JPWO2010116848 | Thermoplastic resin composition |
JP3672499 | POLYPROPYLENE RESIN COMPOSITION AND USE THEREOF |
GAHLEITNER MARKUS (AT)
BERNREITNER KLAUS (AT)
LESKINEN PAULI (FI)
GRESTENBERGER GEORG (AT)
LUMMERSTORFER THOMAS (AT)
WO2020220255A1 | 2020-11-05 | |||
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C L A I M S 1. Fiber reinforced composition (C), comprising a) 55.0 to 95.0 wt.-% of a heterophasic polypropylene composition (HECO), comprising i) a matrix being a propylene homo- or copolymer (PP) having an amount of 1,2 erythro regio-defects of at least 0.4 mol-% and a comonomer content equal or below 8.5 mol-%, and ii) an elastomeric ethylene copolymer (E) being dispersed in said matrix, b) 5.0 to 45.0 wt.-% of fibers (F), and c) optionally 0.1 to 5.0 wt.-% of an adhesion promoter (AP), based on the overall weight of the fiber reinforced composition (C), wherein the fiber reinforced composition (C) has a melt flow rate MFR2 (230 °C, 2.16 kg) determined according to ISO 1133 in the range of 1.0 to 60.0 g/10 min. 2. The fiber reinforced composition (C) according to claim 1, comprising a) 55.0 to 94.9 wt.-% of the heterophasic polypropylene composition (HECO), b) 5.0 to 45.0 wt.-% of the fibers (F), and c) optionally 0.1 to 5.0 wt.-% of the adhesion promoter (AP), based on the overall weight of the fiber reinforced composition (C). 3. Fiber reinforced composition (C) according to claim 1 or 2, wherein the heterophasic polypropylene composition (HECO) comprises i) 60.0 to 95.0 wt.-% of the matrix being the propylene homo- or copolymer (PP), and ii) 5.0 to 40.0 wt.-% of the elastomeric ethylene copolymer (E), based on the overall weight of the heterophasic copolymer (HECO). 4. Fiber reinforced composition (C) according to any one of the preceding claims, wherein the elastomeric ethylene copolymer (E) has an ethylene content in the range of 15.0 to 85.0 wt.-%, based on the overall weight of the elastomeric ethylene copolymer (E). 5. Fiber reinforced composition (C) according to any one of the preceding claims, wherein the heterophasic polypropylene composition (HECO) has a melting temperature Tm determined according to differential scanning calorimetry (DSC) in the range of 130 to 165 °C. 6. Fiber reinforced composition (C) according to any one of the preceding claims, wherein the heterophasic polypropylene composition (HECO) has an intrinsic viscosity (IV) measured according to ISO 1628/1 (at 135 °C in decalin) of the soluble fraction (SF) determined according to CRYSTEX QC in the range of 1.8 to 3.0 dl/g. 7. Fiber reinforced composition (C) according to any one of the preceding claims, wherein the fibers (F) are glass fibers (GF), preferably short glass fibers (SGF) having i) an average length of 2.0 to 10.0 mm, and/or ii) an average diameter of 5 to 20 µm. 8. Fiber reinforced composition (C) according to any one of the preceding claims, wherein the adhesion promoter (AP) is a polar modified polypropylene (PM-PP) being a propylene homo- or copolymer grafted with maleic anhydride having a melt flow rate MFR (230 °C, 2.16 kg) determined according to ISO 1133 of at least 20.0 g/10 min to 400 g/10 min. 9. Fiber reinforced composition (C) according to any one of the preceding claims, wherein i) the propylene homo- or copolymer (PP) is a propylene homopolymer (hPP), and ii) the elastomeric ethylene polymer (E) is a copolymer of ethylene and propylene. 10. Fiber reinforced composition (C) according to claim 9, wherein the propylene homopolymer (hPP) has a melting temperature Tm determined according to differential scanning calorimetry (DSC) in the range of 140 to 160 °C. 11. Fiber reinforced composition (C) according to any one of claims 9 and 10, wherein the heterophasic polypropylene composition (HECO) has a comonomer content in the range of 2.2 to 8.7 mol-%. 12. Fiber reinforced composition (C) according to any one of claims 9 to 11, wherein the heterophasic polypropylene composition (HECO) has a melt flow rate MFR2 (230 °C, 2.16 kg) determined according to ISO 1133 in the range of 20.0 to 100 g/10 min. 13. Fiber reinforced composition (C) according to any one of claims 9 to 12, wherein the heterophasic polypropylene composition (HECO) has i) a xylene cold soluble (XCS) content determined at 25 °C according ISO 16152 in the range of 5.0 to 35.0 wt.-%, based on the overall weight of the heterophasic polypropylene composition (HECO). 14. Fiber reinforced composition (C) according to any one of claims 9 to 13, wherein the heterophasic polypropylene composition (HECO) has an ethylene content of the xylene cold soluble (XCS) fraction in the range of 20.9 to 44.7 mol-%. 15. Fiber reinforced composition (C) according to any one of claims 9 to 14, wherein the heterophasic polypropylene composition (HECO) has a soluble fraction (SF) determined according to CRYSTEX QC in the range of 5.0 to 35.0 wt.-%, based on the overall weight of the heterophasic polypropylene composition (HECO). 16. Fiber reinforced composition (C) according to any one of claims 9 to 15, wherein the heterophasic polypropylene composition (HECO) has an ethylene content of the soluble fraction (SF) determined according to CRYSTEX QC in the range of 20.9 to 44.7 mol-%. 17. Fiber reinforced composition (C) according to any one of claims 9 to 16, having a tensile modulus determined according to ISO 527-1A in the range of 3000 to 6000 MPa. 18. Fiber reinforced composition (C) according to any one of claims 9 to 17, having an elongation at break determined according to ISO 527-2 of more than 3.0 %. 19. Fiber reinforced composition (C) according to any one of the preceding claims, further comprising up to 20.0 wt.-% of a low density polyethylene (LDPE) homo- or copolymer having a density determined according to ISO 1183-187 of more than 900 kg/m³ and comprising ethylene and optionally vinyl acetate. 20. Fiber reinforced composition (C) according to any one of the preceding claims, wherein the propylene homo- or copolymer (PP) is obtained in the presence of a solid catalyst system (SCS) comprising a metallocene complex, preferably having the formula (I) wherein each X independently is a sigma-donor ligand, L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR'2-, -R'2Ge-, wherein each R' is independently a hydrogen atom or a C1-C20-hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 of the periodic table or fluorine atoms, or optionally two R’ groups taken together can form a ring, each R1 are independently the same or can be different and are hydrogen, a linear or branched C1-C6-alkyl group, a C7-20-arylalkyl, C7-20-alkylaryl group or C6-20-aryl group or an OY group, wherein Y is a C1-10-hydrocarbyl group, and optionally two adjacent R1 groups can be part of a ring including the phenyl carbons to which they are bonded, each R2 independently are the same or can be different and are a CH2-R8 group, with R8 being H or linear or branched C1-6-alkyl group, C3-8-cycloalkyl group, C6-10- aryl group, R3 is a linear or branched C1-C6-alkyl group, C7-20-arylalkyl, C7-20-alkylaryl group or C6-C20-aryl group, R4 is a C(R9)3 group, with R9 being a linear or branched C1-C6-alkyl group, R5 is hydrogen or an aliphatic C1-C20-hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 of the periodic table; R6 is hydrogen or an aliphatic C1-C20-hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 of the periodic table; or R5 and R6 can be taken together to form a 5 membered saturated carbon ring which is optionally substituted by n groups R10, n being from 0 to 4; each R10 is same or different and may be a C1-C20-hydrocarbyl group, or a C1-C20- hydrocarbyl group optionally containing one or more heteroatoms belonging to groups 14-16 of the periodic table; R7 is H or a linear or branched C1-C6-alkyl group or an aryl or heteroaryl group having 6 to 20 carbon atoms optionally substituted by one to three groups R11, each R11 are independently the same or can be different and are hydrogen, a linear or branched C1-C6-alkyl group, a C7-20-arylalkyl, C7-20-alkylaryl group or C6-20-aryl group or an OY group, wherein Y is a C1-10-hydrocarbyl group. 21. Article, comprising the fiber reinforced composition (C) according to any one of claims 1 to 20. |
