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Title:
FABRIC WHITENER
Document Type and Number:
WIPO Patent Application WO/2004/096966
Kind Code:
A1
Abstract:
A composition for the whitening of domestic fabrics which include a nylon and/or lycra component, said composition comprising thiourea dioxide and an alkali.

Inventors:
TOMS DAVID (GB)
Application Number:
PCT/GB2004/000322
Publication Date:
November 11, 2004
Filing Date:
January 27, 2004
Export Citation:
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Assignee:
DYLON INTERNAT LTD (GB)
TOMS DAVID (GB)
International Classes:
D06L4/30; (IPC1-7): C11D7/34; C11D3/34; D06L3/10
Foreign References:
EP0615018A11994-09-14
DE3831098A11990-03-22
EP0050015A21982-04-21
US5749923A1998-05-12
US5711764A1998-01-27
GB1410677A1975-10-22
DE2242380B11974-03-07
EP0175272A21986-03-26
Attorney, Agent or Firm:
Copsey, Timothy Graham (20 Red Lion Street, London WC1R 4PJ, GB)
Download PDF:
Claims:
Claims
1. A composition for the whitening of domestic fabrics which include a nylon and/or lycra component, said composition comprising thiourea dioxide and an alkali.
2. A composition as claimed in claim 1, in which the thiourea dioxide is present at a concentration of at least 2.5% o. w. f.
3. A composition as claimed in claim 2, in which the thiourea dioxide is present at a concentration of between 2.5 and 10% o. w. f. , preferably 6 and 10% o. w. f.
4. A composition as claimed in any preceding claim, in which the pH is greater than 7.0.
5. A composition as claimed in claim 4, in which the pH is greater than 8.0 and preferably in the range 8.5 to 10.0.
6. A composition as claimed in any preceding claim, in which the composition is used at an initial temperature of greater than 40°C.
7. A composition as claimed in claim 6, in which the initial temperature is in the range 5065°C, preferably 60°C.
8. A composition as claimed in any preceding claim, in which the composition further comprises a dye scavenger component.
9. A composition as claimed in claim 8, in which the dye scavenger component is selected from polyvinylpyrrolidone and poly (4 vinylpyridinium Noxide).
10. A composition as claimed in claim 9, in which the dye scavenger component is poly (4vinylpyridinium Noxide).
11. A composition as claimed in claim 10, in which the poly (4 vinylpylidinium Noxide) is present at a concentration of greater than 0.2% o. w. f. , preferably about 0.4% o. w. f.
12. A method of treatment to remove discoloration from domestic white fabric articles which include a nylon and/or lycra component, in which the fabric article is treated with a composition as claimed in any preceding claim.
13. A method of treatment as claimed in claim 12, in which the treatment comprises the steps of soaking the article in a solution of the composition as claimed in any one of claims 1 to 11, followed by a water rinse and a conventional washing cycle.
Description:
Fabric Whitener The present invention relates to a product for whitening fabric articles which have become discoloured, in particular lingerie or underwear fabric items made from or containing nylon which have become discoloured due to colour runs or a build up of dye during repeated washing.

It is known that white fabric items, in particular lingerie, become discoloured with time on repeated washing taking on a grey or dirty blue tinge, which is regarded by the consumer as being dirty. It has been found by our research that this discoloration is due in a large part to a very slow colour run from coloured articles washed at the same time and which contain non-fast dye. Often when sorting their washing into coloured and white wash loads, consumers include light blue items and mainly white items (but with a little colour) in the white wash load.

Previously it was thought that most of the discoloration on the white fabrics was a result of dirt becoming entrained in the white fabric. However, our research shows that a small amount of loose dye is released from the coloured article in each wash and transfers to the white article. The colour thus builds up on repeated washing with coloured articles. This is difficult to remove, especially if the white article and the dye have a strong affinity for each other.

Discoloration occurs on most fabrics, but is particularly a problem on nylon and lycra (which each have a strong affinity for non-fast dyes) and to a lesser extent cotton and polyester. There are no products available which will restore this lost whiteness to articles containing nylon and/or lycra which have started to discolour. White lingerie is largely made up from a combination of these materials and is therefore prone to this form of discoloration over time, turning a

blue or grey colour. In some cases this can occur very quickly if the light washing load generally includes a large amount of non-fast dye, in particular from blue articles, in the machine.

