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Title:
DISPERSION OF EXFOLIATED PARTICLES OF LAYERED POLYSILICATE COMPOUND, AND METHOD FOR PRODUCING SAME
Document Type and Number:
WIPO Patent Application WO/2022/181628
Kind Code:
A1
Abstract:
[Problem] To provide a dispersion of exfoliated particles in which a layered polysilicate compound is interlayer-exfoliated. [Solution] Provided are: a dispersion of exfoliated particles which includes at least one nitrogen-containing basic compound (A) which is a tertiary amine or a quaternary ammonium hydroxide having at least one alkyl group having 3 or 4 carbon atoms, and in which exfoliated particles (C) produced by interlayer-exfoliating a proton-type layered polysilicate compound (B) are dispersed in an aqueous solution (D) having 10 vol% to 90 vol% of an alcohol having 1 to 3 carbon atoms; and a film-forming composition , a porous body-forming composition , an LB film, a coating film, a self-supporting film, a proton conductor, an electrolyte membrane for fuel cells, and a porous body each containing exfoliated particles.

Inventors:
IDA SHINTARO (JP)
AWAYA KEISUKE (JP)
SEKIGUCHI KAZUTOSHI (JP)
KITAGAWA HIROTAKE (JP)
YAMADA SHUHEI (JP)
Application Number:
PCT/JP2022/007351
Publication Date:
September 01, 2022
Filing Date:
February 22, 2022
Export Citation:
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Assignee:
UNIV KUMAMOTO NAT UNIV CORP (JP)
NISSAN CHEMICAL CORP (JP)
International Classes:
C01B33/38; H01B1/06; H01M8/10; H01M8/1016
Domestic Patent References:
WO2020153352A12020-07-30
WO2014061606A12014-04-24
Foreign References:
KR101516675B12015-05-06
JPH04367508A1992-12-18
JP2010027605A2010-02-04
Other References:
TAKAHASHI NOBUYUKI, HATA HIDEO, KURODA KAZUYUKI: "Exfoliation of Layered Silicates through Immobilization of Imidazolium Groups", CHEMISTRY OF MATERIALS, AMERICAN CHEMICAL SOCIETY, US, vol. 23, no. 2, 25 January 2011 (2011-01-25), US , pages 266 - 273, XP055788136, ISSN: 0897-4756, DOI: 10.1021/cm102942s
OSADA SHIMON, AOI IRIBE, KAZUYUKI KURODA: "Exfoliation of Layered Octosilicate by Simple Cation Exchange with Didecyldimethylammonium Ions", CHEMISTRY LETTERS, vol. 42, no. 1, 29 December 2012 (2012-12-29), pages 80 - 82, XP055961641, DOI: 10.1246/cl.2013.80
NARKHEDE VAISHALI V., GIES HERMANN: "Crystal Structure of MCM-22 (MWW) and Its Delaminated Zeolite ITQ-2 from High-Resolution Powder X-Ray Diffraction Data: An Analysis Using Rietveld Technique and Atomic Pair Distribution Function", CHEMISTRY OF MATERIALS, AMERICAN CHEMICAL SOCIETY, US, vol. 21, no. 18, 22 September 2009 (2009-09-22), US , pages 4339 - 4346, XP055961643, ISSN: 0897-4756, DOI: 10.1021/cm901883e
G. BORBELYH. K. BEYER: "Chemical Characterization, Structural features, and thermal behavior of sodium and hydrogen a octosilicate", CLAYS AND CLAY MINERALS, vol. 39, no. 5, 1991, pages 490 - 497
TOMOHIRO IWASAKI ET AL.: "Seeding effect on crystal growth in hydrothermal synthesis of layered octosilicate", CHEMICAL ENGINEERING COMMUNICATIONS, vol. 193, 2006, pages 69 - 76
HARUTO MURAISHI: "Variations of Surface Property and Interplanar Spacing of Kenyaite and Magadiite with Ion Exchange and Heating", JOURNAL OF THE CLAY SCIENCE SOCIETY OF JAPAN, vol. 36, no. 1, 1996, pages 22 - 34
NOBUYUKI TAKAHASHI ET AL.: "Exfoliation of layered silicates through immobilization of imidazolium groups", CHEMISTRY OF MATERIALS, vol. 23, no. 2, 2011, pages 266 - 273, XP055788136, DOI: 10.1021/cm102942s
SHIMON OSADA ET AL.: "Exfoliation of Layered Octosilicate by Simple Cation Exchange with Didecyldimethylammonium Ions", CHEMISTRY LETTERS, vol. 42, 2013, pages 80 - 82, XP055961641, DOI: 10.1246/cl.2013.80
Attorney, Agent or Firm:
HANABUSA PATENT & TRADEMARK OFFICE (JP)
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