wherein each X independently is a sigma-donor ligand, L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom or a C 1 -C 20 -hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 of the periodic table or fluorine atoms, or optionally two R’ groups taken together can form a ring, each R 1 are independently the same or can be different and are hydrogen, a linear or branched C 1 -C 6 -alkyl group, a C 7-20 -arylalkyl, C 7-20 -alkylaryl group or C 6-20 -aryl group or an OY group, wherein Y is a C 1-10 -hydrocarbyl group, and optionally two adjacent R 1 groups can be part of a ring including the phenyl carbons to which they are bonded, each R 2 independently are the same or can be different and are a CH 2 -R 8 group, with R 8 being H or linear or branched C 1-6 -alkyl group, C 3-8 -cycloalkyl group, C 6-10 - aryl group, R 3 is a linear or branched C 1 -C 6 -alkyl group, C 7-20 -arylalkyl, C 7-20 -alkylaryl group or C 6 -C 20 -aryl group, R 4 is a C(R 9 ) 3 group, with R 9 being a linear or branched C 1 -C 6 -alkyl group, R 5 is hydrogen or an aliphatic C 1 -C 20 -hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 of the periodic table; R 6 is hydrogen or an aliphatic C 1 -C 20 -hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 of the periodic table; or R 5 and R 6 can be taken together to form a 5 membered saturated carbon ring which is optionally substituted by n groups R 10 , n being from 0 to 4; each R 10 is same or different and may be a C 1 -C 20 -hydrocarbyl group, or a C 1 -C 20 - hydrocarbyl group optionally containing one or more heteroatoms belonging to groups 14-16 of the periodic table; R 7 is H or a linear or branched C 1 -C 6 -alkyl group or an aryl or heteroaryl group having 6 to 20 carbon atoms optionally substituted by one to three groups R 11 , each R 11 are independently the same or can be different and are hydrogen, a linear or branched C 1 -C 6 -alkyl group, a C 7-20 -arylalkyl, C 7-20 -alkylaryl group or C 6-20 -aryl group or an OY group, wherein Y is a C 1-10 -hydrocarbyl group, (ii) a co-catalyst system comprising a boron containing co-catalyst and/or an aluminoxane co-catalyst, and (iii) a silica support. The term “sigma-donor ligand” is well understood by the person skilled in the art, i.e. a group bound to the metal via a sigma bond. Thus the anionic ligands “X” can independently be halogen or be selected from the group consisting of R’, OR’, SiR’ 3 , OSiR’ 3 , OSO 2 CF 3 , OCOR’, SR’, NR’ 2 or PR’ 2 group wherein R´ is independently hydrogen, a linear or branched, cyclic or acyclic, C 1 to C 20 alkyl, C 2 to C 20 alkenyl, C 2 to C 20 alkynyl, C 3 to C 12 cycloalkyl, C 6 to C 20 aryl, C 7 to C 20 arylalkyl, C 7 to C 20 alkylaryl, C 8 to C 20 arylalkenyl, in which the R’ group can optionally contain one or more heteroatoms belonging to groups 14 to 16. In a preferred embodiment the anionic ligands “X” are identical and either halogen, like Cl, or methyl or benzyl. A preferred monovalent anionic ligand is halogen, in particular chlorine (Cl). Preferred metallocene complexes include: rac-dimethylsilanediylbis[2-methyl-4-(3’,5’-dimethylphen yl)-5-methoxy-6-tert-butylinden-1- yl] zirconium dichloride, rac-anti-dimethylsilanediyl[2-methyl-4-(4´-tert-butylphenyl )-inden-1-yl][2-methyl-4-(4´- tertbutylphenyl)- 5-methoxy-6-tert-butylinden-1-yl] zirconium dichloride, rac-anti-dimethylsilanediyl[2-methyl-4-(4´-tert-butylphenyl )-inden-1-yl][2-methyl-4-phenyl-5- methoxy-6-tert-butylinden-1-yl] zirconium dichloride, rac-anti-dimethylsilanediyl[2-methyl-4-(3´,5´-tert-butylph enyl)-1,5,6,7-tetrahydro-sindacen-1- yl][2-methyl-4-(3’,5’-dimethyl-phenyl)-5-methoxy-6-tert- butylinden-1-yl] zirconium dichloride, rac-anti-dimethylsilanediyl[2-methyl-4,8-bis-(4´-tert-butyl phenyl)-1,5,6,7-tetrahydro-sindacen- 1-yl][2-methyl-4-(3’,5’-dimethyl-phenyl)-5-methoxy-6-ter t-butylinden-1-yl] zirconium dichloride, rac-anti-dimethylsilanediyl[2-methyl-4,8-bis-(3’,5’-dime thylphenyl)-1,5,6,7-tetrahydro-s- indacen-1-yl] [2-methyl-4-(3’,5’-dimethylphenyl)-5-methoxy-6-tert-buty linden-1-yl] zirconium dichloride, rac-anti-dimethylsilanediyl[2-methyl-4,8-bis-(3’,5’-dime thylphenyl)-1,5,6,7-tetrahydro-s- indacen-1-yl][2-methyl-4-(3’,5’-5 ditert-butyl-phenyl)-5-methoxy-6-tert-butylinden-1-yl] zirconium dichloride. Especially preferred is rac-anti-dimethylsilanediyl[2-methyl-4,8-bis-(3’,5’-dime thylphenyl)- 1,5,6,7-tetrahydro-s indacen-1-yl] [2-methyl-4-(3’,5’-dimethylphenyl)-5-methoxy-6- tertbutylinden-1-yl] zirconium dichloride (II) The ligands required to form the complexes and hence catalysts of the invention can be synthesised by any process and the skilled organic chemist would be able to devise various synthetic protocols for the manufacture of the necessary ligand materials. For Example WO2007/116034 discloses the necessary chemistry. Synthetic protocols can also generally be found in WO 2002/02576, WO 2011/135004, WO 2012/084961, WO 2012/001052, WO 2011/076780, WO 2015/158790 and WO 2018/122134. Especially reference is made to WO 2019/179959, in which the most preferred catalyst of the present invention is described. According to the present invention a co-catalyst system comprising a boron containing co- catalyst and/or an aluminoxane co-catalyst is used in combination with the above defined metallocene catalyst complex. The aluminoxane co-catalyst can be one of formula (III): where n is usually from 6 to 20 and R has the meaning below. Aluminoxanes are formed on partial hydrolysis of organoaluminum compounds, for example those of the formula AlR 3 , AlR 2 Y and Al 2 R 3 Y 3 where R can be, for example, C 1 -C 10 alkyl, preferably C 1 -C 5 alkyl, or C 3 -C 10 cycloalkyl, C 7 -C 12 arylalkyl or alkylaryl and/or phenyl or naphthyl, and where Y can be hydrogen, halogen, preferably chlorine or bromine, or C 1 -C 10 alkoxy, preferably methoxy or ethoxy. The resulting oxygen-containing aluminoxanes are not in general pure compounds but mixtures of oligomers of the formula (III). The preferred aluminoxane is methylaluminoxane (MAO). Since the aluminoxanes used as co-catalysts according to the invention are not, owing to their mode of preparation, pure compounds, the molarity of aluminoxane solutions hereinafter is based on their aluminium content. According to the present invention, also a boron containing co-catalyst can be used instead of the aluminoxane co-catalyst or the aluminoxane co-catalyst can be used in combination with a boron containing co-catalyst. It will be appreciated by the person skilled in the art that where boron based co-catalysts are employed, it is normal to pre-alkylate the complex by reaction thereof with an aluminium alkyl compound, such as TIBA. This procedure is well known and any suitable aluminium alkyl, e.g. Al(C 1 -C 6 alkyl) 3 can be used. Preferred aluminium alkyl compounds are triethylaluminium, tri-isobutylaluminium, tri-isohexylaluminium, tri-n-octylaluminium and tri- isooctylaluminium. Alternatively, when a borate co-catalyst is used, the metallocene catalyst complex is in its alkylated version, that is for example a dimethyl or dibenzyl metallocene catalyst complex can be used. Boron based co-catalysts of interest include those of formula (IV) BY 3 (IV) wherein Y is the same or different and is a hydrogen atom, an alkyl group of from 1 to about 20 carbon atoms, an aryl group of from 6 to about 15 carbon atoms, alkylaryl, arylalkyl, haloalkyl or haloaryl each having from 1 to 10 carbon atoms in the alkyl radical and from 6- 20 carbon atoms in the aryl radical or fluorine, chlorine, bromine or iodine. Preferred examples for Y are methyl, propyl, isopropyl, isobutyl or trifluoromethyl, unsaturated groups such as aryl or haloaryl like phenyl, tolyl, benzyl groups, p-fluorophenyl, 3,5- difluorophenyl, pentachlorophenyl, pentafluorophenyl, 3,4,5-trifluorophenyl and 3,5- di(trifluoromethyl)phenyl. Preferred options are trifluoroborane, triphenylborane, tris(4- fluorophenyl)borane, tris(3,5-difluorophenyl)borane, tris(4-fluoromethylphenyl)borane, tris(2,4,6-trifluorophenyl)borane, tris(penta-fluorophenyl)borane, tris(tolyl)borane, tris(3,5- dimethyl-phenyl)borane, tris(3,5-difluorophenyl)borane and/or tris (3,4,5- trifluorophenyl)borane. Particular preference is given to tris(pentafluorophenyl)borane. However it is preferred that borates are used, i.e. compounds containing a borate 3+ ion. Such ionic co-catalysts preferably contain a non-coordinating anion such as tetrakis(pentafluorophenyl)borate and tetraphenylborate. Suitable counterions are protonated amine or aniline derivatives such as methylammonium, anilinium, dimethylammonium, diethylammonium, N- methylanilinium, diphenylammonium, N,N-dimethylanilinium, trimethylammonium, triethylammonium, tri-n-butylammonium, methyldiphenylammonium, pyridinium, p-bromo-N,N- dimethylanilinium or p-nitro-N,N-dimethylanilinium. Preferred ionic compounds which can be used according to the present invention include: triethylammoniumtetra(phenyl)borate, tributylammoniumtetra(phenyl)borate, trimethylammoniumtetra(tolyl)borate, tributylammoniumtetra(tolyl)borate, tributylammoniumtetra(pentafluorophenyl)borate, tripropylammoniumtetra(dimethylphenyl)borate, tributylammoniumtetra(trifluoromethylphenyl)borate, tributylammoniumtetra(4-fluorophenyl)borate, N,N-dimethylcyclohexylammoniumtetrakis(pentafluorophenyl)bor ate, N,N-dimethylbenzylammoniumtetrakis(pentafluorophenyl)borate, N,N-dimethylaniliniumtetra(phenyl)borate, N,N-diethylaniliniumtetra(phenyl)borate, N,N-dimethylaniliniumtetrakis(pentafluorophenyl)borate, N,N-di(propyl)ammoniumtetrakis(pentafluorophenyl)borate, di(cyclohexyl)ammoniumtetrakist(pentafluorophenyl)borate, triphenylphosphoniumtetrakis(phenyl)borate, triethylphosphoniumtetrakis(phenyl)borate, diphenylphosphoniumtetrakis(phenyl)borate, tri(methylphenyl)phosphoniumtetrakis(phenyl)borate, tri(dimethylphenyl)phosphoniumtetrakis(phenyl)borate, triphenylcarbeniumtetrakis(pentafluorophenyl)borate, or ferroceniumtetrakis(pentafluorophenyl)borate. Preference is given to triphenylcarbeniumtetrakis(pentafluorophenyl) borate, N,N- dimethylcyclohexylammoniumtetrakis(pentafluorophenyl)borate or N,N- dimethylbenzylammoniumtetrakis(pentafluorophenyl)borate. It has been surprisingly found that certain boron co-catalysts are especially preferred. Preferred borates of use in the invention therefore comprise the trityl ion. Thus the use of N,N-dimethylammonium-tetrakispentafluorophenylborate and Ph 3 CB(PhF 5 ) 4 and analogues therefore are