Some products on the market attempt to prevent non-fast dye from discolouring light or white items in the first place using bleaches or dye scavengers. The object of these products is to pick up any loose dye in the wash before it becomes attached to the white item. Alternatively, they may effectively bleach the non-fast dye while it is loose in the water so that it loses its colour before it attaches itself to a light item. These dye scavenger products do not treat items which have previously become discoloured.

There are products on the market designed to remove colour runs, but these products are only effective on certain fabric types; they are not effective on nylon and lycra which are major constituents of lingerie and underwear. It is also not readily understood by the consumer that the grey discoloration is from a run of coloured dye because this builds up slowly over time.

Industrially, dye removal is operated under very severe conditions. Reducing agents are used at boiling point, usually with caustic soda, to bleach the fabric to remove the colour. Very occasionally, chlorine bleach may be used to strip out dye but this may damage the structure of the fabric material permanently and can subsequently cause white fabric to have a yellow or orange hue. This discoloration can not be treated as the chemical structure of the fabric has been altered.

Dilute chlorine bleach solutions can also be used domestically to treat light or white items, but again this can irreparably damage the chemical structure of the fabric.

The present invention seeks to overcome the problems of the prior art. A first object is to provide a product which restores the whiteness in discoloured nylon and/or lycra fabrics in a domestic environment.

According to the present invention, there is provided a composition for the whitening of domestic fabrics which include a nylon and/or lycra component, said composition comprising thiourea dioxide (formamidesulphinic acid) and an alkali. The invention is particularly suitable for use in whitening nylon and lycra which are perceived as being difficult to treat using conventional materials.

Amongst domestic garments which can be treated using the compositions of the present invention are lingerie and underwear items which usually comprise a nylon element.

The thiourea dioxide operates as a reducing agent and is preferably present at a concentration of at least 2.5% on weight of fabric, more preferably 2.5 to 10% and most preferably 6 to 10%. Surprisingly, thiourea dioxide has been shown to give substantially superior results when compared to other reducing agents such as sodium hydrosulphite and sodium formaldhydesulphoxylate even when much higher concentrations of these other materials are used.

Preferably, the alkali is present in an amount to give a pH greater than 7.0, more preferably greater than 8.0 and most preferably in the range 8. 5-10. 0.

Preferably, the treatment is carried out at a temperature of greater than 40°C, more preferably in the range 50 to 65°C, and most preferably at approximately 60°C.

Optionally, the composition further comprises a dye scavenger component. These compounds are often referred to as dye transfer inhibitors (DTI) and pick up loose or non-fast dye in the solution to prevent most or all of the loose dye from becoming attached to the light fabrics at all. These compounds do not generally remove dye which has previously become permanently attached to the fabrics. Preferably the dye scavenger is selected from the list of polyvinylpyrrolidone and poly (4-vinylpyridinium N-oxide), most preferably poly (4-vinylpyridinium N- oxide). Preferably this is present at a concentration of greater than 0.2% on weight of fabric, more preferably at a concentration of approximately 0.4%.

The invention also extends to a method of treatment to remove discoloration from domestic white fabric articles which include a nylon and/or lycra component, in which the fabric article is treated with a composition including thiourea dioxide and an alkali. A preferred treatment method comprises the steps of soaking the article in a solution of the composition of the present invention, followed by a water rinse and a conventional washing cycle. Other preferred features of the composition set out above apply equally to the method of the invention.

The present invention may be put into practice in a number of different ways and various embodiments will described here in further detail by way of non- limiting example.

Samples of white nylon were stained with various different colour dyes by soaking them in a solution of the dye. In all instances 0.05g dye per kg of nylon were dissolved in water and the fabric was treated with this solution at 60°C in a washing machine cycle, and then spun and dried at ambient temperature to stain the fabric. Once treated, the discoloured samples were measured for "whiteness"using a Datamaster V. 2.3 spectrophotometer. These results are in

the form of delta E (AE), or colour strength, and original white fabric produces a reading of 0.00. The lower the AE value, the whiter the fabric.

