inserting the sample holder in an x-ray diffraction instrument. An intensity is determined of a peak for a crystallographic plane (CP) 100 of quartz in the sample. An intensity is determined of the peak for a CP 101 of quartz in the sample. A ratio of the intensities for the CP 100 peak and the CP 101 peak is calculated. The ratio is compared to a correlation between ratios and depositional environments. The depositional environment for the sample is identified. The placement of the wellbore in the reservoir is determined, based, at least in part, on the depositional environment.

[0056] In an implementation, the method includes drilling an exploratory well to obtain core samples of rock in a subterranean environment. In an implementation, the method includes obtaining the sample of rock from the core sample. In an implementation, the method includes obtaining the sample of rock from cuttings from drilling a wellbore.

[0057] In an implementation, the method includes correlating intensity ratios to depositional environment by determining the depositional environment for each of a plurality of samples. The intensity for the CP 100 peak in the CP 101 peak for each of the plurality of samples is determined. The ratio of the intensity of the CP 100 peak to the CP 101 peak is calculated for each of the plurality of samples. The intensity ratio for each of the plurality of samples is correlated to the depositional environment. [0058] In an implementation, the method includes collecting seismic data on a potential reservoir site and determining the placement of the wellbore in the reservoir based, at least in part, on the seismic data.

[0059] Other implementations are also within the scope of the following claims.