especially favoured. According to the present invention, the preferred co-catalysts are aluminoxanes, more preferably methylaluminoxanes, combinations of aluminoxanes with Al-alkyls, boron or borate co-catalysts, and combination of aluminoxanes with boron-based co-catalysts. Suitable amounts of co-catalyst will be well known to the person skilled in the art. The molar ratio of boron to the metal ion of the metallocene may be in the range 0.5:1 to 10:1 mol/mol, preferably 1:1 to 10:1, especially 1:1 to 5:1 mol/mol. The molar ratio of Al in the aluminoxane to the metal ion of the metallocene may be in the range 1:1 to 2000:1 mol/mol, preferably 10:1 to 1000:1, and more preferably 50:1 to 500:1 mol/mol. The catalyst can be used in supported or unsupported form, preferably in supported form. The particulate support material used is preferably an organic or inorganic material, such as silica, alumina or zirconia or a mixed oxide such as silica-alumina, in particular silica, alumina or silica-alumina. The use of a silica support is preferred. The person skilled in the art is aware of the procedures required to support a metallocene catalyst. Especially preferably, the support is a porous material so that the complex may be loaded into the pores of the support, e.g. using a process analogous to those described in WO94/14856 (Mobil), WO95/12622 (Borealis) and WO2006/097497. The average particle size of the silica support can be typically from 10 to 100 μm. However, it has turned out that special advantages can be obtained if the support has a median particle size d50 from 15 to 80 μm, preferably from 18 to 50 μm. The average pore size of the silica support can be in the range 10 to 100 nm and the pore volume from 1 to 3 mL/g. Examples of suitable support materials are, for instance, ES757 produced and marketed by PQ Corporation, Sylopol 948 produced and marketed by Grace or SUNSPERA DM-L-303 silica produced by AGC Si-Tech Co. Supports can be optionally calcined prior to the use in catalyst preparation in order to reach optimal silanol group content. The use of these supports is well known in the art. According to a second embodiment of the present invention, the propylene homo- or copolymer (PP) being the matrix of the heterophasic polypropylene composition (HECO) is a propylene copolymer (cPP). The heterophasic polypropylene composition (HECO) according to the second embodiment of the present invention preferably has a rather low melt flow rate. Preferably, the melt flow rate MFR 2 (230 °C, 2.16 kg) determined according to ISO 1133 of the heterophasic polypropylene composition (HECO) according to the second embodiment of the present invention is in the range of 5.0 to 20.0 g/10 min, more preferably in the range of 6.0 to 15.0 g/10 min. It is preferred that the heterophasic polypropylene composition (HECO) according to the second embodiment of the present invention comprises i) 40.0 to 90.0 wt.-%, more preferably 45.0 to 85.0 wt.-%, still more preferably 56.0 to 74.0 wt.-%, like 58.0 to 65.0 wt.-% of the propylene copolymer (cPP), and ii) 10.0 to 60.0 wt.-%, more preferably 15.0 to 55.0 wt.-%, still more preferably 26.0 to 44.0 wt.-%, like 35.0 to 42.0 wt.-% of the elastomeric ethylene copolymer (E), based on the overall weight of the heterophasic polypropylene composition (HECO). The propylene copolymer (cPP) preferably comprises monomers copolymerizable with propylene, for example comonomers such as ethylene and/or C 4 to C 8 α-olefins, in particular ethylene and/or C 4 to C 6 α-olefins, e.g.1-butene and/or 1-hexene. Preferably, the propylene copolymer (cPP) comprises, especially consists of, monomers copolymerizable with propylene from the group consisting of ethylene, 1-butene and 1-hexene. More specifically, the propylene copolymer (cPP) comprises - apart from propylene - units derivable from ethylene and/or 1-butene. Thus, in an especially preferred embodiment the propylene copolymer (cPP) comprises units derivable from ethylene and propylene only. In particular, it is preferred that the propylene copolymer (cPP) is a random propylene copolymer, like a random copolymer of propylene and ethylene. The term “random copolymer” has to be preferably understood according to IUPAC (Pure Appl. Chem., Vol. No.68, 8, pp.1591 to 1595, 1996). Preferably the molar concentration of comonomer dyads, like ethylene dyads, obeys the relationship [HH] < [H] 2 wherein [HH] is the molar fraction of adjacent comonomer units, like of adjacent ethylene units, and [H] is the molar fraction of total comonomer units, like of total ethylene units, in the polymer. Preferably, the propylene copolymer (cPP) has a comonomer content, like ethylene content, in the range of 2.2 to 8.5 mol-%, more preferably in the range of 2.5 to 6.0 mol-%, still more preferably in the range of 3.0 to 4.8 mol-%, like in the range of 3.5 to 4.0 mol-%. Further, it is preferred that the propylene copolymer (cPP) has a melt flow rate MFR 2 (230 °C, 2.16 kg) determined according to ISO 1133 in the range of 5.0 to 20.0 g/10 min, more preferably in the range of 6.0 to 15.0 g/10 min, still more preferably in the range of 6.5 to 12.0 g/10 min, like in the range of 7.0 to 10.0 g/10 min. The melting temperature of the propylene copolymer (cPP) is preferably in the range of 120 to 150 °C, more preferably in the range of 123 to 145 °C, still more preferably in the range of 128 to 140 °C, like in the range of 133 to 139 °C. The process for the preparation of the propylene copolymer (cPP) is preferably a sequential polymerization process comprising at least two reactors connected in series, wherein said process comprises the steps of (A) optionally polymerizing in a first reactor (R-1) being a slurry reactor (SR), preferably a loop reactor (LR), propylene and optionally a comonomer selected from ethylene and C4 to C12 α-olefins, preferably ethylene, obtaining a first propylene copolymer fraction, (B) transferring said first propylene copolymer fraction and unreacted comonomers of the first reactor (R-1) in a second reactor (R-2) being a gas phase reactor (GPR-1), (C) feeding to said second reactor (R-2) propylene and a comonomer selected from ethylene and C4 to C12 α-olefins, preferably ethylene, (D) polymerizing in said second reactor (R-2) and in the presence of said first propylene copolymer fraction and a comonomer selected from ethylene and C4 to C12 α-olefins, preferably ethylene, obtaining a second propylene copolymer fraction, said first propylene copolymer fraction and said second propylene copolymer fraction form the propylene copolymer (cPP) as defined in the instant invention, wherein further in the first reactor (R-1) and second reactor (R-2) the polymerization takes place in the presence of a solid catalyst system (SCS). It is preferred that the solid catalyst system (SCS) comprises the metallocene catalyst of formula (I) and the cocatalyst as described with regard to the reference is made to the heterophasic polypropylene composition (HECO) according to the first embodiment of the present invention. Accordingly, it is preferred that the solid catalyst system (SCS) as described above including all preferred embodiments is applied for the preparation of the propylene copolymer (cPP). Regarding the term “sequential polymerization process”, reference is made to the definition provided above. The first reactor (R-1), if applied, is a slurry reactor (SR) and can be any continuous or simple stirred batch tank reactor or loop reactor operating in slurry. According to the present invention the slurry reactor (SR) is preferably a loop reactor (LR). The second reactor (R-2) and any subsequent reactors are gas phase reactors (GPR). Such gas phase reactors (GPR) can be any mechanically mixed or fluid bed reactors. Preferably the gas phase reactor(s) (GPR) comprise a mechanically agitated fluid bed reactor with gas velocities of at least 0.2 m/sec. Thus it is appreciated that the gas phase reactor (GPR) is a fluidized bed type reactor preferably with a mechanical stirrer. The condition (temperature, pressure, reaction time, monomer feed) in each reactor is dependent on the desired product which is in the knowledge of a person skilled in the art. As already indicated above, the first reactor (R-1) is a slurry reactor (SR), like a loop reactor (LR), whereas the second reactor (R-2) is a gas phase reactor (GPR-1). The subsequent reactors – if present – are also gas phase reactors (GPR). A preferred multistage process is a “loop-gas phase”-process, such as developed by Borealis A/S, Denmark (known as BORSTAR® technology) described e.g. in patent literature, such as in EP 0887379 or in WO 92/12182. Multimodal polymers can be produced according to several processes which are described, e.g. in WO 92/12182, EP 0887379, and WO 98/58976. The contents of these documents are included herein by reference. Regarding the conditions for the first reactor (R-1), i.e. the slurry reactor (SR), like the loop reactor (LR) and the second reactor (R-2), i.e. the gas phase reactor (GPR), as well as the residence times, reference is made to the conditions defined above regarding the heterophasic polypropylene composition (HECO) according to the first embodiment of the present invention. This applies accordingly for the optional application of a pre- polymerization step. The elastomeric