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Title:
ELECTROLYTE SOLUTION FOR ALKALI METAL-SULFUR-BASED SECONDARY BATTERY, AND ALKALI METAL-SULFUR-BASED SECONDARY BATTERY
Document Type and Number:
WIPO Patent Application WO/2018/163778
Kind Code:
A1
Abstract:
Provided are the following: an electrolyte solution for an alkali metal-sulfur-based secondary battery, which does not require addition of lithium polysulfide, exhibits excellent cycle performance, and has low resistance during charging and discharging; and an alkali metal-sulfur-based secondary battery. This electrolyte solution for an alkali metal-sulfur-based secondary battery is provided with a positive electrode that includes a composite carbon material that contains a carbon material and a sulfur-containing positive electrode active substance. The electrolyte solution is characterized in that the carbon material has a pore volume ratio (micropore/mesopore) of 1.5 or more, and in containing a fluorinated ether represented by formula (1): R11-(OR12)n11-O-R13. (In the formula, R11 and R13 may be the same as, or different from, each other, and each denote an alkyl group that may have a fluorine atom, but at least one of R11 and R13 has a fluorine atom. R12 is an alkylene group that may have a fluorine atom. n11 is 0, 1 or 2.)

Inventors:
ISHIKAWA MASASHI (JP)
TORII YUYA (JP)
UCHIDA SATOSHI (JP)
YAMAGATA MASAKI (JP)
YAMAZAKI SHIGEAKI (JP)
KINOSHITA SHINICHI (JP)
Application Number:
PCT/JP2018/005770
Publication Date:
September 13, 2018
Filing Date:
February 19, 2018
Export Citation:
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Assignee:
THE SCHOOL CORPORATION KANSAI UNIV (JP)
DAIKIN IND LTD (JP)
International Classes:
H01M10/0569; H01M4/36; H01M4/38; H01M10/052
Domestic Patent References:
WO2008096729A12008-08-14
WO2016075916A12016-05-19
WO2015166636A12015-11-05
Foreign References:
JP2016100094A2016-05-30
JP2008218387A2008-09-18
JP2012178339A2012-09-13
JP2016115417A2016-06-23
JP2010095390A2010-04-30
JP2010095390A2010-04-30
JPS584557B21983-01-26
JP2005108724A2005-04-21
JP2013225497A2013-10-31
Other References:
See also references of EP 3609013A4
Attorney, Agent or Firm:
YASUTOMI & ASSOCIATES (JP)
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