C. I. Direct Red 81 was the primary dye used, as it was easier to see the visual effects of the treatments with a red dye than with a blue dye. However, tests were also conducted using C. I. Direct Blue 251 and C. I. Direct Yellow 27.

The dyed samples were treated with a variety of products under the conditions set out below. The conditions were the same for all examples unless otherwise indicated.

250g of stained fabric was treated in 7.5 litres of water which included the indicated amount of the active component and with an initial pH of 9.9 unless otherwise indicated to the contrary. The water was initially at 60°C and the treatment lasted 30 minutes with the solution being stirred initially and then occasionally over the 30 minutes. There was no external heating of the solution over the 30 minutes so the solution cooled during the treatment. After removal from the treatment solution the fabric sample was rinsed under cold tap water and then washed in a normal washing cycle at 40°C using a standard detergent.

In the following tables, "o. w. f." is an abbreviation for"on weight of fabric" Example 1 Effect of concentration of thiourea dioxide at a pH of 9.9.

Samples were treated with different concentrations of thiourea dioxide as the active component and the results are given in table 1 below. Treatment A E Stained, untreated 16. 05 Thiourea dioxide 10% o. w. f 6.44 Thiourea dioxide 5% o. w. f 6. 11 Thiourea dioxide 2.5% o. w. f 6.91 Thiourea dioxide 1.25% o. w. f 11.66 Thiourea dioxide 0. 63% o. w. f 13. 18

Table 1 From these results it can be seen that a minimum of 2.5% o. w. f thiourea dioxide is desirable to obtain significant whitening of the nylon. It can also be seen that increasing the concentration of the thiourea dioxide further does not significantly increase performance.

Example 2 Effect of pH on thiourea dioxide.

Samples were treated with thiourea dioxide at a concentration of 10% o. w. f. at different pH by altering the concentration of alkali present in the solution. The results are given in table 2 below. pH AE Stained, untreated 16. 05 pH 9. 9 6. 44 pH 9. 0 5. 21 pH 8. 0 8. 98 pH 7. 0 8. 77 pH 5. 0 11. 34 Table 2 From these results it can be seen that the treatment is more effective under alkaline conditions, and in particular at a pH around 9.0.

Example 3 Effect of temperature Samples were treated with thiourea dioxide (10% o. w. f. ) at a range of temperatures and the results are given in table 3 below. Temperature A E Stained, untreated 16. 05 40°C 12. 99 50°C 8. 07 60°C 6. 44 80°C 0. 95 95°C 0. 35 Table 3 From these results it can be seen that a treatment temperature of at least around 50°C is required to achieve significant whitening of the nylon. Treatment at higher temperatures produce even greater effects, but some care may be required if domestic treatment is to be carried out at these higher temperatures.

Comparative Example 1 Effect of concentration of sodium hydrosulphite.

The samples were treated with sodium hydrosulphite as active component in place of thiourea dioxide under the same conditions. The results are set out in table 4 below. Treatment A E Stained, untreated 16. 05 sodium hydrosulphite 20% o. w. f 7. 11 sodium hydrosulphite 10% o. w. f 7. 46 sodium hydrosulphite 5% o. w. f 10. 85 sodium hydrosulphite 2.5% o. w. f 11.96 sodium hydrosulphite 1.25% o. w. f 12.60

Table 4 From these results it can be seen that even at a concentration of 20% o. w. f. sodium hydrosulphite, the nylon is not as white as when treated with 2. 5% o. w. f. thiourea dioxide.

Comparative Example 2 Effect of poly (4-vinylpyridinium N-oxide) (a dye transfer inhibitor) as a whitener.

The samples were treated with poly (4-vinylpyridinium N-oxide) (hereinafter referred to as DTI) as active component in place of thiourea dioxide under the same conditions. The results are set out in table 5 below. Treatment A E Stained, untreated 16. 05 DTI 0.4% o. w. f 14. 40 DTI 0. 2% o. w. f 15. 18 DTI 0. 1% o. w. f 17. 48 DTI 0.05% o. w. f 20. 22 DTI 0.025% o. w. f 20. 17 Table 5 From these results it can be seen that DTI has little effect on its own as a whitener although at concentrations above 0.2% o. w. f. some mild whitening effect can be seen.