ethylene copolymer (E) according to the second embodiment of the present invention can comprise monomers copolymerizable with ethylene, for example comonomers such as C 3 to C 12 α-olefins, in particular propylene, 1-butene, 1-hexene and/or 1-octene. More specifically, the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention comprises - apart from ethylene - units derivable from 1-butene, 1-hexene and/or 1-octene. It is especially preferred that the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention is a copolymer of ethylene and 1-octene. Preferably, the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention is a very low density polyethylene, more preferably a very low density polyethylene polymerized using single site catalysis. The elastomeric ethylene copolymer (E) according to the second embodiment of the present invention has a density determined according to ISO 1183-187 in the range of 860 to 890 kg/m 3 . Preferably, the density determined according to ISO 1183-187 of the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention is in the range of 865 to 885 kg/m 3 , more preferably in the range of 870 to 884 kg/m 3 , like in the range of 879 to 883 kg/m 3 . Preferably, the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention has a melt flow rate MFR (190 °C, 2.16 kg) determined according to ISO 1133 in the range of 0.8 to 20.0 g/10 min, more preferably in the range of 0.9 to 10.0 g/10 min, still more preferably in the range of 1.0 to 5.0 g/10 min, like in the range of 1.0 to 2.0 g/10.0 min. The ethylene content of the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention is in the range of 55.0 to 85.0 wt.-%, preferably in the range of 65.0 to 80.0 wt.-%, more preferably in the range of 70.0 to 78.0 wt.-%, based on the overall weight of the elastomeric ethylene copolymer (E). Additionally it is preferred that the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention has a melting temperature Tm determined according to differential scanning calorimetry (DSC) of below 100 °C, more preferably in the range of 50 °C to 90 °C, still more preferably in the range of 55 °C to 85 °C. Alternatively or additionally to the previous paragraph it is preferred that the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention has a glass transition temperature of below -25 °C, more preferably in the range of -65 °C to -30 °C, still more preferably in the range of -60 °C to -35 °C. In one preferred embodiment the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention is prepared with at least one single-site catalyst. The elastomeric ethylene copolymer (E) according to the second embodiment of the present invention may also be prepared with more than one single-site catalyst or may be a blend of multiple elastomeric copolymers prepared with different single-site catalysts. In some embodiments, the elastomeric ethylene copolymer (E) according to the second embodiment of the present invention is a substantially linear ethylene polymer (SLEP). SLEPs and other single-site catalyzed elastomeric ethylene copolymers are known in the art, for example, US 5,272,236. These resins are also commercially available, for example, as Queo™ plastomers available from Borealis, ENGAGE™ plastomer resins available from Dow Chemical Co., EXACT™ polymers from Exxon or TAFMER™ polymers from Mitsui, Lucene polymers from LG, Fortify polymers from Sabic or Solumer polymers from SK Chemicals. The heterophasic polypropylene composition (HECO) according to the second embodiment of the present invention may further comprise a low density polyethylene (LDPE). Preferably, the low density polyethylene (LDPE) has a melt flow rate MFR (190 °C, 2.16 kg) determined according to ISO 1133 in the range of 0.5 to 5.0 g/10 min, more preferably in the range of 0.8 to 10.0 g/10 min, still more preferably in the range of 1.0 to 7.0 g/10 min, like in the range of 2.5 to 3.5 g/10 min. Additionally, it is preferred that the low density polyethylene (LDPE) has a density determined according to ISO 1183-187 of more than 900 kg/m 3 , preferably in the range of 920 to 960 kg/m 3 , more preferably in the range of 925 to 955 kg/m 3 . Further, it is preferred that the low density polyethylene (LDPE) is a copolymer of ethylene and a polar comonomer copolymerizable with ethylene. Examples of polar comonomers are vinyl carboxylate esters selected from the group consisting of vinyl acetate and vinyl pivalate, (meth)acrylates, such as methyl(meth)acrylate, ethyl(meth)acrylate, butyl(meth)acrylate and hydroxyethyl-(meth)acrylate, olefinically unsaturated carboxylic acids, such as (meth)acrylic acid, maleic acid and fumaric acid, (meth)acrylic acid derivatives, such as (meth)acrylonitrile and (meth)acrylic amide, and vinyl ethers, such as vinyl methyl ether and vinyl phenyl ether. Preferably, the polar comonomer is a vinyl carboxylate ester. It is especially preferred that the polar comonomer is vinyl acetate. Further, it is preferred that the low density polyethylene (LDPE) has a comonomer content, preferably vinyl acetate content in the range of 10.0 to 40.0 wt.-%, more preferably in the range of 15.0 to 35.0 wt.-%, still more preferably in the range of 20.0 to 33.0 wt.-%, like in the range of 25.0 to 30.0 wt.-%, based on the overall weight of the low density polyethylene (LDPE). It is particularly preferred that the low density polyethylene (LDPE) consists of ethylene and vinyl acetate units only. The low density polyethylene (LDPE) is preferably produced by a high-pressure polymerization with free radical initiation. Preferably, the low density polyethylene (LDPE) is a copolymer known in the art. It is especially preferred that the low density polyethylene (LDPE) is the commercial copolymer of ethylene and vinyl acetate OE5328I of Borealis. The heterophasic polypropylene composition (HECO) according to the second embodiment of the present invention is preferably obtained by melt blending the propylene copolymer (cPP), the elastomeric ethylene copolymer (E) and optionally the low density polyethylene (LDPE). The fiber reinforced composition (C) according to the second embodiment of the present invention preferably has a melt flow rate MFR 2 (230 °C, 2.16 kg) determined according to ISO 1133 in the range of 1.0 to 10.0 g/10 min, more preferably in the range of 1.5 to 6.0 g/10 min, still more preferably in the range of 2.0 to 4.5 g/10 min, like in the range of 2.5 to 3.8 g/10 min. Further, it is preferred that the fiber reinforced composition (C) according to the second embodiment of the present invention has a tensile modulus determined according to ISO 527-1A in the range of 2500 to 5500 MPa, more preferably in the range of 2550 to 4200 MPa, still more preferably in the range of 2600 to 3500 MPa, like in the range of 2650 to 2800 MPa. Additionally or alternatively, it is preferred that the fiber reinforced composition (C) according to the second embodiment of the present invention has an elongation at break determined according to ISO 527-2 of more than 10.0 %, more preferably more than 10.3 %, still more preferably more than 10.8 %, like equal or above 11.0 %. The fibers (F) Essential components of the present fiber reinforced composition (C) are the fibers (F). Preferably the fibers (F) are selected from the group consisting of glass fibers, carbon fibers, polymeric fibers, metal fibers, mineral fibers, ceramic fibers and mixtures thereof. More preferably, the fibers (F) are glass fibers and/or carbon fibers. It is especially preferred that the fibers (F) are glass fibers (GF). Preferably, the glass fibers (GF) are cut glass fibers, also known as short glass fibers (SGF) or chopped strands, and/or long glass fibers (LGF), preferably long glass fibers (LGF) obtained from glass rovings. It is particularly preferred that the fibers (F) are short glass fibers (GF). The cut or short glass fibers (SGF) used in the fiber reinforced composition (C) preferably have an average length in the range of from 2.0 to 10.0 mm, more preferably in the range of 2.3 to 9.0 mm, still more preferably in the range of 2.5 to 8.0 mm, like in the range of 3.0 to 7.0 mm. The cut or short glass fibers (SGF) used in the fiber reinforced composition (C) preferably have an average diameter of from 5 to 20 μm, more preferably from 6 to 18 μm, still more preferably 8 to 16 μm. Preferably, the short glass fibers (SGF) have an aspect ratio of 125 to 650, preferably of 150 to 500, more preferably 200 to 450. The aspect ratio is the relation between average length and average diameter of the fibers. The adhesion promoter (AP) In accordance with the present invention, the fiber reinforced polypropylene composition (C) may further comprise an adhesion promoter (AP). In case the fibers (F) are glass fibers and/or carbon fibers, it is preferred that the fiber reinforced polypropylene composition (C) comprises the adhesion promoter (AP). The adhesion promoter (AP) is specified as being a polar modified polypropylene (PM-PP) homo- or copolymer. The polar modified polypropylene (PM-PP) homo- or copolymer comprises a low molecular weight compound having reactive polar groups. Modified polypropylene homopolymers and copolymers, like copolymers of propylene and ethylene or with other α-olefins, e.g. C4 to C10 α-olefins, are most preferred, as they are highly compatible