Title:
FLUORINE-CONTAINING CATIONIC POLYMERIZED MONOMER AND SYNTHESIS AND APPLICATION THEREOF
Document Type and Number:
WIPO Patent Application WO/2020/078422
Kind Code:
A1
Abstract:
Provided is the monomer compound of formula (I), the variables thereof being as defined in the description. The monomer is synthesized at high yield and quickly by means of a click chemistry reaction between a thiol and an olefin; furthermore, a substantially perfluorinated alkane chain is introduced into an oxacycloalkane monomer by means of a linker containing a norbornane structural part, such that the surface hardness of a photocured film obtained by photocuring the obtained monomer cation is high and surface energy is low, and the hydrophobic and oleophobic properties are excellent; in particular, it is very resistant to oil stains; the invention also relates to a method for preparing a monomer; the polymer obtained by ring-opening polymerization of the monomer contains the photocurable composition of the monomer and a photocurable material obtained by photocuring said photocurable composition.
Inventors:
ZOU YINGQUAN (CN)
DENG YUFEI (CN)
DENG YUFEI (CN)
Application Number:
PCT/CN2019/111675
Publication Date:
April 23, 2020
Filing Date:
October 17, 2019
Export Citation:
Assignee:
HUBEI GURUN TECH CO LTD (CN)
International Classes:
C07C41/00; C07D305/06; C07C41/09; C07D303/04
Foreign References:
| CN106187953A | 2016-12-07 | |||
| CN1496496A | 2004-05-12 | |||
| EP0430887A2 | 1991-06-05 | |||
| JP2018127410A | 2018-08-16 |
Other References:
SHU-QING FANG ET AL.: "Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers", CHINESE JOURNAL OF POLYMER SCIENCE, vol. 36, 20 December 2017 (2017-12-20), XP036490646, DOI: 20191231170115A
Attorney, Agent or Firm:
ZHONGZI LAW OFFICE (CN)
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