Example 4

Effect of combinations of thiourea dioxide and DTI at a pH of 9.9.

A composition including both thiourea dioxide and a dye transfer inhibitor (DTI) was tested under the conditions set out above, and the results are shown in table 6 below. Treatment A E Stained, untreated 16. 05 10% thiourea dioxide o. w. f/DTI 0. 4% o. w. f 4.60 5 % thiourea dioxide o. w. f/DTI 0. 2% o. w. f 5.70 2. 5% thiourea dioxide o. w. f/DTI 0. 1% o. w. f 7.50 1. 25% thiourea dioxide o. w. f/DTI 0. 05% o. w. f 8.29 0. 63% thiourea dioxide o. w. f/DTI 0. 025% o. w. f 12.49 Table 6 From these results it can be seen that there is a synergistic effect of the reducing agent (thiourea dioxide) and the dye transfer inhibitor which produces results which are unexpectedly significantly better than using either component alone. For example, comparing the AE value from Table 1 for 10% thiourea dioxide with that for 10% thiourea dioxide and 0.4% DTI from Table 6 it can be seen that the nylon is whiter after treatment with the combined composition (4.6 c. f. 6.44).

Comparative Example 3 Comparison with commercially available products A number of commercially available products for domestic cleaning and treatment which either claim to whiten fabric or to remove colour runs from the wash liquid thereby avoiding discoloration were tested and compared with a product according to the present invention. The samples were all treated by the same method set out above. The results are set out in table 7 below. Product treatment A E Stained, untreated 16. 05 Glo-Care Rescue Colour Run Remover. 5% o. w. f 10. 92 Glo-White Super whitener. 3.4% o. w. f/Ariel Essential 14% o. w. f 17.85 Vanish Tablets 8.8% o. w. f/Ariel Essential 14% o. w. f 15. 44 Ace Washbooster 30% o. w. f/Ariel Essential 14% o. w. f 19. 13 Ariel Essential 14% o. w. f 13. 88 Dylon Lingerie Whitener 10% o. w. f thiourea dioxide/0.4% o. w. f DTI 4.60

Table 7 It is clear that the commercially available products do not work effectively on nylon. Indeed, the most effective (Glo-Care Rescue) which is based on sodium hydrosulphite states that it is not suitable for use on nylon. The present invention whitens nylon (amongst other fabrics) as shown in the table above.

Example 5 Samples were discoloured with C. I. Direct Blue 251 instead of C. I. Direct Red 81 and the results of treatment with a variety of compositions are set out in table 8 below. Treatment A E Stained, untreated 7. 15 Effect of sodium hydrosulphite (20% o. w. f) 1.87 Effect of thiourea dioxide (10% o. w. f) 1.71 Effect of sodium hypochlorite (40% o. w. f. of 15% available chlorine) 14.55 Table 8 It will be apparent from these results that treatment with thiourea dioxide under alkaline conditions significantly whitens the nylon. Treatment with sodium hypochlorite (household chlorine bleach) removes the dye, but discolours the

nylon-hence the high colour strength. As indicated above, the use of chlorine also damages the underlying structure of the fabric.

Example 6 Samples were discoloured with C. I. Direct Yellow 27 instead of C. I. Direct Red 81 and the results of treatment with a variety of compositions are set out in table 9 below. Treatment #E Stained, untreated 13.87 Effect of sodium hydrosulphite (20% o.w.f) 13.86 Effect of thiourea dioxide (10% o.w.f) 11.25 Combination of thiourea dioxide / DTI (10% o.w.f / 0.4% o.w.f) 9.36 Table 9 Again, it will be apparent from the results that treatment with thiourea dioxide under alkaline conditions significantly whitens the nylon. It is also apparent that thiourea dioxide again produces a significantly better performance than sodium hydrosulphite even at half the concentration. Further, it can be seen that the addition of DTI to the thiourea dioxide produces an even greater effect than thiourea dioxide alone, highlighting the synergy between the components.

These examples are not limiting and it will be apparent to a person skilled in the art that the results from the experiments described above are not dependent upon the dye which discolours the white fabric. Therefore it is clear that the composition of the present invention is generally applicable to treatment in a domestic environment of white fabrics which include a nylon and/or lycra component.




 
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