with the propylene homo- or copolymer (PP) of the inventive fiber reinforced polypropylene composition (C). In terms of structure, the polar modified polypropylene (PM-PP) homo- or copolymer are preferably selected from graft homo- or copolymers. In this context, preference is given to polar modified polypropylene (PM-PP) homo- or copolymers containing groups derived from polar compounds, in particular selected from the group consisting of acid anhydrides, carboxylic acids, carboxylic acid derivatives, primary and secondary amines, hydroxyl compounds, oxazoline and epoxides, and also ionic compounds. Specific examples of said polar compounds are unsaturated cyclic anhydrides and their aliphatic diesters, and the diacid derivatives. In particular, one can use maleic anhydride and compounds selected from C1 to C10 linear and branched dialkyl maleates, C1 to C10 linear and branched dialkyl fumarates, itaconic anhydride, C1 to C10 linear and branched itaconic acid dialkyl esters, acrylic acid, maleic acid, fumaric acid, itaconic acid and mixtures thereof. Particular preference is given to use a polypropylene homo- or copolymer grafted with maleic anhydride or acrylic acid as the polar modified polypropylene (PM-PP) homo- or copolymer, i.e. the adhesion promoter (AP). The modified polymer, i.e. the adhesion promoter, can be produced in a simple manner by reactive extrusion of the polymer, for example with maleic anhydride or acrylic acid in the presence of free radical generators (like organic peroxides), as disclosed for instance in US 4,506,056, US 4,753,997 or EP 1805238. Preferred amounts of groups derived from polar compounds in the polar modified polypropylene (PM-PP) homo- or copolymer, i.e. the adhesion promoter (AP), are from 0.5 to 5.0 wt.-%. For example, the amount may be in the range of 0.5 wt.-% to 4.5 wt.-%, preferably in the range of 0.5 wt.-% to 4.0 wt.-%, more preferably in the range of 0.5 wt.-% to 3.5 wt.-%. Preferred values of the melt flow rate MFR 2 (230 °C) for the polar modified polypropylene (PM-PP) homo- or copolymer, i.e. for the adhesion promoter (AP), are from at least 20.0 to 400 g/10 min. It is particularly preferred that the polar modified polypropylene (PM-PP) homo- or copolymer has a melt flow rate MFR 2 (230 °C) in the range of 40.0 to 300 g/10 min, more preferably in the range of 50.0 to 250 g/10 min. In one preferred embodiment of the present invention, the adhesion promoter (AP) is a maleic anhydride modified polypropylene homo-or copolymer and/or an acrylic acid modified polypropylene homo-or copolymer. Preferably, the adhesion promoter (AP) is a maleic anhydride modified polypropylene homopolymer and/or an acrylic acid modified polypropylene homopolymer and preferably a maleic anhydride modified polypropylene homopolymer. For example, suitable polar modified polypropylene (PM-PP) homo- or copolymers include, for example, a polypropylene homopolymer grafted with maleic anhydride (PP-g-MAH) and a polypropylene homopolymer grafted with acrylic acid (PP-g- AA). The additives (AD) In addition to the heterophasic polypropylene composition (HECO), the fibers (F) and the adhesion promoter (AP), the fiber reinforced composition (C) of the invention may include additives (AD). Typical additives are acid scavengers, antioxidants, colorants, light stabilisers, plasticizers, slip agents, anti-scratch agents, dispersing agents, processing aids, lubricants, pigments, and the like. Such additives are commercially available and for example described in “Plastic Additives Handbook”, 6th edition 2009 of Hans Zweifel (pages 1141 to 1190). Furthermore, the term “additives (AD)” according to the present invention also includes carrier materials, in particular polymeric carrier materials. The Polymeric Carrier Material Preferably the fiber reinforced polypropylene composition (C) of the invention does not comprise (a) further polymer (s) different to the components of the heterophasic polypropylene composition (HECO) and the adhesion promoter (AP), in an amount exceeding 15 wt.-%, preferably in an amount exceeding 10 wt.-%, more preferably in an amount exceeding 9 wt.-%, based on the weight of the fiber reinforced polypropylene composition (C). Any polymer being a carrier material for additives (AD) is not calculated to the amount of polymeric compounds as indicated in the present invention, but to the amount of the respective additive. The polymeric carrier material of the additives (AD) is a carrier polymer to ensure a uniform distribution in the fiber reinforced polypropylene composition (C) of the invention. The polymeric carrier material is not limited to a particular polymer. The polymeric carrier material may be ethylene homopolymer, ethylene copolymer obtained from ethylene and α-olefin comonomer such as C3 to C8 α-olefin comonomer, propylene homopolymer and/or propylene copolymer obtained from propylene and α-olefin comonomer such as ethylene and/or C4 to C8 α-olefin comonomer. It is preferred that the polymeric carrier material does not contain monomeric units derivable from styrene or derivatives thereof. The article The present invention also relates to an article, like an injection moulded article, comprising the fiber reinforced composition (C) as defined above. The present invention in particular relates to an article, like an injection moulded article, comprising at least 60 wt.-%, more preferably at least 80 wt.-%, still more preferably at least 90 wt.-%, like at least 95 wt.-% or at least 99 wt.-%, of the fiber reinforced polypropylene composition (C) as defined above. In an especially preferred embodiment the present invention relates to an article, like an injection moulded article, consisting of the fiber reinforced composition (C) as defined above. Preferably, the article is an automotive article, like an injection moulded automotive article. Further embodiments [1] Fiber reinforced composition (C), comprising a) 55.0 to 94.9 wt.-% of a heterophasic polypropylene composition (HECO), comprising i) a matrix being a propylene homo- or copolymer (PP) having an amount of 1,2 erythro regio-defects of at least 0.4 mol-% and a comonomer content equal or below 8.5 mol-%, and ii) an elastomeric ethylene copolymer (E) being dispersed in said matrix, b) 5.0 to 45.0 wt.-% of fibers (F), and c) optionally 0.1 to 5.0 wt.-% of an adhesion promoter (AP), based on the overall weight of the fiber reinforced composition (C), wherein the fiber reinforced composition (C) has a melt flow rate MFR 2 (230 °C, 2.16 kg) determined according to ISO 1133 in the range of 1.0 to 60.0 g/10 min. [2] Fiber reinforced composition (C) according to embodiment [1], wherein the heterophasic polypropylene composition (HECO) comprises i) 60.0 to 95.0 wt.-% of the matrix being the propylene homo- or copolymer (PP), and ii) 5.0 to 40.0 wt.-% of the elastomeric ethylene copolymer (E), based on the overall weight of the heterophasic copolymer (HECO). [3] Fiber reinforced composition (C) according to embodiment [1] or [2], wherein the elastomeric ethylene copolymer (E) has an ethylene content in the range of 15.0 to 85.0 wt.-%, based on the overall weight of the elastomeric ethylene copolymer (E). [4] Fiber reinforced composition (C) according to any one of embodiments [1] to [3], wherein the heterophasic polypropylene composition (HECO) has a melting temperature Tm determined according to differential scanning calorimetry (DSC) in the range of 130 to 165 °C. [5] Fiber reinforced composition (C) according to any one of embodiments [1] to [4], wherein the heterophasic polypropylene composition (HECO) has an intrinsic viscosity (IV) measured according to ISO 1628/1 (at 135 °C in decalin) of the soluble fraction (SF) determined according to CRYSTEX QC the range of 1.8 to 3.0 dl/g. [6] Fiber reinforced composition (C) according to any one of embodiments [1] to [5], wherein the fibers (F) are glass fibers (GF), preferably short glass fibers (SGF) having i) an average length of 2.0 to 10.0 mm, and/or ii) an average diameter of 5 to 20 µm. [7] Fiber reinforced composition (C) according to any one of embodiments [1] to [6], wherein the adhesion promoter (AP) is a polar modified polypropylene (PM-PP) being a propylene homo- or copolymer grafted with maleic anhydride having a melt flow rate MFR (230 °C, 2.16 kg) determined according to ISO 1133 of at least 20.0 g/10 min to 400 g/10 min. [8] Fiber reinforced composition (C) according to any one of embodiments [1] to [7], wherein i) the propylene homo- or copolymer (PP) is a propylene homopolymer (hPP), and ii) the elastomeric ethylene polymer (E) is a copolymer of ethylene and propylene. [9] Fiber reinforced composition (C) according to embodiment [8], wherein the propylene homopolymer (hPP) has a melting temperature Tm determined according to differential scanning calorimetry (DSC) in the range of 140 to 160 °C. [10] Fiber reinforced composition (C) according to embodiment [8] or [9], wherein the heterophasic polypropylene composition (HECO) has i) a comonomer content in the range of 2.2 to 8.7 mol-%, and/or ii) a melt flow rate MFR 2 (230 °C, 2.16 kg) determined according to ISO 1133 in the range of 20.0 to 100 g/10 min. [11] Fiber reinforced composition (C) according to any one of embodiments [8] to [10], wherein the heterophasic polypropylene composition (HECO) has i) a xylene cold soluble (XCS) content determined at 25 °C according ISO 16152 in the range of 5.0 to 35.0 wt.-%, based on the overall weight of the heterophasic polypropylene composition (HECO), and/or ii) an ethylene content of the xylene cold soluble (XCS) fraction in the range of 20.9 to 44.7 mol-%. and/or ii) a soluble fraction (SF) determined according to CRYSTEX QC in the range of 5.0 to 35.0 wt.-%, based on the overall weight of the heterophasic polypropylene composition (HECO), and/or iv) an ethylene content of the soluble fraction (SF) determined according to CRYSTEX QC in the range of 20.9 to 44.7 mol-%. [12] Fiber reinforced composition (C) according to any one of embodiments [8] to [11], having i) a tensile modulus determined according to ISO 527-1A in the range of 3000 to 6000 MPa, and/or ii) an elongation at break determined according to ISO 527-2 of more than 3.0 %. [13] Fiber reinforced composition (C) according to any one of embodiments [1] to [7], wherein i) the propylene homo- or copolymer (PP) is a propylene copolymer (cPP) copolymer of propylene and ethylene having an ethylene content of 2.2 to 8.5 mol-%, and ii) the elastomeric ethylene copolymer (E) is a copolymer of ethylene and a C 4 to C 12 α-olefin, preferably 1-octene, having an ethylene content of 55.0 to 85.0 wt.-%, based on the overall weight of elastomeric ethylene copolymer (E). [14] Fiber reinforced composition (C) according to embodiment [13], wherein i) the propylene copolymer (cPP) has a melt flow rate MFR 2 (230 °C, 2.16 kg) determined according to ISO 1133 in the range of 5.0 to 20.0 g/10 min, and/or ii) the elastomeric ethylene copolymer (E) has a melt flow rate MFR (190 °C, 2.16 kg) determined according to ISO 1133 in the range of 0.8 to 20.0 g/10 min and/or a density determined according to ISO 1183-187 in the range of 860 to 890 kg/m³ and/or iii) the fiber reinforced composition (C) has a melt flow rate MFR 2 (230 °C, 2.16 kg) determined according to ISO 1133 in the range of 1.0 to 10.0 g/10 min. [15] Fiber reinforced composition (C) according to embodiment [13] or [14], having i) a tensile modulus determined according to ISO 527-1A in the range of 2500 to 5500 MPa, and/or ii) an elongation at break determined according to ISO 527-2 of more than 10.0 %. [16] Fiber reinforced composition (C) according to any one of embodiments [1] to [15], further comprising up to 20.0 wt.-% of a low density polyethylene (LDPE) homo- or copolymer having a density determined according to ISO 1183-187 of more than 900 kg/m³ and comprising ethylene and optionally vinyl acetate. [17] Fiber reinforced composition (C) according to any one of embodiments [1] to [16], wherein the propylene homo- or copolymer (PP) is obtained in the presence of a solid catalyst system (SCS) comprising a metallocene complex complex preferably having the formula (I)
wherein each X independently is a sigma-donor ligand, L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom or a C 1 -C 20 -hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 of the periodic table or fluorine atoms, or optionally two R’ groups taken together can form a ring, each R 1 are independently the same or can be different and are hydrogen, a linear or branched C 1 -C 6 -alkyl group, a C 7-20 -arylalkyl, C 7-20 -alkylaryl group or C 6-20 -aryl group or an OY group, wherein Y is a C 1-10 -hydrocarbyl group, and optionally two adjacent R 1 groups can be part of a ring including the phenyl carbons to which they are bonded, each R 2 independently are the same or can be different and are a CH 2 -R 8 group, with R 8 being H or linear or branched C 1-6 -alkyl group, C 3-8 -cycloalkyl group, C 6-10 - aryl group, R 3 is a linear or branched C 1 -C 6 -alkyl group, C 7-20 -arylalkyl, C 7-20 -alkylaryl group or C 6 -C 20 -aryl group, R 4 is a C(R 9 ) 3 group, with R 9 being a linear or branched C 1 -C 6 -alkyl group, R 5 is hydrogen or an aliphatic C 1 -C 20 -hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 of the periodic table; R 6 is hydrogen or an aliphatic C 1 -C 20 -hydrocarbyl group optionally containing one or more heteroatoms from groups 14-16 of the periodic table; or R 5 and R 6 can be taken together to form a 5 membered saturated carbon ring which is optionally substituted by n groups R 10 , n being from 0 to 4; each R 10 is same or different and may be a C 1 -C 20 -hydrocarbyl group, or a C 1 -C 20 - hydrocarbyl group optionally containing one or more heteroatoms belonging to groups 14-16 of the periodic table; R 7 is H or a linear or branched C 1 -C 6 -alkyl group or an aryl or heteroaryl group having 6 to 20 carbon atoms optionally substituted by one to three groups R 11 , each R 11 are independently the same or can be different and are hydrogen, a linear or branched C 1 -C 6 -alkyl group, a C 7-20 -arylalkyl, C 7-20 -alkylaryl group or C 6-20 -aryl group or an OY group, wherein Y is a C 1-10 -hydrocarbyl group. [18] Article, comprising the fiber reinforced composition (C) according to any one of embodiments [1] to [17]. The present invention will now be described in further detail by the examples provided below.
E X A M P L E S A. Measuring methods The following definitions of terms and determination methods apply for the above general description of the invention as well as to the below examples unless otherwise defined. Melt Flow Rate The melt flow rate (MFR) was determined according to ISO 1133 and is indicated in g/10 min. The MFR is an indication of the flowability, and hence the processability, of the polymer. The higher the melt flow rate, the lower the viscosity of the polymer. The MFR 2 of polypropylene is determined at a temperature of 230 °C or 190°C and a load of 2.16 kg. Melting temperature T m and crystallization temperature T c , were measured with Mettler TA820 differential scanning calorimetry (DSC) on 5-7 mg samples. DSC was run according to ISO 11357 / part 3 / method C2 in a heat / cool / heat cycle with a scan rate of 10 °C/min in the temperature range of -30 to +225°C. Crystallization temperature was determined from the cooling step, while melting temperature is determined from the second heating step. All mechanical measurements were conducted after 96 h conditioning time (at 23°C at 50 % relative humidity) of the test specimen. Quantification of PP matrix microstructure by 13 C-NMR spectroscopy Quantitative nuclear-magnetic resonance (NMR) spectroscopy was used to quantify the stereo-regularity (tacticity) and regio-regularity of the crystalline matrix of the polymers. Quantitative 13 C { 1 H} NMR spectra were recorded in the solution-state using a Bruker Advance III 400 NMR spectrometer operating at 400.15 and 100.62 MHz for 1 H and 13 C respectively. All spectra were recorded using a 13C optimised 10 mm extended temperature probe head at 125°C using nitrogen gas for all pneumatics. For propylene homopolymers approximately 200 mg of material was dissolved in 1,2- tetrachloroethane-d2 (TCE-d2). To ensure a homogenous solution, after initial sample preparation in a heat block, the NMR tube was further heated in a rotatary oven for at least 1 hour. Upon insertion into the magnet the tube was spun at 10 Hz. This setup was chosen primarily for the high resolution needed for tacticity distribution quantification (Busico, V., Cipullo, R., Prog. Polym. Sci.26 (2001) 443; Busico, V.; Cipullo, R., Monaco, G., Vacatello, M., Segre, A.L., Macromolecules 30 (1997) 6251). Standard single-pulse excitation was employed utilising the NOE and bi-level WALTZ16 decoupling scheme (Zhou, Z., Kuemmerle, R., Qiu, X., Redwine, D., Cong, R., Taha, A., Baugh, D. Winniford, B., J. Mag. Reson.187 (2007) 225; Busico, V., Carbonniere, P., Cipullo, R., Pellecchia, R., Severn, J., Talarico, G., Macromol. Rapid Commun.2007, 28, 11289). A total of 8192 (8k) transients were acquired per spectra. Quantitative 13 C{ 1 H} NMR spectra were processed, integrated and relevant quantitative properties determined from the integrals using proprietary computer programs. For propylene homopolymers all chemical shifts are internally referenced to the methyl isotactic pentad (mmmm) at 21.85 ppm. The tacticity distribution was quantified through integration of the methyl region between 23.6-19.7 ppm correcting for any sites not related to the stereo sequences of interest (Busico, V., Cipullo, R., Prog. Polym. Sci.26 (2001) 443; Busico, V., Cipullo, R., Monaco, G., Vacatello, M., Segre, A.L., Macromoleucles 30 (1997) 6251). Specifically the influence of regio defects and comonomer on the quantification of the tacticity distribution was corrected for by subtraction of representative regio defect and comonomer integrals from the specific integral regions of the stereo sequences. The isotacticity was determined at the pentad level and reported as the percentage of isotactic pentad (mmmm) sequences with respect to all pentad sequences: The presence of 2,1 erythro regio defects was indicated by the presence of the two methyl sites at 17.7 and 17.2 ppm and confirmed by other characteristic sites. Characteristic signals corresponding to other types of regio defects were not observed (Resconi, L., Cavallo, L., Fait, A., Piemontesi, F., Chem. Rev.2000, 100, 1253). The amount of 2,1 erythro regio defects was quantified using the average integral of the two characteristic methyl sites at 17.7 and 17.2 ppm: The amount of 1,2 primary inserted propene was quantified based on the methyl region with correction undertaken for sites included in this region not related to primary insertion and for primary insertion sites excluded from this region: The total amount of propene was quantified as the sum of primary inserted propene and all other present regio defects: The mole percent of 2,1 erythro regio defects was quantified with respect to all propene: Determination of the C2- and C3-content in PP copolymers Quantitative nuclear-magnetic resonance (NMR) spectroscopy was used to quantify the comonomer content and comonomer sequence distribution of the polymers. Quantitative 13 C{ 1 H} NMR spectra were recorded in the solution-state using a Bruker Avance III 400 NMR spectrometer operating at 400.15 and 100.62 MHz for 1 H and 13 C respectively. All spectra were recorded using a 13 C optimised 10 mm extended temperature probehead at 125°C using nitrogen gas for all pneumatics. Approximately 200 mg of material was dissolved in 3 ml of 1,2-tetrachloroethane-d 2 (TCE-d 2 ) along with chromium-(III)-acetylacetonate (Cr(acac) 3 ) resulting in a 65 mM solution of relaxation agent in solvent (Singh, G., Kothari, A., Gupta, V., Polymer Testing 285 (2009), 475). To ensure a homogenous solution, after initial sample preparation in a heat block, the NMR tube was further heated in a rotary oven for at least 1 hour. Upon insertion into the magnet the tube was spun at 10 Hz. This setup was chosen primarily for the high resolution and quantitatively needed for accurate ethylene content quantification. Standard single-pulse excitation was employed without NOE, using an optimised tip angle, 1 s recycle delay and a bi-level WALTZ16 decoupling scheme (Zhou, Z., Kuemmerle, R., Qiu, X., Redwine, D., Cong, R., Taha, A., Baugh, D. Winniford, B., J. Mag. Reson. 187 (2007) 225; Busico, V., Carbonniere, P., Cipullo, R., Pellecchia, R., Severn, J., Talarico, G., Macromol. Rapid Commun.2007, 28, 1128). A total of 6144 (6k) transients were acquired per spectra. Quantitative 13 C{ 1 H} NMR spectra were processed, integrated and relevant quantitative properties determined from the integrals using proprietary computer programs. All chemical shifts were indirectly referenced to the central methylene group of the ethylene block (EEE) at 30.00 ppm using the chemical shift of the solvent. This approach allowed comparable referencing even when this structural unit was not present. Characteristic signals corresponding to the incorporation of ethylene were observed Cheng, H. N., Macromolecules 17 (1984), 1950). The comonomer fraction was quantified using the method of Wang et. al. (Wang, W-J., Zhu, S., Macromolecules 33 (2000), 1157) through integration of multiple signals across the whole spectral region in the 13 C{ 1 H} spectra. This method was chosen for its robust nature and ability to account for the presence of regio-defects when needed. Integral regions were slightly adjusted to increase applicability across the whole range of encountered comonomer contents. For systems where only isolated ethylene in PPEPP sequences was observed the method of Wang et. al. was modified to reduce the influence of non-zero integrals of sites that are known to not be present. This approach reduced the overestimation of ethylene content for such systems and was achieved by reduction of the number of sites used to determine the absolute ethylene content to: E = 0.5(Sββ + Sβγ + Sβδ + 0.5(Sαβ + Sαγ)) Through the use of this set of sites the corresponding integral equation becomes: E = 0.5(I H +I G + 0.5(I C + I D )) using the same notation used in the article of Wang et. al. (Wang, W-J., Zhu, S., Macromolecules 33 (2000), 1157). Equations used for absolute propylene content were not modified. The mole percent comonomer incorporation was calculated from the mole fraction: E [mol-%] = 100 * fE The weight percent comonomer incorporation was calculated from the mole fraction: E [wt.-%] = 100 * (fE * 28.06) / ((fE * 28.06) + ((1-fE) * 42.08)) Comonomer content in ethylene/1-octene copolymer was measured in a known manner based on Fourier transform infrared spectroscopy (FTIR) calibrated with 13 C-NMR, using Nicolet Magna 550 IR spectrometer together with Nicolet Omnic FTIR software. Films having a thickness of about 250 μm were compression moulded from the samples. Similar films were made from calibration samples having a known content of the comonomer. The comonomer content was determined from the spectrum from the wave number range of from 1430 to 1100 cm -1 . The absorbance is measured as the height of the peak by selecting the so-called short or long base line or both. The short base line is drawn in about 1410 - 1320 cm -1 through the minimum points and the long base line about between 1410 and 1220 cm -1 . Calibrations need to be done specifically for each base line type. Also, the comonomer content of the unknown sample needs to be within the range of the comonomer contents of the calibration samples. The glass transition temperatures Tg were determined by dynamic mechanical analysis according to ISO 6721-7. The measurements were done in torsion mode on compression moulded samples (40x10x1 mm 3 ) between -100 °C and +150 °C with a heating rate of 2 °C/min and a frequency of 1 Hz. Density was measured according to ISO 1183-187. Sample preparation is done by compression moulding in accordance with ISO 1872-2:2007. Xylene Cold Soluble (XCS) Xylene Cold Soluble fraction at room temperature (XCS, wt.-%) was determined at 25°C according to ISO 16152; 5 th edition; 2005-07-01. Flexural Modulus: The flexural modulus was determined in 3-point-bending according to ISO 178 on injection moulded specimens of 80 x 10 x 4 mm prepared in accordance with ISO 294-1:1996. Charpy notched impact strength was determined according to ISO 179-1 / 1eA at 23 °C by using injection moulded test specimens (80 x 10 x 4 mm) prepared according to EN ISO 1873-2. Tensile properties were determined on injection moulded dogbone specimens of 4 mm thickness prepared in accordance with EN ISO 1873-2. Tensile modulus was determined according to ISO 527-1A at a strain rate of 1 mm/min and 23°C, tensile strength and elongation (strain) at break are determined according to ISO 527-2 at a strain rate of 50 mm/min and 23°C. Crystex analysis Crystalline and soluble fractions method The crystalline (CF) and soluble fractions (SF) of the polypropylene (PP) compositions as well as the comonomer content and intrinsic viscosities of the respective fractions were analyzed by the CRYSTEX QC, Polymer Char (Valencia, Spain). A schematic representation of the CRYSTEX QC instrument is shown in Figure 1a. The crystalline and amorphous fractions are separated through temperature cycles of dissolution at 160°C, crystallization at 40°C and re-dissolution in a 1,2,4-trichlorobenzene (1,2,4-TCB) at 160°C as shown in Figure 1b. Quantification of SF and CF and determination of ethylene content (C2) of the parent EP copolymer and its soluble and crystalline fractions are achieved by means of an infrared detector (IR4) and an online 2-capillary viscometer which is used for the determination of the intrinsic viscosity (iV). The IR4 detector is a multiple wavelength detector detecting IR absorbance at two different bands (CH3 and CH2) for the determination of the concentration and the Ethylene content in Ethylene-Propylene copolymers. IR4 detector is calibrated with series of 8 EP copolymers with known Ethylene content in the range of 2 wt.-% to 69 wt.-% (determined by 13 C-NMR spectroscopy) and various concentration between 2 and 13mg/ml for each used EP copolymer used for calibration. The amount of Soluble fraction (SF) and Crystalline Fraction (CF) are correlated through the XS calibration to the “Xylene Cold Soluble” (XCS) quantity and respectively Xylene Cold Insoluble (XCI) fractions, determined according to standard gravimetric method as per ISO16152. XS calibration is achieved by testing various EP copolymers with XS content in the range 2-31 wt.-%. The intrinsic viscosity (iV) of the parent EP copolymer and its soluble and crystalline fractions are determined with a use of an online 2-capillary viscometer and are correlated to corresponding iV’s determined by standard method in decalin according to ISO 1628. Calibration is achieved with various EP PP copolymers with iV = 2-4 dL/g. A sample of the PP composition to be analyzed is weighed out in concentrations of 10mg/ml to 20mg/ml. After automated filling of the vial with 1,2,4-TCB containing 250 mg/l 2,6-tert- butyl-4-methylphenol (BHT) as antioxidant, the sample is dissolved at 160°C until complete dissolution is achieved, usually for 60 min, with constant stirring of 800 rpm. As shown in a Figure 1a and 1b, a defined volume of the sample solution is injected into the column filled with inert support where the crystallization of the sample and separation of the soluble fraction from the crystalline part is taking place. This process is repeated two times. During the first injection the whole sample is measured at high temperature, determining the iV[dl/g] and the C2[wt.-%] of the PP composition. During the second injection the soluble fraction (at low temperature) and the crystalline fraction (at high temperature) with the crystallization cycle are measured (wt.-% SF, wt.-% C2, iV). EP means ethylene propylene copolymer. PP means polypropylene. Figure 1(a): schematic diagram of the CRYSTEX QC instrument Figure 1(b): elution of the EP copolymer sample and obtained soluble and crystalline fractions in the TREF column (column filled with inert material e.g. glass beads) (see Del Hierro, P.; Ortin, A.; Monrabal, B.; ‘Soluble Fraction Analysis in polypropylene). Intrinsic viscosity: The intrinsic viscosity (IV) was measured according to DIN ISO 1628/1, October 1999, in Decalin at 135°C. VOC/Fog emission was measured according to VDA 278:2002 on injection moulded test specimen and on the granulated compounds. The volatile organic compounds are measured in toluene equivalents per gram. The fogging is measured in hexadecane equivalents per gram. The measurements were carried out with a TDSA supplied by Gerstel using helium 5.0 as carrier gas and a column HP Ultra 2 of 50 m length and 0.32 mm diameter and 0.52 µm coating of 5 % Phenyl-Methyl-Siloxane. The VOC-Analysis was done according to device setting 1 listed in the standard using following main parameters: flow mode splitless, final temperature 90 °C; final time 30 min, rate 60K/min. The cooling trap was purged with a flow-mode split 1:30 in a temperature range from -150 °C to + 280 °C with a heating rate of 12 K/sec and a final time of 5 min. The following GC settings were used for analysis: 2 min isothermal at 40 °C. heating at 3 K/min up to 92 °C, then at 5 K/min up to 160 °C, and then at 10 K/min up to 280 °C, 10 minutes isothermal; flow 1.3 ml/min. The fog analysis was done according to device setting 1 listed in the standard using following main parameters: flow-mode splitless, rate 60 K/min; final temperature 120 °C; final time 60 min. The cooling trap was purged with a flow-mode split 1:30 in a temperature range from -150 °C to + 280 °C with a heating rate of 12 K/sec. The following GC-settings were used for analysis: isothermal at 50 °C for 2 min, heating at 25 K/min up to 160 °C, then at 10 K/min up to 280 °C, 30 minutes isothermal; flow 1.3 ml/min. B. Examples 1. Catalyst synthesis The catalyst used was Anti-dimethylsilanediyl[2-methyl-4,8-di(3,5-dimethylphenyl)- 1,5,6,7- tetrahydro-s-indacen-1-yl][2-methyl-4-(3,5-dimethylphenyl)-5 -methoxy-6-tert-butylinden-1-yl] zirconium dichloride as disclosed in WO 2020/239602 A1 as ICS3. Preparation of MAO-silica support A steel reactor equipped with a mechanical stirrer and a filter net was flushed with nitrogen and the reactor temperature was set to 20 °C. Next silica grade DM-L-303 from AGC Si-Tech Co, pre-calcined at 600 °C (5.0 kg) was added from a feeding drum followed by careful pressurising and depressurising with nitrogen using manual valves. Then toluene (22 kg) was added. The mixture was stirred for 15 min. Next 30 wt.-% solution of MAO in toluene (9.0 kg) from Lanxess was added via feed line on the top of the reactor within 70 min. The reaction mixture was then heated up to 90°C and stirred at 90 °C for additional two hours. The slurry was allowed to settle and the mother liquor was filtered off. The catalyst was washed twice with toluene (22 kg) at 90°C, following by settling and filtration. The reactor was cooled off to 60°C and the solid was washed with heptane (22.2 kg). Finally MAO treated SiO2 was dried at 60° under nitrogen flow for 2 hours and then for 5 hours under vacuum (-0.5 barg) with stirring. MAO treated support was collected as a free-flowing white powder found to contain 12.2% Al by weight. Catalyst preparation 30 wt.-% MAO in toluene (0.7 kg) was added into a steel nitrogen blanked reactor via a burette at 20 °C. Toluene (5.4 kg) was then added under stirring. The catalyst as cited above (93 g) was added from a metal cylinder followed by flushing with 1 kg toluene. The mixture was stirred for 60 minutes at 20 °C Trityl tetrakis(pentafluorophenyl) borate (91 g) was then added from a metal cylinder followed by a flush with 1 kg of toluene. The mixture was stirred for 1 h at room temperature. The resulting solution was added to a stirred cake of MAO-silica support prepared as described above over 1 hour. The cake was allowed to stay for 12 hours, followed by drying under N 2 flow at 60°C for 2h and additionally for 5 h under vacuum (-0.5 barg) under stirring. Dried catalyst was sampled in the form of pink free flowing powder containing 13.9% Al and 0.11% Zr. 2. Preparation of the in-reactor heterophasic polypropylene composition (HECO1) and the propylene copolymer (cPP) The in-reactor heterophasic polypropylene composition (HECO1) and the propylene copolymer (cPP) were prepared in a sequential process comprising a loop reactor and one or two gas phase reactors in the presence of the above described catalyst. The reaction conditions and properties of the final polymers are summarized in Tables 1 and 2. Table 1: Preparation of the in-reactor heterophasic polypropylene composition (HECO1) and the propylene copolymer (cPP) Table 1: (continued) Table 2: Properties of the the in-reactor heterophasic polypropylene composition (HECO1) and the propylene copolymer (cPP) after pelletiziation 3. Preparation of the fiber reinforced composition (C) with HECO1 The fiber reinforced composition (C) was obtained by melt blending the in-reactor heterophasic polypropylene composition (HECO1) with the glass fibers (GF), the adhesion promoter (AP) and the additives (AD) in a co-rotating twin screw extruder. The composition and properties of the inventive and comparative examples are summarized in Table 3. Table 3: Composition and properties of the inventive and comparative examples HECO1a is the commercial heterophasic propylene copolymer EF015AE of Borealis AG prepared with a Ziegler-Natta catalyst having a xylene cold soluble content of 29.0 wt.-%, an ethylene content of 11.1 mol-% and an intrinsic viscosity of the xylene soluble fraction of 2.7 dl/g. hP is the commercial propylene homopolymer HJ120UB of Borealis AG prepared with a Ziegler-Natta catalyst having a melt flow rate MFR 2 (230 °C) of 75 g/10 min, a density of 905 kg/m 3 and a glass transition temperature Tg of +2 °C. GF is the commercial product ECS 03 T-480H of Nippon Electric Glass Co., Ltd. having a filament diameter of 10.5 μm and a strand length of 3 mm. AP is the adhesion promoter SCONA TPPP 8112 GA by Scona being a polypropylene functionalized with maleic anhydride having a maleic anhydride content of 1.4 wt.-% and a MFR (190 °C, 2.16 kg) above 80 g/10 min. AD1 is a masterbatch consisting of 14.0 wt.-% Tris (2,4-di-t-butylphenyl) phosphite (Kinox-68- G by HPL Additives), 14.0 wt.-% of pentaerythrityl- tetrakis(3-(3’,5’-di-tert. butyl-4-hydroxyphenyl)-propionate (Irganox 1010FF by BASF), 36.0 wt.-% of carbon black (50 wt.-% masterbatch) by Borealis, and 36.0 wt.-% of the propylene homopolymer HC001A by Borealis having a density of 905 kg/m 3 and a MFR (230 °C, 2.16 kg) of 3.2 g/10 min. 4. Preparation of the compounded heterophasic polypropylene composition (HECO2) Preparation of the fiber reinforced composition (C) with HECO2 The propylene copolymer (cPP) was melt blended with the elastomeric ethylene copolymer (E), the glass fibers (GF), the adhesion promoter (AP), optionally the low density polyethylene (LDPE) and the additives (AD) in a co-rotating twin screw extruder. The composition and properties of the inventive and comparative examples are summarized in Table 4. Table 4: Composition of the inventive and comparative examples cPPa is the commercial propylene ethylene random copolymer RD208CF of Borealis AG prepared with a Ziegler-Natta catalyst having an ethylene content of 7.3 mol-%, a melt flow rate MFR 2 (230 °C, 2.16kg) determined according to ISO 1133 of 8.0 g/10 min and a melting temperature Tm of 140 °C. cPPb is the metallocene propylene ethylene random copolymer according to example IE1 of WO 2015/121160 A1 having an ethylene content of 4.1 mol-% and a melt flow rate MFR 2 (230 °C, 2.16 kg) determined according to ISO 1133 of 4.0 g/10 min. E is the commercial copolymer of ethylene and 1-octene Queo 8201 of Borealis AG having a melt flow rate (190 °C, 2.16 kg) determined according to ISO 1133 of 1.1 g/10 min, a melting temperature Tm of 72 °C, a glass transition temperature Tg of -52 °C, a density of 882 kg/m 3 and an ethylene content of 75.5 wt.-%. LDPE is the commercial copolymer of ethylene and vinyl acetate OE5328 of Borealis AG having a melt flow rate 190 °C, 2.16 kg) determined according to ISO 1133 of 3.0 g/10 min, a density of 950 kg/m³ and a vinyl acetate content of 28.0 wt.-%. AD2 is a masterbatch consisting of 20.0 wt.-% of Erucamide (Finawax-E by Fine Organics), 6.6 wt.-% of Tris(2,4-di-tert.-butylphenyl)phosphite (Irgafox 168 by BASF), 6.6 wt.-% of pentaerythrityl-tetrakis(3-(3’,5’-di-tert. butyl-4-hydroxyphenyl)- propionate (Irganox 1010FF by BASF), 33.3 wt.-% of carbon black (50 wt.-% masterbatch) by Borealis, and 33.3 wt.-% of the propylene homopolymer HC001A by Borealis having a density of 905 kg/m 3 and a MFR (230 °C, 2.16 kg) of 3.2 g/10 min. AD3 is a masterbatch consisting of 18.18 wt.-% of Tris(2,4-di-tert.-butylphenyl)phosphite (Irgafox 168 by BASF), 36.36 wt.-% of pentaerythrityl-tetrakis(3-(3’,5’-di-tert. butyl- 4-hydroxyphenyl)-propionate (Irganox 1010FF by BASF) and 45.45 wt.-% Di- stearyl-thio-propionate (Irganox PS-802 FL by BASF).